DOI: 10.1002/jrs.2763. Structural study of Mg‐bearing sodosilicate glasses by Raman spectroscopy

Structural study of Mg‐bearing sodosilicate glasses by Raman spectroscopy

10.1002/jrs.2763

Crossref journal-article

Wiley

Journal of Raman Spectroscopy (311)

Abstract

AbstractThe presence of magnesium in glasses of geological, medical, and technological interests influences their physicochemical and durability properties. However, the understanding of the role of magnesium is dependent on the combined knowledge of the structural environment of magnesium in the glass or melt and of the silicate network connectivity of the studied systems. In this article, we present a Raman spectroscopic study of the network connectivity of 10 ternary silicate glasses in the system Na2OMgOSiO2 and one Mg‐free binary silicate glass Na2OSiO2. Results obtained at constant polymerization suggest the existence of various Qn units according to the nature of the modifying cation. As polymerization decreases for Na2OMgOαSiO2 glasses (labeled as NMSα with α decreasing from 10 to 2), the band associated with SiOSi bending in fully polymerized region disappears being gradually replaced by a band attributed to SiOSi bending in region containing mainly Q2 and Q3 species. For highly polymerized glasses (NMS10‐NMS4), the coexistence of these two bands suggests the presence of two interconnected networks. Concomitantly, the signal associated with Q3 species first increases. For a further decrease of the polymerization, the high wavenumber part of the signal associated with Q3 species decreases, while the intensity of the high wavenumber part of the band related to Q2 species increases. This result strongly suggests that magnesium charge‐balances preferentially Q2 species rather than Q3 species. Copyright © 2010 John Wiley & Sons, Ltd.

Bibliography

Trcera, N., Rossano, S., & Tarrida, M. (2011). Structural study of Mgâbearing sodosilicate glasses by Raman spectroscopy. Journal of Raman Spectroscopy, 42(4), 765â772. Portico.

Authors 3

Nicolas Trcera (first)
Stéphanie Rossano (additional)
Martine Tarrida (additional)

