DOI: 10.1002/kin.550131104. Rate constants for the gas‐phase reactions of O<sub>3</sub> with a series of carbonyls at 296 K

Rate constants for the gas‐phase reactions of O3 with a series of carbonyls at 296 K

10.1002/kin.550131104

Crossref journal-article

Wiley

International Journal of Chemical Kinetics (311)

Abstract

AbstractRate constants for the gas‐phase reactions of O3 with the carbonyls acrolein, crotonaldehyde, methacrolein, methylvinylketone, 3‐penten‐2‐one, 2‐cyclohexen‐1‐one, acetaldehyde, and methylglyoxal have been determined at 296 ± 2 K. The rate constants ranged from <6 × 10−21 cm3 molecule−1 s−1 for acetaldehyde to 2.13 × 10−17 cm3 molecule−1 s−1 for 3‐penten‐2‐one. The substituent effects of CHO and CH3CO groups on the rate constants are assessed and discussed, as are implications for the atmospheric chemistry of the natural hydrocarbon isoprene.

Bibliography

Atkinson, R., Aschmann, S. M., Winer, A. M., & Pitts, J. N. (1981). Rate constants for the gasâphase reactions of O3 with a series of carbonyls at 296 K. International Journal of Chemical Kinetics, 13(11), 1133â1142. Portico.

Authors 4

Roger Atkinson (first)
Sara M. Aschmann (additional)
Arthur M. Winer (additional)
James N. Pitts (additional)

References 22 Referenced 66

{'key': 'e_1_2_1_2_2', 'first-page': '75', 'volume': '7', 'author': 'Finlayson‐Pitts B. J.', 'year': '1977', 'journal-title': 'Adv. Environ. Sci. Technol.'} / Adv. Environ. Sci. Technol. by Finlayson‐Pitts B. J. (1977)
10.6028/NBS.SP.557
10.1080/10934527609385750
{'key': 'e_1_2_1_5_2', 'volume-title': 'Atmospheric Ozone‐Olefin Reactions', 'author': 'Hanst P. L.', 'year': '1958'} / Atmospheric Ozone‐Olefin Reactions by Hanst P. L. (1958)
10.1080/00139307309435501
10.1002/kin.550080602
10.1029/GL005i008p00679
{'key': 'e_1_2_1_9_2', 'series-title': 'EPA‐600/3–79–081', 'volume-title': 'Photochemistry of Some Naturally Emitted Hydrocarbons', 'author': 'Arnts R. R.', 'year': '1979'} / Photochemistry of Some Naturally Emitted Hydrocarbons / EPA‐600/3–79–081 by Arnts R. R. (1979)
{'key': 'e_1_2_1_10_2', 'series-title': 'EPA‐600/S3–81–024', 'volume-title': 'Experimental Protocol forDetermining Ozone Reaction Rate Constants', 'author': 'Pitts J. N.', 'year': '1981'} / Experimental Protocol forDetermining Ozone Reaction Rate Constants / EPA‐600/S3–81–024 by Pitts J. N. (1981)
R.Atkinson S. M.Aschmann D. R.Fitz A. M.Winer andJ. N.Pitts Jr. Int. J. Chem. Kinet. in press.
A. J.Bowles W. O.George andW. F.Maddams J. Chem. Soc. B 810(1969). (10.1039/J29690000810)
10.1021/ja00803a023
10.1021/j150671a003
10.1063/1.435230
10.1002/kin.550111106
10.1002/kin.550121009
10.1002/kin.550121202
G. W.Harris T. E.Kleindienst andJ. N.Pitts Jr. unpublished data.
R.Atkinson W. P. L.Carter A. M.Winer andJ. N.Pitts Jr. unpublished data.
10.1021/j100614a004
{'key': 'e_1_2_1_22_2', 'series-title': 'Int. J. Chem. Kinet., Symp. 1', 'first-page': '165', 'author': 'Huie R. E.', 'year': '1975'} / Int. J. Chem. Kinet., Symp. 1 by Huie R. E. (1975)
10.1002/9780470133415.ch5

