DOI: 10.1002/kin.550060402. The kinetics of nucleophilic substitution processes in the alkyl halides. Part A

The kinetics of nucleophilic substitution processes in the alkyl halides. Part A—theory

10.1002/kin.550060402

Crossref journal-article

Wiley

International Journal of Chemical Kinetics (311)

Abstract

AbstractActivation energies for substitution reactions of the type AC + B → A + CB, occurring in polar media and characterized by an abrupt change of the term along two coordinates have been calculated within the framework of the quantum‐mechanical theory of chemical reactions. In the case of nonadiabatic processes, the transmission coefficient and activation energy for these reactions are expressed in terms of characteristic parameters of the medium (reorganization energy, effective frequency of solvent fluctuation polarization) and the potential energy curves for intermolecular interactions between the reactants (AC and B) and between the products (A and BC).

Bibliography

German, E. D., & Dogonadze, R. R. (1974). The kinetics of nucleophilic substitution processes in the alkyl halides. Part Aâtheory. International Journal of Chemical Kinetics, 6(4), 457â466. Portico.

Authors 2

E. D. German (first)
R. R. Dogonadze (additional)

References 27 Referenced 21

{'key': 'e_1_2_1_2_2', 'first-page': '603', 'volume': '31', 'author': 'Ogg R. A.', 'year': '1935', 'journal-title': 'Trans. Faraday Soc.'} / Trans. Faraday Soc. by Ogg R. A. (1935)
10.1039/tf9353101385
10.1039/tf9413700603
I.Dostrovsky E. D.Hughes andC. K.Ingold J. Chem. Soc. 173(1946). (10.1039/JR9460000173)
P. B. D.de la Mare L.Fowden E. D.Hughes C. K.Ingold andJ. D.Mackie J. Chem. Soc. 3(1955).
{'key': 'e_1_2_1_7_2', 'first-page': '364', 'volume': '47', 'author': 'Pahari M.', 'year': '1970', 'journal-title': 'J. Ind. Chem. Soc.'} / J. Ind. Chem. Soc. by Pahari M. (1970)
10.1246/bcsj.38.1749
10.1016/S0040-4039(01)96463-9
10.1021/ja00731a002
94(1972).
10.1007/BF00527114
10.1016/0009-2614(70)85156-9
10.1016/0009-2614(71)87053-7
{'key': 'e_1_2_1_14_2', 'volume-title': 'Reactions of Molecules at Electrodes', 'author': 'Dogonadze R. R.', 'year': '1971'} / Reactions of Molecules at Electrodes by Dogonadze R. R. (1971)
10.1016/0013-4686(70)80027-5
{'key': 'e_1_2_1_16_2', 'first-page': '99', 'volume': '19', 'author': 'German E. D.', 'year': '1971', 'journal-title': 'J. Res. Inst. Catal. Hokk. Univ.'} / J. Res. Inst. Catal. Hokk. Univ. by German E. D. (1971)
10.1002/pssb.2220540111
10.1002/pssb.2220530205
10.1016/S0022-0728(71)80189-4
{'key': 'e_1_2_1_20_2', 'first-page': '130', 'volume': '198', 'author': 'Dogonadze R. R.', 'year': '1971', 'journal-title': 'Dokl. Akad. Nauk SSSR'} / Dokl. Akad. Nauk SSSR by Dogonadze R. R. (1971)
{'key': 'e_1_2_1_21_2', 'first-page': '124', 'volume': '209', 'author': 'German E. D.', 'year': '1973', 'journal-title': 'Dokl. Akad. Nauk SSSR'} / Dokl. Akad. Nauk SSSR by German E. D. (1973)
{'key': 'e_1_2_1_22_2', 'first-page': '129', 'volume': '210', 'author': 'German E. D.', 'year': '1973', 'journal-title': 'Dokl. Akad. Nauk SSSR'} / Dokl. Akad. Nauk SSSR by German E. D. (1973)
{'key': 'e_1_2_1_23_2', 'first-page': '1135', 'volume': '209', 'author': 'Vorotyntsev M. A.', 'year': '1973', 'journal-title': 'Dokl. Akad. Nauk SSSR'} / Dokl. Akad. Nauk SSSR by Vorotyntsev M. A. (1973)
10.1063/1.1742723
10.1039/df9602900021
10.1146/annurev.pc.15.100164.001103
10.1063/1.1696792