References 63 Referenced 33

{'key': 'e_1_2_7_2_2', 'first-page': '21', 'volume': '32', 'author': 'Dingwell D. B.', 'year': '1995', 'journal-title': 'Rev. Mineral.'} / Rev. Mineral. by Dingwell D. B. (1995)
10.1016/j.apgeochem.2006.03.010
10.1007/BF00705272
10.2109/jcersj.114.82
10.1016/S0169-4332(03)00179-X
10.1063/1.431671
10.1063/1.442472
10.1016/0022-3093(83)90032-7
{'key': 'e_1_2_7_10_2', 'first-page': '622', 'volume': '69', 'author': 'McMillan P. F.', 'year': '1984', 'journal-title': 'Am. Mineral.'} / Am. Mineral. by McMillan P. F. (1984)
{'key': 'e_1_2_7_11_2', 'first-page': '645', 'volume': '69', 'author': 'McMillan P. F.', 'year': '1984', 'journal-title': 'Am. Mineral.'} / Am. Mineral. by McMillan P. F. (1984)
10.1007/BF00307725
10.1016/0022-3093(82)90108-9
10.1103/PhysRevLett.53.2429
10.1002/jrs.1540
10.1016/j.jnoncrysol.2007.01.039
{'key': 'e_1_2_7_17_2', 'first-page': '686', 'volume': '67', 'author': 'Mysen B. O.', 'year': '1982', 'journal-title': 'Am. Mineral.'} / Am. Mineral. by Mysen B. O. (1982)
10.1016/j.chemgeo.2006.01.008
10.1016/j.jnoncrysol.2006.12.015
10.1016/0009-2541(95)00161-1
10.1016/S0022-3093(03)00303-X
10.1111/j.1551-2916.2005.00096.x
10.1016/j.culher.2008.06.005
10.1016/S0022-3093(01)00577-4
10.1063/1.1800971
10.2138/am.2008.2783
10.1016/j.jnoncrysol.2007.06.031
10.1002/jrs.2338
10.1016/j.jnoncrysol.2007.06.033
10.1016/0378-4371(93)90440-F
10.1016/0022-3093(94)90338-7
{'key': 'e_1_2_7_32_2', 'volume-title': 'Silicate Glasses and Melts: Properties and Structure', 'author': 'Mysen B. O.', 'year': '2005'} / Silicate Glasses and Melts: Properties and Structure by Mysen B. O. (2005)
{'key': 'e_1_2_7_33_2', 'first-page': '17', 'volume': '45', 'author': 'Pouchou J.‐L.', 'year': '1984', 'journal-title': 'J. Phys. (Paris), Colloque'} / J. Phys. (Paris), Colloque by Pouchou J.‐L. (1984)
10.1002/jrs.1894
{'key': 'e_1_2_7_35_2', 'author': 'Henderson G. S.', 'year': '2010', 'journal-title': 'J. Non‐Cryst. Solids'} / J. Non‐Cryst. Solids by Henderson G. S. (2010)
{'key': 'e_1_2_7_36_2', 'first-page': '258', 'volume': '77', 'author': 'Kubicki J. D.', 'year': '1992', 'journal-title': 'Am. Mineral.'} / Am. Mineral. by Kubicki J. D. (1992)
10.1016/0022-3093(89)90019-7
10.1016/0022-3093(91)90400-Z
10.1016/0022-3093(77)90009-6
10.1016/0022-3093(90)90243-F
10.1103/PhysRevB.72.064206
10.1016/S0022-3093(98)00838-2
10.1103/PhysRevB.17.1928
10.1016/S0022-3093(03)00013-9
10.1063/1.2360275
10.1103/PhysRevLett.80.5145
10.1103/PhysRevLett.90.036401
10.1007/s00269-008-0273-z
10.1209/epl/i2003-10286-8
10.1016/j.chemgeo.2004.08.049
{'key': 'e_1_2_7_51_2', 'first-page': '15723', 'volume': '113', 'author': 'Pedone A.', 'year': '2009', 'journal-title': 'J. Phys. Chem.'} / J. Phys. Chem. by Pedone A. (2009)
10.1016/0022-3093(95)00188-3
{'key': 'e_1_2_7_53_2', 'first-page': '8', 'volume': '76', 'author': 'Xue X.', 'year': '1991', 'journal-title': 'Am. Mineral.'} / Am. Mineral. by Xue X. (1991)
10.1016/j.jnoncrysol.2003.09.012
10.1007/s100510050079
10.1016/S0022-3093(02)01549-1
10.1007/s002690050190
10.1016/0022-3093(95)00634-6
10.1063/1.441703
10.1063/1.447455
10.1103/PhysRevLett.57.747
10.1063/1.1618351
10.1016/j.jnoncrysol.2004.04.014
10.1016/j.jnoncrysol.2006.11.028

Dates

Type	When
Created	15 years, 1 month ago (July 20, 2010, 12:20 a.m.)
Deposited	1 year, 10 months ago (Oct. 9, 2023, 7:55 p.m.)
Indexed	1 year ago (Aug. 29, 2024, 1:49 p.m.)
Issued	14 years, 5 months ago (April 1, 2011)
Published	14 years, 5 months ago (April 1, 2011)
Published Online	14 years, 4 months ago (April 19, 2011)
Published Print	14 years, 5 months ago (April 1, 2011)

