DOI: 10.1002/jrs.1250170131. High‐resolution Raman investigation of the vibrational relaxation of two‐phonon bound states in solid CO<sub>2</sub> at different temperatures

High‐resolution Raman investigation of the vibrational relaxation of two‐phonon bound states in solid CO2 at different temperatures

10.1002/jrs.1250170131

Crossref journal-article

Wiley

Journal of Raman Spectroscopy (311)

Abstract

AbstractThe Raman spectra of the bound states Ω+ and Ω− of the Fermi diad ω1:2ω2 in crystalline CO2 have been measured at several temperatures under very high resolution. Band profiles have been determined for each of the two factor group components, one Ag and one Fg, of the two states.The evolution with temperature of the bandwidths has been interpreted in terms of four‐phonon decay processes. A single down‐process, involving a lattice phonon at 60 cm−1, is shown to be sufficient to reproduce the experimental data for the Ω+ state. In the same way, a single up‐process, involving the same lattice phonon, is sufficient to fit the experimental data for the Ω− state. The variation of the factor group splitting of the Ω− component as a function of temperature has also been determined.

Bibliography

Ranson, P., Ouillon, R., & Califano, S. (1986). Highâresolution Raman investigation of the vibrational relaxation of twoâphonon bound states in solid CO2 at different temperatures. Journal of Raman Spectroscopy, 17(1), 155â159. Portico.

Authors 3

P. Ranson (first)
R. Ouillon (additional)
S. Califano (additional)

References 18 Referenced 33

{'key': 'e_1_2_1_2_2', 'volume-title': 'Crystal Structures', 'author': 'Wycoff R. W. G.', 'year': '1960'} / Crystal Structures by Wycoff R. W. G. (1960)
10.1016/0009-2614(71)80086-6
10.1063/1.434229
10.1016/0009-2614(80)80385-X
10.1063/1.442183
10.1063/1.440012
10.1063/1.447484
10.1103/PhysRevLett.54.823
10.1051/jcp/1985820179
10.1063/1.449307
10.1051/jcp/1985820169 / J. Chim. Phys. by Ranson P. (1985)
10.1016/0301-0104(83)80021-4
10.1007/978-3-642-93186-4
10.1051/jcp/1985820137
{'key': 'e_1_2_1_11_2', 'first-page': '176', 'volume-title': 'Lattice Dynamics and Intermolecular Forces, Proceedings of the LV International School E. Fermi', 'author': 'Dolling G.', 'year': '1975'} / Lattice Dynamics and Intermolecular Forces, Proceedings of the LV International School E. Fermi by Dolling G. (1975)
{'key': 'e_1_2_1_11_3', 'first-page': '207', 'volume-title': 'Neutron Inelastic Scattering', 'author': 'Powell B. M.', 'year': '1972'} / Neutron Inelastic Scattering by Powell B. M. (1972)
10.1063/1.1679088
10.1016/0301-0104(84)80048-8

Dates

Type	When
Created	20 years, 2 months ago (May 28, 2005, 3:26 p.m.)
Deposited	1 year, 10 months ago (Oct. 21, 2023, noon)
Indexed	1 year, 6 months ago (Feb. 10, 2024, 9:27 a.m.)
Issued	39 years, 6 months ago (Feb. 1, 1986)
Published	39 years, 6 months ago (Feb. 1, 1986)
Published Online	20 years, 4 months ago (April 14, 2005)
Published Print	39 years, 6 months ago (Feb. 1, 1986)

Funders 0

None

BibTeX

@article{Ranson_1986, title={High‐resolution Raman investigation of the vibrational relaxation of two‐phonon bound states in solid CO2 at different temperatures}, volume={17}, ISSN={1097-4555}, url={http://dx.doi.org/10.1002/jrs.1250170131}, DOI={10.1002/jrs.1250170131}, number={1}, journal={Journal of Raman Spectroscopy}, publisher={Wiley}, author={Ranson, P. and Ouillon, R. and Califano, S.}, year={1986}, month=feb, pages={155–159} }

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