DOI: 10.1002/jrs.1250020405. Resonance Raman scattering and vibronic coupling in aquo‐ and cyano‐cobalamin

Resonance Raman scattering and vibronic coupling in aquo‐ and cyano‐cobalamin

10.1002/jrs.1250020405

Crossref journal-article

Wiley

Journal of Raman Spectroscopy (311)

Abstract

AbstractThe resonance Raman spectra of cyano‐and aquocobalamin have been obtained from aqueous solutions. In order to check the vibronic theory of Raman intensity in the rigorous resonance case, the excitation profile of the 1502 cm−1 vibration was measured and analyzed using a model of two displaced harmonic oscillators for the ground and the resonant electronic state. A very good agreement is shown between the calculated and the experimental values of both the excitation profile and the absorption spectrum. Information on the corrin ring symmetry and evaluation of the vibronic interaction energies have been obtained. The appearance of several overtones and combinations is also reported.

Bibliography

Galluzzi, F., Garozzo, M., & Ricci, F. F. (1974). Resonance Raman scattering and vibronic coupling in aquoâ and cyanoâcobalamin. Journal of Raman Spectroscopy, 2(4), 351â362. Portico.

Authors 3

F. Galluzzi (first)
M. Garozzo (additional)
F. F. Ricci (additional)

References 32 Referenced 32

10.1007/978-1-4684-3027-1_2
{'key': 'e_1_2_1_3_2', 'volume-title': 'Raman Spectroscopy', 'author': 'Behringer J.', 'year': '1967'} / Raman Spectroscopy by Behringer J. (1967)
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10.1073/pnas.69.9.2622
10.1002/jrs.1250010411
10.1016/0009-2614(73)89520-X
10.1063/1.1701032
10.1007/BF00537510
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10.1016/0304-4165(73)90107-4
10.1039/f29736901350
10.1021/ja00791a065
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{'key': 'e_1_2_1_18_2', 'first-page': '341', 'volume': '20', 'author': 'Verlan E. M.', 'year': '1966', 'journal-title': 'Opt. Spectrosc.'} / Opt. Spectrosc. by Verlan E. M. (1966)
{'key': 'e_1_2_1_19_2', 'first-page': '63', 'volume-title': 'Physics of Color Centers', 'author': 'Fowler W. B.', 'year': '1968'} / Physics of Color Centers by Fowler W. B. (1968)
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10.1063/1.1712176
Pratt J. M.:J. Chem. Soc. 5154(1964). (10.1039/jr9640005154)
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{'key': 'e_1_2_1_24_2', 'volume-title': 'Infrared Spectra of Inorganic and Coordination Compounds', 'author': 'Nakamoto K.', 'year': '1963'} / Infrared Spectra of Inorganic and Coordination Compounds by Nakamoto K. (1963)
Powell D. B.andSheppard N.:J. Chem. Soc. 3108(1956). (10.1039/jr9560003108)
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10.1016/0005-2795(73)90004-4
10.1098/rspa.1968.0039

Dates

Type	When
Created	20 years, 3 months ago (May 28, 2005, 2:55 p.m.)
Deposited	1 year, 10 months ago (Oct. 18, 2023, 9:10 p.m.)
Indexed	1 year, 6 months ago (Feb. 9, 2024, 4:29 p.m.)
Issued	51 years, 1 month ago (Aug. 1, 1974)
Published	51 years, 1 month ago (Aug. 1, 1974)
Published Online	20 years, 4 months ago (April 12, 2005)
Published Print	51 years, 1 month ago (Aug. 1, 1974)

Funders 0

None

BibTeX

@article{Galluzzi_1974, title={Resonance Raman scattering and vibronic coupling in aquo‐ and cyano‐cobalamin}, volume={2}, ISSN={1097-4555}, url={http://dx.doi.org/10.1002/jrs.1250020405}, DOI={10.1002/jrs.1250020405}, number={4}, journal={Journal of Raman Spectroscopy}, publisher={Wiley}, author={Galluzzi, F. and Garozzo, M. and Ricci, F. F.}, year={1974}, month=aug, pages={351–362} }

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