Funders 0

None

BibTeX

@article{Trcera_2011, title={Structural study of Mg‐bearing sodosilicate glasses by Raman spectroscopy}, volume={42}, ISSN={1097-4555}, url={http://dx.doi.org/10.1002/jrs.2763}, DOI={10.1002/jrs.2763}, number={4}, journal={Journal of Raman Spectroscopy}, publisher={Wiley}, author={Trcera, Nicolas and Rossano, Stéphanie and Tarrida, Martine}, year={2011}, month=apr, pages={765–772} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2024,
        8,
        29
      ]
    ],
    "date-time": "2024-08-29T17:49:11Z",
    "timestamp": 1724953751771
  },
  "reference-count": 63,
  "publisher": "Wiley",
  "issue": "4",
  "license": [
    {
      "start": {
        "date-parts": [
          [
            2011,
            4,
            19
          ]
        ],
        "date-time": "2011-04-19T00:00:00Z",
        "timestamp": 1303171200000
      },
      "content-version": "vor",
      "delay-in-days": 18,
      "URL": "http://onlinelibrary.wiley.com/termsAndConditions#vor"
    }
  ],
  "content-domain": {
    "domain": [],
    "crossmark-restriction": false
  },
  "published-print": {
    "date-parts": [
      [
        2011,
        4
      ]
    ]
  },
  "abstract": "<jats:title>Abstract</jats:title><jats:p>The presence of magnesium in glasses of geological, medical, and technological interests influences their physicochemical and durability properties. However, the understanding of the role of magnesium is dependent on the combined knowledge of the structural environment of magnesium in the glass or melt and of the silicate network connectivity of the studied systems. In this article, we present a Raman spectroscopic study of the network connectivity of 10 ternary silicate glasses in the system Na<jats:sub>2</jats:sub>O\uf8ffMgO\uf8ffSiO<jats:sub>2</jats:sub> and one Mg\u2010free binary silicate glass Na<jats:sub>2</jats:sub>O\uf8ffSiO<jats:sub>2</jats:sub>. Results obtained at constant polymerization suggest the existence of various Q<jats:sup><jats:italic>n</jats:italic></jats:sup> units according to the nature of the modifying cation. As polymerization decreases for Na<jats:sub>2</jats:sub>O\uf8ffMgO\uf8ff\u03b1SiO<jats:sub>2</jats:sub> glasses (labeled as NMS\u03b1 with \u03b1 decreasing from 10 to 2), the band associated with Si\uf8ffO\uf8ffSi bending in fully polymerized region disappears being gradually replaced by a band attributed to Si\uf8ffO\uf8ffSi bending in region containing mainly Q<jats:sup>2</jats:sup> and Q<jats:sup>3</jats:sup> species. For highly polymerized glasses (NMS10\u2010NMS4), the coexistence of these two bands suggests the presence of two interconnected networks. Concomitantly, the signal associated with Q<jats:sup>3</jats:sup> species first increases. For a further decrease of the polymerization, the high wavenumber part of the signal associated with Q<jats:sup>3</jats:sup> species decreases, while the intensity of the high wavenumber part of the band related to Q<jats:sup>2</jats:sup> species increases. This result strongly suggests that magnesium charge\u2010balances preferentially Q<jats:sup>2</jats:sup> species rather than Q<jats:sup>3</jats:sup> species. Copyright \u00a9 2010 John Wiley &amp; Sons, Ltd.</jats:p>",
  "DOI": "10.1002/jrs.2763",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2010,
        7,
        20
      ]
    ],
    "date-time": "2010-07-20T04:20:47Z",
    "timestamp": 1279599647000
  },
  "page": "765-772",
  "source": "Crossref",
  "is-referenced-by-count": 33,
  "title": "Structural study of Mg\u2010bearing sodosilicate glasses by Raman spectroscopy",
  "prefix": "10.1002",
  "volume": "42",
  "author": [
    {
      "given": "Nicolas",
      "family": "Trcera",
      "sequence": "first",
      "affiliation": []
    },
    {
      "given": "St\u00e9phanie",
      "family": "Rossano",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "Martine",
      "family": "Tarrida",
      "sequence": "additional",
      "affiliation": []
    }
  ],
  "member": "311",
  "published-online": {
    "date-parts": [
      [
        2011,
        4,
        19
      ]
    ]
  },
  "reference": [
    {
      "key": "e_1_2_7_2_2",
      "first-page": "21",
      "volume": "32",
      "author": "Dingwell D. B.",
      "year": "1995",
      "journal-title": "Rev. Mineral."
    },
    {
      "key": "e_1_2_7_3_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/j.apgeochem.2006.03.010"