Dates

Type	When
Created	20 years, 7 months ago (Jan. 5, 2005, 11:15 p.m.)
Deposited	1 year, 10 months ago (Oct. 19, 2023, 3:23 a.m.)
Indexed	1 year, 6 months ago (Feb. 9, 2024, 7:37 p.m.)
Issued	51 years, 2 months ago (July 1, 1974)
Published	51 years, 2 months ago (July 1, 1974)
Published Online	20 years, 10 months ago (Oct. 19, 2004)
Published Print	51 years, 2 months ago (July 1, 1974)

Funders 0

None

BibTeX

@article{German_1974, title={The kinetics of nucleophilic substitution processes in the alkyl halides. Part A—theory}, volume={6}, ISSN={1097-4601}, url={http://dx.doi.org/10.1002/kin.550060402}, DOI={10.1002/kin.550060402}, number={4}, journal={International Journal of Chemical Kinetics}, publisher={Wiley}, author={German, E. D. and Dogonadze, R. R.}, year={1974}, month=jul, pages={457–466} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2024,
        2,
        10
      ]
    ],
    "date-time": "2024-02-10T00:37:40Z",
    "timestamp": 1707525460503
  },
  "reference-count": 27,
  "publisher": "Wiley",
  "issue": "4",
  "license": [
    {
      "start": {
        "date-parts": [
          [
            2004,
            10,
            19
          ]
        ],
        "date-time": "2004-10-19T00:00:00Z",
        "timestamp": 1098144000000
      },
      "content-version": "vor",
      "delay-in-days": 11068,
      "URL": "http://onlinelibrary.wiley.com/termsAndConditions#vor"
    }
  ],
  "content-domain": {
    "domain": [],
    "crossmark-restriction": false
  },
  "published-print": {
    "date-parts": [
      [
        1974,
        7
      ]
    ]
  },
  "abstract": "<jats:title>Abstract</jats:title><jats:p>Activation energies for substitution reactions of the type AC + B \u2192 A + CB, occurring in polar media and characterized by an abrupt change of the term along two coordinates have been calculated within the framework of the quantum\u2010mechanical theory of chemical reactions. In the case of nonadiabatic processes, the transmission coefficient and activation energy for these reactions are expressed in terms of characteristic parameters of the medium (reorganization energy, effective frequency of solvent fluctuation polarization) and the potential energy curves for intermolecular interactions between the reactants (AC and B) and between the products (A and BC).</jats:p>",
  "DOI": "10.1002/kin.550060402",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2005,
        1,
        6
      ]
    ],
    "date-time": "2005-01-06T04:15:58Z",
    "timestamp": 1104984958000
  },
  "page": "457-466",
  "source": "Crossref",
  "is-referenced-by-count": 21,
  "title": "The kinetics of nucleophilic substitution processes in the alkyl halides. Part A\u2014theory",
  "prefix": "10.1002",
  "volume": "6",
  "author": [
    {
      "given": "E. D.",
      "family": "German",
      "sequence": "first",
      "affiliation": []
    },
    {
      "given": "R. R.",
      "family": "Dogonadze",
      "sequence": "additional",
      "affiliation": []
    }
  ],
  "member": "311",
  "published-online": {
    "date-parts": [
      [
        2004,
        10,
        19
      ]
    ]
  },
  "reference": [
    {
      "key": "e_1_2_1_2_2",
      "first-page": "603",
      "volume": "31",
      "author": "Ogg R. A.",
      "year": "1935",
      "journal-title": "Trans. Faraday Soc."
    },
    {
      "key": "e_1_2_1_3_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1039/tf9353101385"
    },
    {
      "key": "e_1_2_1_4_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1039/tf9413700603"
    },
    {
      "key": "e_1_2_1_5_2",
      "doi-asserted-by": "crossref",
      "unstructured": "I.Dostrovsky E. D.Hughes andC. K.Ingold J. Chem. Soc. 173(1946).",
      "DOI": "10.1039/JR9460000173"
    },
    {
      "key": "e_1_2_1_6_2",
      "unstructured": "P. B. D.de la Mare L.Fowden E. D.Hughes C. K.Ingold andJ. D.Mackie J. Chem. Soc. 3(1955)."
    },
    {
      "key": "e_1_2_1_7_2",
      "first-page": "364",
      "volume": "47",
      "author": "Pahari M.",
