DOI: 10.1002/kin.550030504. Very low‐pressure pyrolysis. IV. The decomposition of <i>i</i>‐propyl iodide and <i>n</i>‐propyl iodide

Very low‐pressure pyrolysis. IV. The decomposition of i‐propyl iodide and n‐propyl iodide

10.1002/kin.550030504

Crossref journal-article

Wiley

International Journal of Chemical Kinetics (311)

Abstract

AbstractThe decomposition rate constant of i‐PrI under conditions of very low‐pressure pyrolysis (VLPP) is completely consistent with the well‐known high‐pressure Arrhenius parameters and the RRK(M) theory. The decomposition of n‐PrI under the same conditions proceeds via two pathways, the anti‐Markownikoff dehydroiodination and CI bond scission. The data, analyzed by taking into account the mutual interaction of the two pathways, is completely consistent with the known Arrhenius parameters for the bond scission step and, when combined with a reasonable A‐factor, yields an activation energy for HI elimination which is as predicted for these semi‐ion pair transition states.

Bibliography

King, K. D., Golden, D. M., Spokes, G. N., & Benson, S. W. (1971). Very lowâpressure pyrolysis. IV. The decomposition of iâpropyl iodide and nâpropyl iodide. International Journal of Chemical Kinetics, 3(5), 411â426. Portico.

Authors 4

Keith D. King (first)
David M. Golden (additional)
G. Neil Spokes (additional)
Sidney W. Benson (additional)

References 16 Referenced 34

10.1021/ja01000a007
{'key': 'e_1_2_1_3_2', 'volume-title': 'Kinetics of Homogeneous Gas Reactions', 'author': 'Kassel L. S.', 'year': '1932'} / Kinetics of Homogeneous Gas Reactions by Kassel L. S. (1932)
10.1063/1.1700424
{'key': 'e_1_2_1_4_3', 'volume': '37', 'author': 'Wieder G. M.', 'year': '1835', 'journal-title': 'J. Chem. Phys.'} / J. Chem. Phys. by Wieder G. M. (1835)
10.1021/j100868a600
10.1016/0021-9614(69)90066-4
{'key': 'e_1_2_1_7_2', 'first-page': '415', 'volume': '69', 'author': 'Yamada T.', 'year': '1966', 'journal-title': 'J. Chem. Soc. Japan, Industr. Chem. (Kogyo Kagaku Zasshi)'} / J. Chem. Soc. Japan, Industr. Chem. (Kogyo Kagaku Zasshi) by Yamada T. (1966)
10.1021/cr60257a002
{'key': 'e_1_2_1_9_2', 'volume-title': 'Kinetic Data on Gas‐Phase Unimolecular Reactions', 'author': "O'Neal H. E.", 'year': '1970'} / Kinetic Data on Gas‐Phase Unimolecular Reactions by O'Neal H. E. (1970)
10.1021/j100796a006
10.1021/j100680a001
{'key': 'e_1_2_1_12_2', 'first-page': '78', 'volume-title': 'Thermochemical Kinetics', 'author': 'Benson S. W.', 'year': '1968'} / Thermochemical Kinetics by Benson S. W. (1968)
10.1021/ja01096a002
{'key': 'e_1_2_1_13_3', 'volume-title': 'Symposium on the Transition State, Paris, 1970', 'author': 'Benson S. W.', 'year': '1971'} / Symposium on the Transition State, Paris, 1970 by Benson S. W. (1971)
10.1039/tf9545001164
10.1063/1.1696099

Dates

Type	When
Created	20 years, 7 months ago (Jan. 1, 2005, 9:16 p.m.)
Deposited	1 year, 10 months ago (Oct. 19, 2023, 2:56 a.m.)
Indexed	1 year, 1 month ago (July 10, 2024, 7:06 a.m.)
Issued	53 years, 11 months ago (Sept. 1, 1971)
Published	53 years, 11 months ago (Sept. 1, 1971)
Published Online	20 years, 10 months ago (Oct. 19, 2004)
Published Print	53 years, 11 months ago (Sept. 1, 1971)

Funders 0

None

BibTeX

@article{King_1971, title={Very low‐pressure pyrolysis. IV. The decomposition of i‐propyl iodide and n‐propyl iodide}, volume={3}, ISSN={1097-4601}, url={http://dx.doi.org/10.1002/kin.550030504}, DOI={10.1002/kin.550030504}, number={5}, journal={International Journal of Chemical Kinetics}, publisher={Wiley}, author={King, Keith D. and Golden, David M. and Spokes, G. Neil and Benson, Sidney W.}, year={1971}, month=sep, pages={411–426} }

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