DOI: 10.1002/jrs.1250110516. Determination of anharmonicity constants from the Raman spectrum of gaseous acetylene

Determination of anharmonicity constants from the Raman spectrum of gaseous acetylene

10.1002/jrs.1250110516

Crossref journal-article

Wiley

Journal of Raman Spectroscopy (311)

Abstract

AbstractFrom an analysis of the photoelectrically recorded Raman band of acetylene at 3950 cm−1, which contains contributions from ν1+ν4 and its hot bands, ν3+ν5 in Fermi resonance with ν2+ν4+2ν5, and the Q‐branch of 2ν2, some anharmonicity constants were determined. In particular x22= −7.4 cm−1 was obtained directly for the first time, other constants are revised due to a more complete consideration of the resonance perturbations. A computer simulation of the ν4 fundamental and the ν1+ν4 combination band shows excellent agreement with the experimental spectra.

Bibliography

FinsterhÃ¶lzl, H., SchrÃ¶tter, H. W., & Strey, G. (1981). Determination of anharmonicity constants from the Raman spectrum of gaseous acetylene. Journal of Raman Spectroscopy, 11(5), 375â383. Portico.

Authors 3

H. Finsterhölzl (first)
H. W. Schrötter (additional)
G. Strey (additional)

References 27 Referenced 36

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{'key': 'e_1_2_1_5_2', 'first-page': '358', 'volume': '16', 'author': 'Wang I.‐Y.', 'year': '1978', 'journal-title': 'Indian J. Pure Appl. Phys.'} / Indian J. Pure Appl. Phys. by Wang I.‐Y. (1978)
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{'key': 'e_1_2_1_10_2', 'first-page': '944', 'volume': '9', 'author': 'Rich N. H.', 'year': '1971', 'journal-title': 'Indian J. Pure Appl. Phys.'} / Indian J. Pure Appl. Phys. by Rich N. H. (1971)
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{'key': 'e_1_2_1_17_2', 'first-page': '319', 'volume': '68', 'author': 'Ziegler E.', 'year': '1967', 'journal-title': 'österr, Chem. Z.'} / österr, Chem. Z. by Ziegler E. (1967)
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10.1515/zna-1972-0111 / Z. Naturforsch. Teil A by Altmann K. (1972)
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10.1016/0022-2852(66)90015-4
10.1016/0022-2852(72)90197-X
10.1016/0022-2852(79)90052-3

Dates

Type	When
Created	20 years, 3 months ago (May 28, 2005, 3:12 p.m.)
Deposited	1 year, 10 months ago (Oct. 16, 2023, 1:25 a.m.)
Indexed	1 year, 6 months ago (Feb. 11, 2024, 7:59 a.m.)
Issued	43 years, 10 months ago (Oct. 1, 1981)
Published	43 years, 10 months ago (Oct. 1, 1981)
Published Online	20 years, 4 months ago (April 14, 2005)
Published Print	43 years, 10 months ago (Oct. 1, 1981)

Funders 0

None

BibTeX

@article{Finsterh_lzl_1981, title={Determination of anharmonicity constants from the Raman spectrum of gaseous acetylene}, volume={11}, ISSN={1097-4555}, url={http://dx.doi.org/10.1002/jrs.1250110516}, DOI={10.1002/jrs.1250110516}, number={5}, journal={Journal of Raman Spectroscopy}, publisher={Wiley}, author={Finsterhölzl, H. and Schrötter, H. W. and Strey, G.}, year={1981}, month=oct, pages={375–383} }

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