Dates

Type	When
Created	20 years, 7 months ago (Jan. 1, 2005, 9:33 p.m.)
Deposited	1 year, 10 months ago (Oct. 19, 2023, 3:30 a.m.)
Indexed	1 month, 2 weeks ago (July 16, 2025, 8:01 a.m.)
Issued	43 years, 9 months ago (Nov. 1, 1981)
Published	43 years, 9 months ago (Nov. 1, 1981)
Published Online	20 years, 9 months ago (Nov. 1, 2004)
Published Print	43 years, 9 months ago (Nov. 1, 1981)

Funders 0

None

BibTeX

@article{Atkinson_1981, title={Rate constants for the gas‐phase reactions of O3 with a series of carbonyls at 296 K}, volume={13}, ISSN={1097-4601}, url={http://dx.doi.org/10.1002/kin.550131104}, DOI={10.1002/kin.550131104}, number={11}, journal={International Journal of Chemical Kinetics}, publisher={Wiley}, author={Atkinson, Roger and Aschmann, Sara M. and Winer, Arthur M. and Pitts, James N.}, year={1981}, month=nov, pages={1133–1142} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2025,
        7,
        16
      ]
    ],
    "date-time": "2025-07-16T12:01:01Z",
    "timestamp": 1752667261487
  },
  "reference-count": 22,
  "publisher": "Wiley",
  "issue": "11",
  "license": [
    {
      "start": {
        "date-parts": [
          [
            2004,
            11,
            1
          ]
        ],
        "date-time": "2004-11-01T00:00:00Z",
        "timestamp": 1099267200000
      },
      "content-version": "vor",
      "delay-in-days": 8401,
      "URL": "http://onlinelibrary.wiley.com/termsAndConditions#vor"
    }
  ],
  "content-domain": {
    "domain": [],
    "crossmark-restriction": false
  },
  "published-print": {
    "date-parts": [
      [
        1981,
        11
      ]
    ]
  },
  "abstract": "<jats:title>Abstract</jats:title><jats:p>Rate constants for the gas\u2010phase reactions of O<jats:sub>3</jats:sub> with the carbonyls acrolein, crotonaldehyde, methacrolein, methylvinylketone, 3\u2010penten\u20102\u2010one, 2\u2010cyclohexen\u20101\u2010one, acetaldehyde, and methylglyoxal have been determined at 296 \u00b1 2 K. The rate constants ranged from &lt;6 \u00d7 10<jats:sup>\u221221</jats:sup> cm<jats:sup>3</jats:sup> molecule<jats:sup>\u22121</jats:sup> s<jats:sup>\u22121</jats:sup> for acetaldehyde to 2.13 \u00d7 10<jats:sup>\u221217</jats:sup> cm<jats:sup>3</jats:sup> molecule<jats:sup>\u22121</jats:sup> s<jats:sup>\u22121</jats:sup> for 3\u2010penten\u20102\u2010one. The substituent effects of \uf8ffCHO and CH<jats:sub>3</jats:sub>CO\uf8ff groups on the rate constants are assessed and discussed, as are implications for the atmospheric chemistry of the natural hydrocarbon isoprene.</jats:p>",
  "DOI": "10.1002/kin.550131104",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2005,
        1,
        2
      ]
    ],
    "date-time": "2005-01-02T02:33:12Z",
    "timestamp": 1104633192000
  },
  "page": "1133-1142",
  "source": "Crossref",
  "is-referenced-by-count": 66,
  "title": "Rate constants for the gas\u2010phase reactions of O<sub>3</sub> with a series of carbonyls at 296 K",
  "prefix": "10.1002",
  "volume": "13",
  "author": [
    {
      "given": "Roger",
      "family": "Atkinson",
      "sequence": "first",
      "affiliation": []
    },
    {
      "given": "Sara M.",
      "family": "Aschmann",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "Arthur M.",
      "family": "Winer",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "suffix": "Jr.",
      "given": "James N.",
      "family": "Pitts",
      "sequence": "additional",
      "affiliation": []
    }
  ],
  "member": "311",
  "published-online": {
    "date-parts": [
      [
        2004,
        11
      ]
    ]
  },
  "reference": [
    {
      "key": "e_1_2_1_2_2",
      "first-page": "75",
      "volume": "7",
      "author": "Finlayson\u2010Pitts B. J.",
      "year": "1977",
      "journal-title": "Adv. Environ. Sci. Technol."
    },
    {
      "key": "e_1_2_1_3_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.6028/NBS.SP.557"
