DOI: 10.1002/jrs.1250240103. Resonance Raman spectra of the S<sub>3</sub> molecule in sulphur vapour

Resonance Raman spectra of the S3 molecule in sulphur vapour

10.1002/jrs.1250240103

Crossref journal-article

Wiley

Journal of Raman Spectroscopy (311)

Abstract

AbstractSulphur vapour was investigated by Raman spectroscopy using six laser excitation wavelengths located in the electronic absorption band of the S3 molecule (406.7–514.5 nm). With excitation wavelengths close to the S3 λmax (395 nm) the spectra are mainly resonance enhanced. With the excitation located in the S3 electronic absorption band edge the observed resonance Raman spectra are mainly due to the vibrationally excited molecules. Most Raman lines involve transitions between overtone or combination levels of the symmetric stretching (ν1) and symmetric bending (ν2) modes. The comparison of spectra of samples with various 34S contents recorded with various excitation wavelengths enable us to determine the ω10 and ω20 harmonic wavenumbers and the anharmonicity constants x x and x, for 32S3 and 34S3. New assignments are proposed for all Raman lines observed. A valence force field treatment with the calculated geometry rss = 1.988 Å and α = 117° yields force constants ƒr = 3.91 mdyn Å−1 and ƒrr = 0.36 mdyn Å−1. These force constants are compared with those of the parent X2 or X3 molecules (X = O, S, Se or Te).

Bibliography

Picquenard, E., El Jaroudi, O., & Corset, J. (1993). Resonance Raman spectra of the S3 molecule in sulphur vapour. Journal of Raman Spectroscopy, 24(1), 11â19. Portico.

Authors 3

E. Picquenard (first)
O. El Jaroudi (additional)
J. Corset (additional)

References 41 Referenced 18

Science 1979 203 (10.1126/science.203.4379.417.a)
Science 1979 205 4401
10.1021/cr60301a003
10.1007/3-540-11345-2_10
10.1016/B978-0-444-42355-9.50006-2
{'key': 'e_1_2_1_4_2', 'first-page': '600', 'volume': '18', 'author': "San'ko N. F.", 'year': '1980', 'journal-title': 'Kosm. Issled.'} / Kosm. Issled. by San'ko N. F. (1980)
{'key': 'e_1_2_1_4_3', 'first-page': '572', 'volume': '20', 'author': 'Golovin Y. M.', 'year': '1982', 'journal-title': 'Kosm. Issled.'} / Kosm. Issled. by Golovin Y. M. (1982)
{'key': 'e_1_2_1_4_4', 'first-page': '254', 'volume': '21', 'author': 'Ekonomov A. P.', 'year': '1983', 'journal-title': 'Kosm. Issled.'} / Kosm. Issled. by Ekonomov A. P. (1983)
{'key': 'e_1_2_1_4_5', 'first-page': '236', 'volume': '21', 'author': 'Ekonomov E. P.', 'year': '1983', 'journal-title': 'Kosm. Issled.'} / Kosm. Issled. by Ekonomov E. P. (1983)
10.1016/0273-1177(87)90198-0
10.1016/S0021-9614(73)80045-X
10.1063/1.89394
10.1063/1.91587
in 1980 Proceedings of European Conference on Optical Systems and Applications (SPIE Vol. 326) p.345. SPIE Beilingham (1981).
{'key': 'e_1_2_1_9_2', 'first-page': '659', 'volume-title': 'Raman Spectroscopy, Linear and Non‐Linear', 'author': 'Schinazi M.', 'year': '1982'} / Raman Spectroscopy, Linear and Non‐Linear by Schinazi M. (1982)
{'key': 'e_1_2_1_10_2', 'first-page': '450', 'volume-title': 'Proceedings of IXth International Conference on Raman Spectroscopy', 'author': 'Lenain P.', 'year': '1984'} / Proceedings of IXth International Conference on Raman Spectroscopy by Lenain P. (1984)
P.Lenain Thèse de Doctorat de Troisième Cycle Université Paris XI Orsay (1985).
10.1002/bbpc.198800210
10.1016/0022-2852(72)90089-6
10.1002/bbpc.197800123
10.1016/0047-2670(85)85030-9
10.1016/0019-1035(88)90111-X
10.1021/ja00792a007
10.1021/ic50153a055
10.1016/0022-2860(86)85132-8
10.1021/j100154a019
O.El Jaroudi Thèse de Doctorat Université P. & M. Curie Paris (1990).
O.El Jaroudi E.PicquenardandJ.Corset to be published.
10.1007/BFb0116561
10.1002/anie.198601311
{'key': 'e_1_2_1_24_2', 'volume-title': 'Molecular Spectra and Molecular Structure: II. Infrared and Raman Spectra of Polyatomic Molecules', 'author': 'Herzberg G.', 'year': '1964'} / Molecular Spectra and Molecular Structure: II. Infrared and Raman Spectra of Polyatomic Molecules by Herzberg G. (1964)
E.PicquenardandM. S.Boumédien to be published.
10.1016/0022-2852(74)90267-7
10.1063/1.1698806
10.1021/j100660a017
10.1139/v85-328
10.1063/1.451253
10.1021/j100666a018
10.1002/zaac.19824940109
10.1002/zaac.19845100311
10.1007/978-1-4757-0961-2_2

Dates

Type	When
Created	20 years, 3 months ago (May 28, 2005, 3:57 p.m.)
Deposited	1 year, 10 months ago (Oct. 25, 2023, 1:10 p.m.)
Indexed	1 year, 6 months ago (Feb. 10, 2024, 9:58 p.m.)
Issued	32 years, 8 months ago (Jan. 1, 1993)
Published	32 years, 8 months ago (Jan. 1, 1993)
Published Online	20 years, 4 months ago (April 14, 2005)
Published Print	32 years, 8 months ago (Jan. 1, 1993)

Funders 0

None

BibTeX

@article{Picquenard_1993, title={Resonance Raman spectra of the S3 molecule in sulphur vapour}, volume={24}, ISSN={1097-4555}, url={http://dx.doi.org/10.1002/jrs.1250240103}, DOI={10.1002/jrs.1250240103}, number={1}, journal={Journal of Raman Spectroscopy}, publisher={Wiley}, author={Picquenard, E. and El Jaroudi, O. and Corset, J.}, year={1993}, month=jan, pages={11–19} }

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