    },
    {
      "key": "e_1_2_7_4_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1007/BF00705272"
    },
    {
      "key": "e_1_2_7_5_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.2109/jcersj.114.82"
    },
    {
      "key": "e_1_2_7_6_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/S0169-4332(03)00179-X"
    },
    {
      "key": "e_1_2_7_7_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1063/1.431671"
    },
    {
      "key": "e_1_2_7_8_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1063/1.442472"
    },
    {
      "key": "e_1_2_7_9_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0022-3093(83)90032-7"
    },
    {
      "key": "e_1_2_7_10_2",
      "first-page": "622",
      "volume": "69",
      "author": "McMillan P. F.",
      "year": "1984",
      "journal-title": "Am. Mineral."
    },
    {
      "key": "e_1_2_7_11_2",
      "first-page": "645",
      "volume": "69",
      "author": "McMillan P. F.",
      "year": "1984",
      "journal-title": "Am. Mineral."
    },
    {
      "key": "e_1_2_7_12_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1007/BF00307725"
    },
    {
      "key": "e_1_2_7_13_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0022-3093(82)90108-9"
    },
    {
      "key": "e_1_2_7_14_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1103/PhysRevLett.53.2429"
    },
    {
      "key": "e_1_2_7_15_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/jrs.1540"
    },
    {
      "key": "e_1_2_7_16_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/j.jnoncrysol.2007.01.039"
    },
    {
      "key": "e_1_2_7_17_2",
      "first-page": "686",
      "volume": "67",
      "author": "Mysen B. O.",
      "year": "1982",
      "journal-title": "Am. Mineral."
    },
    {
      "key": "e_1_2_7_18_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/j.chemgeo.2006.01.008"
    },
    {
      "key": "e_1_2_7_19_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/j.jnoncrysol.2006.12.015"
    },
    {
      "key": "e_1_2_7_20_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0009-2541(95)00161-1"
    },
    {
      "key": "e_1_2_7_21_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/S0022-3093(03)00303-X"
    },
    {
      "key": "e_1_2_7_22_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1111/j.1551-2916.2005.00096.x"
    },
    {
      "key": "e_1_2_7_23_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/j.culher.2008.06.005"
    },
    {
      "key": "e_1_2_7_24_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/S0022-3093(01)00577-4"
    },
    {
      "key": "e_1_2_7_25_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1063/1.1800971"
    },
    {
      "key": "e_1_2_7_26_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.2138/am.2008.2783"
    },
    {
      "key": "e_1_2_7_27_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/j.jnoncrysol.2007.06.031"
    },
    {
      "key": "e_1_2_7_28_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/jrs.2338"
    },
    {
      "key": "e_1_2_7_29_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/j.jnoncrysol.2007.06.033"
    },
    {
      "key": "e_1_2_7_30_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0378-4371(93)90440-F"
    },
    {
      "key": "e_1_2_7_31_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0022-3093(94)90338-7"
    },
    {
      "key": "e_1_2_7_32_2",
      "volume-title": "Silicate Glasses and Melts: Properties and Structure",
      "author": "Mysen B. O.",
      "year": "2005"
    },
    {
      "key": "e_1_2_7_33_2",
      "first-page": "17",
      "volume": "45",
      "author": "Pouchou J.\u2010L.",
      "year": "1984",
      "journal-title": "J. Phys. (Paris), Colloque"
    },
    {
      "key": "e_1_2_7_34_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/jrs.1894"
    },
    {
      "key": "e_1_2_7_35_2",
      "author": "Henderson G. S.",
      "year": "2010",
      "journal-title": "J. Non\u2010Cryst. Solids"
    },
    {
      "key": "e_1_2_7_36_2",
      "first-page": "258",
      "volume": "77",
      "author": "Kubicki J. D.",
      "year": "1992",
      "journal-title": "Am. Mineral."
    },
    {
      "key": "e_1_2_7_37_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0022-3093(89)90019-7"
    },
    {
      "key": "e_1_2_7_38_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0022-3093(91)90400-Z"
    },
    {