    },
    {
      "key": "e_1_2_1_4_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1080/10934527609385750"
    },
    {
      "key": "e_1_2_1_5_2",
      "volume-title": "Atmospheric Ozone\u2010Olefin Reactions",
      "author": "Hanst P. L.",
      "year": "1958"
    },
    {
      "key": "e_1_2_1_6_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1080/00139307309435501"
    },
    {
      "key": "e_1_2_1_7_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/kin.550080602"
    },
    {
      "key": "e_1_2_1_8_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1029/GL005i008p00679"
    },
    {
      "key": "e_1_2_1_9_2",
      "series-title": "EPA\u2010600/3\u201379\u2013081",
      "volume-title": "Photochemistry of Some Naturally Emitted Hydrocarbons",
      "author": "Arnts R. R.",
      "year": "1979"
    },
    {
      "key": "e_1_2_1_10_2",
      "series-title": "EPA\u2010600/S3\u201381\u2013024",
      "volume-title": "Experimental Protocol forDetermining Ozone Reaction Rate Constants",
      "author": "Pitts J. N.",
      "year": "1981"
    },
    {
      "key": "e_1_2_1_11_2",
      "unstructured": "R.Atkinson S. M.Aschmann D. R.Fitz A. M.Winer andJ. N.Pitts Jr. Int. J. Chem. Kinet. in press."
    },
    {
      "key": "e_1_2_1_12_2",
      "doi-asserted-by": "crossref",
      "unstructured": "A. J.Bowles W. O.George andW. F.Maddams J. Chem. Soc. B 810(1969).",
      "DOI": "10.1039/J29690000810"
    },
    {
      "key": "e_1_2_1_13_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ja00803a023"
    },
    {
      "key": "e_1_2_1_14_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/j150671a003"
    },
    {
      "key": "e_1_2_1_15_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1063/1.435230"
    },
    {
      "key": "e_1_2_1_16_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/kin.550111106"
    },
    {
      "key": "e_1_2_1_17_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/kin.550121009"
    },
    {
      "key": "e_1_2_1_18_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/kin.550121202"
    },
    {
      "key": "e_1_2_1_19_2",
      "unstructured": "G. W.Harris T. E.Kleindienst andJ. N.Pitts Jr. unpublished data."
    },
    {
      "key": "e_1_2_1_20_2",
      "unstructured": "R.Atkinson W. P. L.Carter A. M.Winer andJ. N.Pitts Jr. unpublished data."
    },
    {
      "key": "e_1_2_1_21_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/j100614a004"
    },
    {
      "key": "e_1_2_1_22_2",
      "series-title": "Int. J. Chem. Kinet., Symp. 1",
      "first-page": "165",
      "author": "Huie R. E.",
      "year": "1975"
    },
    {
      "key": "e_1_2_1_23_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/9780470133415.ch5"
    }
  ],
  "container-title": "International Journal of Chemical Kinetics",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fkin.550131104",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "text-mining"
    },
    {
      "URL": "https://onlinelibrary.wiley.com/doi/pdf/10.1002/kin.550131104",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2023,
        10,
        19
      ]
    ],
    "date-time": "2023-10-19T07:30:39Z",
    "timestamp": 1697700639000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://onlinelibrary.wiley.com/doi/10.1002/kin.550131104"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        1981,
        11
      ]
    ]
  },
  "references-count": 22,
  "journal-issue": {
    "issue": "11",
    "published-print": {
      "date-parts": [
        [
          1981,
          11
        ]
      ]
    }
  },
  "alternative-id": [
    "10.1002/kin.550131104"
  ],
  "URL": "http://dx.doi.org/10.1002/kin.550131104",
  "relation": {},
  "ISSN": [
    "0538-8066",
    "1097-4601"
  ],
  "subject": [],
  "container-title-short": "Int J of Chemical Kinetics",
  "published": {
    "date-parts": [
      [
        1981,
        11
      ]
    ]
  }
}