DOI: 10.1002/jrs.1874. Raman spectroscopy of Bi‐Te thin films

10.1002/jrs.1874

Crossref journal-article

Wiley

Journal of Raman Spectroscopy (311)

Abstract

AbstractThe deposition of micro‐ and nanocrystalline bismuth telluride thin films with tailored structure and composition is of interest in view of improving the well‐known material thermoelectric properties. Only a few works exist that discuss Raman scattering of Bi2Te3 crystals and films, while a Raman characterization of other phases, i.e. other lesser known compounds of the Bi‐Te system, such as tsumoite (BiTe) and pilsenite (Bi4Te3), is still completely lacking. We here present a Raman investigation of Bi‐Te polycrystalline thin films with controlled structure (stoichiometry and growth orientation), morphology and phase composition, produced by nanosecond pulsed laser deposition. Interpretation of Raman spectra from Bi‐Te films was supported by scanning electron microscopy, energy dispersive spectroscopy (EDS) and X‐Ray diffraction measurements, together with the predictions of the group theory. In this way, the first Raman characterization of Bi‐rich phases (namely BiTe and Bi4Te3) has been obtained. For Bi‐Te compositions characterized by a high Bi or Te content, Raman spectra reveal that segregation of elemental Bi or Te occurs. Copyright © 2008 John Wiley & Sons, Ltd.

Bibliography

Russo, V., Bailini, A., Zamboni, M., Passoni, M., Conti, C., Casari, C. S., Li Bassi, A., & Bottani, C. E. (2008). Raman spectroscopy of BiâTe thin films. Journal of Raman Spectroscopy, 39(2), 205â210. Portico.

Authors 8

V. Russo (first)
A. Bailini (additional)
M. Zamboni (additional)
M. Passoni (additional)
C. Conti (additional)
C. S. Casari (additional)
A. Li Bassi (additional)
C. E. Bottani (additional)

References 25 Referenced 115

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YamasakiI YamanakaR MikamiM SonobeH MoriY SasakiT.Proc. 17th International Conference on Thermoelectrics Nagoya 1998;210.
10.1007/BF01490284
10.1088/0508-3443/9/10/307
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{'key': 'e_1_2_1_14_2', 'first-page': '655', 'volume': '8', 'author': 'Stasova MM', 'year': '1967', 'journal-title': 'Zh. Strukt. Khim.'} / Zh. Strukt. Khim. by Stasova MM (1967)
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{'key': 'e_1_2_1_21_2', 'first-page': 'F03', 'volume': '886', 'author': 'Craps M', 'year': '2006', 'journal-title': 'Mater. Res. Soc. Symp. Proc.'} / Mater. Res. Soc. Symp. Proc. by Craps M (2006)
10.1103/PhysRevB.75.195203
{'key': 'e_1_2_1_23_2', 'volume-title': 'Pulsed Laser Deposition of Thin Films', 'author': 'Chrisey DB', 'year': '1994'} / Pulsed Laser Deposition of Thin Films by Chrisey DB (1994)
10.1002/jrs.1250100152
10.1103/PhysRevB.60.10080
10.1103/PhysRevB.4.356

Dates

Type	When
Created	17 years, 7 months ago (Jan. 18, 2008, 8 a.m.)
Deposited	1 year, 11 months ago (Sept. 10, 2023, 10:35 p.m.)
Indexed	1 week, 2 days ago (Aug. 23, 2025, 1:03 a.m.)
Issued	17 years, 7 months ago (Jan. 18, 2008)
Published	17 years, 7 months ago (Jan. 18, 2008)
Published Online	17 years, 7 months ago (Jan. 18, 2008)
Published Print	17 years, 7 months ago (Feb. 1, 2008)

Funders 0

None

BibTeX

@article{Russo_2008, title={Raman spectroscopy of Bi‐Te thin films}, volume={39}, ISSN={1097-4555}, url={http://dx.doi.org/10.1002/jrs.1874}, DOI={10.1002/jrs.1874}, number={2}, journal={Journal of Raman Spectroscopy}, publisher={Wiley}, author={Russo, V. and Bailini, A. and Zamboni, M. and Passoni, M. and Conti, C. and Casari, C. S. and Li Bassi, A. and Bottani, C. E.}, year={2008}, month=jan, pages={205–210} }

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