DOI: 10.1002/kin.550060509. Ozone–olefin reactions in the gas phase 1. Rate constants and activation energies

Ozone–olefin reactions in the gas phase 1. Rate constants and activation energies

10.1002/kin.550060509

Crossref journal-article

Wiley

International Journal of Chemical Kinetics (311)

Abstract

AbstractReactions of ozone with simple olefins have been studied between 6 and 800 mtorr total pressure in a 220‐m3 reactor. Rate constants for the removal of ozone by an excess of olefin in the presence of 150 mtorr oxygen were determined over the temperature range 280 to 360° K by continuous optical absorption measurements at 2537 Å. The technique was tested by measuring the rate constants k1 and k2 of the reactions (1) NO + O3 → NO2 + O2 and (2) NO2 + O3 rarr; NO3 + O2 which are known from the literature. The results for NO, NO2, C2H4, C3H6, 2‐butene (mixture of the isomers), 1,3→butadiene, isobutene, and 1,1 ‐difluoro‐ethylene are 1.7 × 10−1 4 (290°K), 3.24 × 10−17 (289°K), 1.2 × 10−1 4 exp (–4.95 ± 0.20/RT), 1.1 × 10−1 4 exp (–3.91 ± 0.20/RT), 0.94 × 10−1 4 exp ( –2.28 ± 0.15/RT), 5.45 ± 10−1 4 exp ( –5.33 ± 0.20/RT), 1.8 ×10−17 (283°K), and 8 × 10−20 cm3/molecule ·s(290°K). Productformation from the ozone–propylene reaction was studied by a mass spectrometric technique. The stoichiometry of the reaction is near unity in the presence of molecular oxygen.

Bibliography

Becker, K. H., Schurath, U., & Seitz, H. (1974). Ozoneâolefin reactions in the gas phase 1. Rate constants and activation energies. International Journal of Chemical Kinetics, 6(5), 725â739. Portico.

Authors 3

K. H. Becker (first)
U. Schurath (additional)
H. Seitz (additional)

References 35 Referenced 50

10.1002/cber.19550881210
10.1021/cr50023a005
10.1021/ja00776a072
10.1021/ja00791a044
{'key': 'e_1_2_1_3_2', 'volume-title': 'Photochemistry of Air Pollution', 'author': 'Leighton P. A.', 'year': '1961'} / Photochemistry of Air Pollution by Leighton P. A. (1961)
10.1139/v60-146
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10.1139/v65-302
10.1002/kin.550010207
10.1007/BF00623126
(b)K. H.Becker W.Groth andD.Thran inProc. 14th Internat. Symp. on Combustion The Combustion Institute Pittsburgh Pa. 1973. (10.1016/S0082-0784(73)80035-9)
10.1029/RG009i002p00305
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{'key': 'e_1_2_1_19_2', 'first-page': '427', 'volume-title': 'The Foundation of Chemical Kinetics', 'author': 'Benson S. W.', 'year': '1960'} / The Foundation of Chemical Kinetics by Benson S. W. (1960)
{'key': 'e_1_2_1_20_2', 'volume-title': 'Atmospheric Ozone–Olefin Reactions', 'author': 'Hanst P. L.', 'year': '1958'} / Atmospheric Ozone–Olefin Reactions by Hanst P. L. (1958)
10.1139/v73-228
K. H.Becker K. H.Steinhoff andU.Schurath to be published.
10.1016/0009-2614(72)90016-4
10.1002/kin.550050310
{'key': 'e_1_2_1_25_2', 'volume-title': 'Thermochemical Kinetics', 'author': 'Benson S. W.', 'year': '1968'} / Thermochemical Kinetics by Benson S. W. (1968)
10.1021/cr60259a002
10.1063/1.1676885
10.1039/f19726801735

Dates

Type	When
Created	20 years, 8 months ago (Jan. 5, 2005, 11:19 p.m.)
Deposited	1 year, 10 months ago (Oct. 18, 2023, 10:56 p.m.)
Indexed	1 year, 5 months ago (March 19, 2024, 12:26 a.m.)
Issued	51 years ago (Sept. 1, 1974)
Published	51 years ago (Sept. 1, 1974)
Published Online	20 years, 10 months ago (Oct. 19, 2004)
Published Print	51 years ago (Sept. 1, 1974)

Funders 0

None

BibTeX

@article{Becker_1974, title={Ozone–olefin reactions in the gas phase 1. Rate constants and activation energies}, volume={6}, ISSN={1097-4601}, url={http://dx.doi.org/10.1002/kin.550060509}, DOI={10.1002/kin.550060509}, number={5}, journal={International Journal of Chemical Kinetics}, publisher={Wiley}, author={Becker, K. H. and Schurath, U. and Seitz, H.}, year={1974}, month=sep, pages={725–739} }

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