      "year": "1970",
      "journal-title": "J. Ind. Chem. Soc."
    },
    {
      "key": "e_1_2_1_8_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1246/bcsj.38.1749"
    },
    {
      "key": "e_1_2_1_9_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/S0040-4039(01)96463-9"
    },
    {
      "key": "e_1_2_1_10_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ja00731a002"
    },
    {
      "key": "e_1_2_1_10_3",
      "unstructured": "94(1972)."
    },
    {
      "key": "e_1_2_1_11_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1007/BF00527114"
    },
    {
      "key": "e_1_2_1_12_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0009-2614(70)85156-9"
    },
    {
      "key": "e_1_2_1_13_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0009-2614(71)87053-7"
    },
    {
      "key": "e_1_2_1_14_2",
      "volume-title": "Reactions of Molecules at Electrodes",
      "author": "Dogonadze R. R.",
      "year": "1971"
    },
    {
      "key": "e_1_2_1_15_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0013-4686(70)80027-5"
    },
    {
      "key": "e_1_2_1_16_2",
      "first-page": "99",
      "volume": "19",
      "author": "German E. D.",
      "year": "1971",
      "journal-title": "J. Res. Inst. Catal. Hokk. Univ."
    },
    {
      "key": "e_1_2_1_17_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/pssb.2220540111"
    },
    {
      "key": "e_1_2_1_18_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/pssb.2220530205"
    },
    {
      "key": "e_1_2_1_19_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/S0022-0728(71)80189-4"
    },
    {
      "key": "e_1_2_1_20_2",
      "first-page": "130",
      "volume": "198",
      "author": "Dogonadze R. R.",
      "year": "1971",
      "journal-title": "Dokl. Akad. Nauk SSSR"
    },
    {
      "key": "e_1_2_1_21_2",
      "first-page": "124",
      "volume": "209",
      "author": "German E. D.",
      "year": "1973",
      "journal-title": "Dokl. Akad. Nauk SSSR"
    },
    {
      "key": "e_1_2_1_22_2",
      "first-page": "129",
      "volume": "210",
      "author": "German E. D.",
      "year": "1973",
      "journal-title": "Dokl. Akad. Nauk SSSR"
    },
    {
      "key": "e_1_2_1_23_2",
      "first-page": "1135",
      "volume": "209",
      "author": "Vorotyntsev M. A.",
      "year": "1973",
      "journal-title": "Dokl. Akad. Nauk SSSR"
    },
    {
      "key": "e_1_2_1_24_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1063/1.1742723"
    },
    {
      "key": "e_1_2_1_24_3",
      "doi-asserted-by": "publisher",
      "DOI": "10.1039/df9602900021"
    },
    {
      "key": "e_1_2_1_24_4",
      "doi-asserted-by": "publisher",
      "DOI": "10.1146/annurev.pc.15.100164.001103"
    },
    {
      "key": "e_1_2_1_24_5",
      "doi-asserted-by": "publisher",
      "DOI": "10.1063/1.1696792"
    }
  ],
  "container-title": "International Journal of Chemical Kinetics",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fkin.550060402",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "text-mining"
    },
    {
      "URL": "https://onlinelibrary.wiley.com/doi/pdf/10.1002/kin.550060402",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2023,
        10,
        19
      ]
    ],
    "date-time": "2023-10-19T07:23:54Z",
    "timestamp": 1697700234000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://onlinelibrary.wiley.com/doi/10.1002/kin.550060402"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        1974,
        7
      ]
    ]
  },
  "references-count": 27,
  "journal-issue": {
    "issue": "4",
    "published-print": {
      "date-parts": [
        [
          1974,
          7
        ]
      ]
    }
  },
  "alternative-id": [
    "10.1002/kin.550060402"
  ],
  "URL": "http://dx.doi.org/10.1002/kin.550060402",
  "relation": {},
  "ISSN": [
    "0538-8066",
    "1097-4601"
  ],
  "subject": [],
  "container-title-short": "Int J of Chemical Kinetics",
  "published": {
    "date-parts": [
      [
        1974,
        7
      ]
    ]
  }
}