      "key": "e_1_2_7_39_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0022-3093(77)90009-6"
    },
    {
      "key": "e_1_2_7_40_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0022-3093(90)90243-F"
    },
    {
      "key": "e_1_2_7_41_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1103/PhysRevB.72.064206"
    },
    {
      "key": "e_1_2_7_42_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/S0022-3093(98)00838-2"
    },
    {
      "key": "e_1_2_7_43_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1103/PhysRevB.17.1928"
    },
    {
      "key": "e_1_2_7_44_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/S0022-3093(03)00013-9"
    },
    {
      "key": "e_1_2_7_45_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1063/1.2360275"
    },
    {
      "key": "e_1_2_7_46_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1103/PhysRevLett.80.5145"
    },
    {
      "key": "e_1_2_7_47_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1103/PhysRevLett.90.036401"
    },
    {
      "key": "e_1_2_7_48_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1007/s00269-008-0273-z"
    },
    {
      "key": "e_1_2_7_49_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1209/epl/i2003-10286-8"
    },
    {
      "key": "e_1_2_7_50_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/j.chemgeo.2004.08.049"
    },
    {
      "key": "e_1_2_7_51_2",
      "first-page": "15723",
      "volume": "113",
      "author": "Pedone A.",
      "year": "2009",
      "journal-title": "J. Phys. Chem."
    },
    {
      "key": "e_1_2_7_52_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0022-3093(95)00188-3"
    },
    {
      "key": "e_1_2_7_53_2",
      "first-page": "8",
      "volume": "76",
      "author": "Xue X.",
      "year": "1991",
      "journal-title": "Am. Mineral."
    },
    {
      "key": "e_1_2_7_54_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/j.jnoncrysol.2003.09.012"
    },
    {
      "key": "e_1_2_7_55_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1007/s100510050079"
    },
    {
      "key": "e_1_2_7_56_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/S0022-3093(02)01549-1"
    },
    {
      "key": "e_1_2_7_57_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1007/s002690050190"
    },
    {
      "key": "e_1_2_7_58_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0022-3093(95)00634-6"
    },
    {
      "key": "e_1_2_7_59_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1063/1.441703"
    },
    {
      "key": "e_1_2_7_60_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1063/1.447455"
    },
    {
      "key": "e_1_2_7_61_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1103/PhysRevLett.57.747"
    },
    {
      "key": "e_1_2_7_62_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1063/1.1618351"
    },
    {
      "key": "e_1_2_7_63_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/j.jnoncrysol.2004.04.014"
    },
    {
      "key": "e_1_2_7_64_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/j.jnoncrysol.2006.11.028"
    }
  ],
  "container-title": "Journal of Raman Spectroscopy",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fjrs.2763",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "text-mining"
    },
    {
      "URL": "https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fjrs.2763",
      "content-type": "application/pdf",
      "content-version": "vor",
      "intended-application": "text-mining"
    },
    {
      "URL": "http://onlinelibrary.wiley.com/wol1/doi/10.1002/jrs.2763/fullpdf",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2023,
        10,
        9
      ]
    ],
    "date-time": "2023-10-09T23:55:26Z",
    "timestamp": 1696895726000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://analyticalsciencejournals.onlinelibrary.wiley.com/doi/10.1002/jrs.2763"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        2011,
        4
      ]
    ]
  },
  "references-count": 63,
  "journal-issue": {
    "issue": "4",
    "published-print": {
      "date-parts": [
        [
          2011,
          4
        ]
      ]
    }
  },
  "alternative-id": [
    "10.1002/jrs.2763"
  ],
  "URL": "http://dx.doi.org/10.1002/jrs.2763",
  "relation": {},
  "ISSN": [
    "0377-0486",
    "1097-4555"
  ],
  "subject": [],
  "container-title-short": "J Raman Spectroscopy",
  "published": {
    "date-parts": [
      [
        2011,
        4
      ]
    ]
  }
}