DOI: 10.1002/hlca.19630460404. Zur Kenntnis der sogenannten «Alkalicarbonyle» I Die Kristallstruktur des Kalium‐acetylendiolats, KOCCOK

Zur Kenntnis der sogenannten «Alkalicarbonyle» I Die Kristallstruktur des Kalium‐acetylendiolats, KOCCOK

10.1002/hlca.19630460404

Crossref journal-article

Wiley

Helvetica Chimica Acta (311)

Abstract

AbstractThe structure of the yellow «potassium carbonyl», obtained from CO and K in liquid ammonia, has been shown to be potassium acetylenediolate, KOCCOK. From X‐ray powder‐diagrams a tetragonal cell containing two KOCCOK units with a = 3.93, Å, c = 12.75 Å (space group I 4/mmm) has been derived. The KOCCOK units are arranged parallel to the c‐axis with the following internuclear distnaces: K0: 2.67 and 2.78 Å; KK: 3.65 Å; C0 : 1.28 Å; CC: 1.21 Å.

Bibliography

Weiss, E., & BÃ¼chner, W. (1963). Zur Kenntnis der sogenannten Â«AlkalicarbonyleÂ» I Die Kristallstruktur des Kaliumâacetylendiolats, KOCï£½COK. Helvetica Chimica Acta, 46(4), 1121â1127. Portico.

Authors 2

E. Weiss (first)
W. Büchner (additional)

References 19 Referenced 63

{'key': 'e_1_2_1_1_2', 'first-page': '182', 'volume': '11', 'year': '1834', 'journal-title': 'J. Liebig, Ann. Chem. Pharm.'} / J. Liebig, Ann. Chem. Pharm. (1834)
10.1002/jlac.18601130310
{'key': 'e_1_2_1_2_2', 'first-page': '1834', 'volume': '18', 'author': 'Nietzki R.', 'year': '1885', 'journal-title': 'Ber. deutsch. chem. Ges.'} / Ber. deutsch. chem. Ges. by Nietzki R. (1885)
{'key': 'e_1_2_1_3_2', 'first-page': '1818', 'volume': '206', 'author': 'Hackspill L.', 'year': '1938', 'journal-title': 'C. r. hebd. Séances Acad. Sci.'} / C. r. hebd. Séances Acad. Sci. by Hackspill L. (1938)
{'key': 'e_1_2_1_4_2', 'first-page': '874', 'volume': '158', 'author': 'Joannis A.', 'year': '1914', 'journal-title': 'C. r. hebd. Séances Acad. Sci.'} / C. r. hebd. Séances Acad. Sci. by Joannis A. (1914)
«Scotch Brand Tape» MINNESOTAMINING& MFG.CO.Die Klebschicht der 0 05 mm dicken Folien wurde an allen Stellen entfernt die mit dem Präparat in Berührung kamen.
SIEMENS‐Kristalloflex 4 SIEMENS‐Goniometer mit Szintillationszähler und Kompensograph.
Werte aus GUINIER‐Aufnahmen.
W. F.Sager A.Fatiadi P. C.Pars D. G.White&T. P.Perros J. inorg. nucl. Chemistry im Druck. Wir danken Herrn Prof. Perros für die Mitteilung der Ergebnisse.
10.1063/1.1749880
10.1002/zaac.19392410107
10.1107/S0365110X55001540
Intern. Tables for X‐Ray Crystallography Birmingham1952.
10.1107/S0365110X55001497
10.1107/S0365110X54002253
Die Aufnahmen wurden mit einer GUINIER‐DEWOLFF‐Kamera (ENRAF‐NONIUS Delft) angefertigt.
10.1002/bbpc.19340400811
10.1002/zaac.19572910104
10.1038/131166b0

Dates

Type	When
Created	20 years, 8 months ago (Dec. 23, 2004, 6:02 p.m.)
Deposited	1 year, 10 months ago (Oct. 19, 2023, 1:54 a.m.)
Indexed	1 year, 6 months ago (Feb. 11, 2024, 3:34 a.m.)
Issued	62 years, 8 months ago (Jan. 1, 1963)
Published	62 years, 8 months ago (Jan. 1, 1963)
Published Online	20 years, 10 months ago (Oct. 24, 2004)
Published Print	62 years, 8 months ago (Jan. 1, 1963)

Funders 0

None

BibTeX

@article{Weiss_1963, title={Zur Kenntnis der sogenannten «Alkalicarbonyle» I Die Kristallstruktur des Kalium‐acetylendiolats, KOCCOK}, volume={46}, ISSN={1522-2675}, url={http://dx.doi.org/10.1002/hlca.19630460404}, DOI={10.1002/hlca.19630460404}, number={4}, journal={Helvetica Chimica Acta}, publisher={Wiley}, author={Weiss, E. and Büchner, W.}, year={1963}, month=jan, pages={1121–1127} }

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