DOI: 10.1002/kin.550150207. Pyrolysis studies of main group metal‐alkyl bond dissociation energies: VLPP of GeMe4, SbEt3, PbEt4, and PEt3

Pyrolysis studies of main group metal‐alkyl bond dissociation energies: VLPP of GeMe4, SbEt3, PbEt4, and PEt3

10.1002/kin.550150207

Crossref journal-article

Wiley

International Journal of Chemical Kinetics (311)

Abstract

AbstractThe bond dissociation energies of tetramethyl germane, triethyl stibine, tetraethyl lead, and triethylphosphine were determined using the technique of very‐low‐pressure pyrolysis. Arguments are presented for log A ≥ 17.0. The respective dissociation energies ΔH298 are 83, 57, 54, and 68 (±2) kcal/mol. A consistent set of methyl bond energies to main group metals is determined from these and previous results, and is examined for trends. Bond energies for various radicals to tin are also derived.

Bibliography

Smith, G. P., & Patrick, R. (1983). Pyrolysis studies of main group metalâalkyl bond dissociation energies: VLPP of GeMe4, SbEt3, PbEt4, and PEt3. International Journal of Chemical Kinetics, 15(2), 167â185. Portico.

Authors 2

Gregory P. Smith (first)
Roger Patrick (additional)

References 43 Referenced 64

{'key': 'e_1_2_1_2_2', 'volume-title': 'Thermochemical Kinetics', 'author': 'Benson S. W.', 'year': '1976'} / Thermochemical Kinetics by Benson S. W. (1976)
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{'key': 'e_1_2_1_30_4', 'series-title': 'NSRDS‐NBS39', 'volume-title': 'Molecular Vibrational Frequencies', 'author': 'Shimanouchi T.'} / Molecular Vibrational Frequencies / NSRDS‐NBS39 by Shimanouchi T.
{'key': 'e_1_2_1_31_2', 'volume-title': 'Molecular Theory of Gases and Liquids', 'author': 'Hirschfelder J. O.', 'year': '1954'} / Molecular Theory of Gases and Liquids by Hirschfelder J. O. (1954)
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{'key': 'e_1_2_1_40_2', 'volume-title': 'Chemical Thermodynamics of Organic Compounds', 'author': 'Stull D. R.', 'year': '1969'} / Chemical Thermodynamics of Organic Compounds by Stull D. R. (1969)
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10.1002/zfch.19630031103

Dates

Type	When
Created	20 years, 7 months ago (Jan. 1, 2005, 9:58 p.m.)
Deposited	1 year, 10 months ago (Oct. 20, 2023, 4:28 a.m.)
Indexed	1 year, 6 months ago (Feb. 10, 2024, 6:42 a.m.)
Issued	42 years, 6 months ago (Feb. 1, 1983)
Published	42 years, 6 months ago (Feb. 1, 1983)
Published Online	20 years, 10 months ago (Oct. 19, 2004)
Published Print	42 years, 6 months ago (Feb. 1, 1983)

Funders 0

None

BibTeX

@article{Smith_1983, title={Pyrolysis studies of main group metal‐alkyl bond dissociation energies: VLPP of GeMe4, SbEt3, PbEt4, and PEt3}, volume={15}, ISSN={1097-4601}, url={http://dx.doi.org/10.1002/kin.550150207}, DOI={10.1002/kin.550150207}, number={2}, journal={International Journal of Chemical Kinetics}, publisher={Wiley}, author={Smith, Gregory P. and Patrick, Roger}, year={1983}, month=feb, pages={167–185} }

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