DOI: 10.1002/jrs.1250190606. Temperature study of intra‐ and inter‐molecular coupling and Fermi resonance constants in the Raman spectra of liquid water using Fourier deconvolution

Temperature study of intra‐ and inter‐molecular coupling and Fermi resonance constants in the Raman spectra of liquid water using Fourier deconvolution

10.1002/jrs.1250190606

Crossref journal-article

Wiley

Journal of Raman Spectroscopy (311)

Abstract

AbstractThe structure of the Raman OH stretching band of water has been investigated from 4 to 90 °C using a Fourier deconvolution technique. The overlapped components in the isotropic and anisotropic spectra have been resolved. The information on the positions of the components in the deconvoluted spectra was used for calculation of the constants for intra‐ and inter‐molecular coupling and Fermi resonance and for an estimation of the component frequencies according to the model presented. For the first time, the value of the asymmetric Fermi resonance constant and the temperature dependences of all coupling constants have been obtained. Their temperature behaviour is in good agreement with the data in the literature concerning the different phases of water. It was established that the intramolecular coupling constant increases and the intermolecular coupling constant decreases as the temperature increases. The Fermi resonance constant for symmetric components tends to decrease with increasing temperature. The decrease in the symmetric Fermi resonance interaction with increasing temperature is due to the increase in the distance between the unperturbed fundamental and overtone band positions. The asymmetric Fermi resonance constant tends to increase with increasing temperature and this determines the strengthening of the asymmetric Fermi resonance interaction, which exhibits a limiting value at high temperatures.

Bibliography

Zhelyaskov, V., Georgiev, G., & Nickolov, Zh. (1988). Temperature study of intraâ and interâmolecular coupling and Fermi resonance constants in the Raman spectra of liquid water using Fourier deconvolution. Journal of Raman Spectroscopy, 19(6), 405â412. Portico.

Authors 3

V. Zhelyaskov (first)
G. Georgiev (additional)
Zh. Nickolov (additional)

References 32 Referenced 43

{'key': 'e_1_2_1_2_2', 'volume-title': 'The Structure and Properties of Water', 'author': 'Eisenberg D.', 'year': '1969'} / The Structure and Properties of Water by Eisenberg D. (1969)
{'key': 'e_1_2_1_3_2', 'volume-title': 'Water, A Comprehensive Treatise', 'author': 'Franks F.', 'year': '1972'} / Water, A Comprehensive Treatise by Franks F. (1972)
{'key': 'e_1_2_1_4_2', 'first-page': '149', 'volume-title': 'Advances in Infrared and Raman Spectroscopy', 'author': 'Sherer J. R.', 'year': '1978'} / Advances in Infrared and Raman Spectroscopy by Sherer J. R. (1978)
10.1002/jrs.1250170202
10.1080/00268977800102101
10.1002/jrs.1250170409
10.1002/jrs.1250170107
10.1063/1.438389
10.1139/v77-481
10.1063/1.445416
10.1366/0003702814732634
10.1364/AO.20.001866
10.1366/0003702834634271
10.1366/0003702834634244
10.1080/00387018308062387
10.1016/0022-2860(84)80100-3
10.1063/1.2140498
10.1063/1.1673629
10.1021/j100606a013
10.1021/ac60363a029
10.1021/j100222a013
10.1063/1.1711834
{'key': 'e_1_2_1_22_2', 'volume-title': 'Raman Spectroscopy', 'author': 'Long D. A.', 'year': '1977'} / Raman Spectroscopy by Long D. A. (1977)
10.1021/j100652a010
10.1016/0022-2860(81)80066-X
10.1515/zpch-1985-26685 / Z. Phys. Chem. (Leipzig) by Kabish G. (1985)
10.2307/807002
10.1063/1.1742731
{'key': 'e_1_2_1_28_2', 'first-page': '142', 'volume': '43', 'author': 'Josien M.', 'year': '1967', 'journal-title': 'Discuss. Faraday Soc.'} / Discuss. Faraday Soc. by Josien M. (1967)
10.1016/0584-8539(72)80234-4
10.1021/j100873a045
10.1007/BFb0116438

Dates

Type	When
Created	20 years, 2 months ago (May 28, 2005, 3:35 p.m.)
Deposited	1 year, 10 months ago (Oct. 21, 2023, 12:48 a.m.)
Indexed	11 months, 1 week ago (Sept. 14, 2024, 9:22 a.m.)
Issued	36 years, 11 months ago (Sept. 1, 1988)
Published	36 years, 11 months ago (Sept. 1, 1988)
Published Online	20 years, 4 months ago (April 14, 2005)
Published Print	36 years, 11 months ago (Sept. 1, 1988)

Funders 0

None

BibTeX

@article{Zhelyaskov_1988, title={Temperature study of intra‐ and inter‐molecular coupling and Fermi resonance constants in the Raman spectra of liquid water using Fourier deconvolution}, volume={19}, ISSN={1097-4555}, url={http://dx.doi.org/10.1002/jrs.1250190606}, DOI={10.1002/jrs.1250190606}, number={6}, journal={Journal of Raman Spectroscopy}, publisher={Wiley}, author={Zhelyaskov, V. and Georgiev, G. and Nickolov, Zh.}, year={1988}, month=sep, pages={405–412} }

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