Surface‐enhanced Raman scattering of adsorbates
10.1002/jrs.1250221204
Crossref journal-article
Wiley
Journal of Raman Spectroscopy (311)
Abstract

AbstractThis review concentrates on the electronic contribution to surface‐enhanced Raman scattering (SERS). This socalled ‘chemical effect’ is quantitatively separated from classical electromagnetic enhancement. It proceeds by increased electron‐photon coupling at an atomically rough surface and by temporary charge transfer to adsorbate orbitals. These concepts are supported by various experimental results. The model accounts for the chemical specificity and vibrational selectivity of SERS and (partly) for the ‘SERS specificity’ of various metals.

Bibliography

Otto, A. (1991). Surface‐enhanced Raman scattering of adsorbates. Journal of Raman Spectroscopy, 22(12), 743–752. Portico.

Authors 1
  1. A. Otto (first)
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Dates
Type When
Created 20 years, 3 months ago (May 28, 2005, 3:47 p.m.)
Deposited 1 year, 10 months ago (Oct. 22, 2023, 6:56 p.m.)
Indexed 4 months, 2 weeks ago (April 18, 2025, 12:06 a.m.)
Issued 33 years, 9 months ago (Dec. 1, 1991)
Published 33 years, 9 months ago (Dec. 1, 1991)
Published Online 20 years, 4 months ago (April 12, 2005)
Published Print 33 years, 9 months ago (Dec. 1, 1991)
Funders 0

None

@article{Otto_1991, title={Surface‐enhanced Raman scattering of adsorbates}, volume={22}, ISSN={1097-4555}, url={http://dx.doi.org/10.1002/jrs.1250221204}, DOI={10.1002/jrs.1250221204}, number={12}, journal={Journal of Raman Spectroscopy}, publisher={Wiley}, author={Otto, A.}, year={1991}, month=dec, pages={743–752} }