DOI: 10.1002/ijch.198200065. Non‐Markoffian Theory of Activated Rate Processes II. Thermal Desorption

Non‐Markoffian Theory of Activated Rate Processes II. Thermal Desorption

10.1002/ijch.198200065

Crossref journal-article

Wiley

Israel Journal of Chemistry (311)

Abstract

AbstractA model for thermal desorption, described by a one dimensional classical generalized Langevin equation (GLE) for the motion of an adatom, is solved by reducing the GLE to a Fokker Planck equation in action space. The escape rate is obtained as the inverse mean first passage time for the particle to achieve a threshold energy (or action). A calculation using parameters corresponding to the desorption of Ar from W is compared with quantum mechanical results for the same model.

Bibliography

Nitzan, A., & Carmeli, B. (1982). NonâMarkoffian Theory of Activated Rate Processes II. Thermal Desorption. Israel Journal of Chemistry, 22(4), 360â364. Portico.

Authors 2

Abraham Nitzan (first)
Benny Carmeli (additional)

References 29 Referenced 10

10.1016/0079-6816(72)90005-6
10.1016/0079-6816(74)90002-1
10.1007/BFb0015587
10.1016/0039-6028(75)90302-7
10.1016/0039-6028(77)90339-9
10.1103/PhysRevB.11.2122
10.1016/0375-9601(75)90827-0
10.1007/BF00516917
10.1016/0375-9601(78)90391-2
68 297(1978);
10.1016/0039-6028(79)90019-0
10.1051/jphys:0197600370110131300
10.1088/0022-3719/11/12/013
10.1103/PhysRevB.18.545
10.1007/BF01327320
10.1016/0039-6028(77)90414-9
10.1063/1.1679299
10.1063/1.1679602
10.1007/BF01292657
10.1103/PhysRevB.21.3256
10.1016/0039-6028(82)90678-1
10.1016/0009-2614(80)85011-1
10.1016/0009-2614(81)80193-5
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10.1063/1.1724384
10.1103/PhysRevLett.49.423
10.1063/1.444277
10.1063/1.434249
For this calculation the steady‐state distribution was approximated by a Boltzmann equilibrium distribution in the well.

Dates

Type	When
Created	11 years, 9 months ago (Nov. 20, 2013, 11:49 p.m.)
Deposited	1 year, 11 months ago (Sept. 13, 2023, 8:52 a.m.)
Indexed	1 year, 6 months ago (Feb. 10, 2024, 1:21 a.m.)
Issued	43 years, 7 months ago (Jan. 1, 1982)
Published	43 years, 7 months ago (Jan. 1, 1982)
Published Online	11 years, 9 months ago (Nov. 20, 2013)
Published Print	43 years, 7 months ago (Jan. 1, 1982)

Funders 0

None

BibTeX

@article{Nitzan_1982, title={Non‐Markoffian Theory of Activated Rate Processes II. Thermal Desorption}, volume={22}, ISSN={1869-5868}, url={http://dx.doi.org/10.1002/ijch.198200065}, DOI={10.1002/ijch.198200065}, number={4}, journal={Israel Journal of Chemistry}, publisher={Wiley}, author={Nitzan, Abraham and Carmeli, Benny}, year={1982}, month=jan, pages={360–364} }

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