DOI: 10.1002/ep.10363. Oxide‐supported tetraethylenepentamine for CO<sub>2</sub> capture

Oxide‐supported tetraethylenepentamine for CO2 capture

10.1002/ep.10363

Crossref journal-article

Wiley

Environmental Progress & Sustainable Energy (311)

Abstract

AbstractCO2 capture capacity of tetraethylenepentamine (TEPA) supported on beta zeolite, SiO2, and Al2O3 has been studied by transient flow switching approach and temperature programmed desorption (TPD) technique coupled with diffuse infrared reflectance Fourier transform spectroscopy and mass spectrometry (MS). TEPA/beta zeolite shows the highest CO2 capture capacity. Adsorbed CO2 on TEPA/beta zeolite can be characterized as weakly and strongly adsorbed CO2. The former desorbs when CO2 partial pressure decreases; the latter desorbs during TPD. Strongly adsorbed CO2 is in the form of carbonates interacting with the NH functional groups of TEPA. This interaction caused the NH and CH intensity to decrease. TEPA/Al2O3 showed the lowest CO2 capture capacity. The infrared results revealed that TEPA/Al2O3 possessed high content of H2O, which inhibited CO2 adsorption. © 2009 American Institute of Chemical Engineers Environ Prog, 2009

Bibliography

Fisher, J. C., Tanthana, J., & Chuang, S. S. C. (2009). Oxideâsupported tetraethylenepentamine for CO2 capture. Environmental Progress & Sustainable Energy, 28(4), 589â598. Portico.

Authors 3

James C. Fisher (first)
Jak Tanthana (additional)
Steven S.C. Chuang (additional)

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Dates

Type	When
Created	16 years, 1 month ago (July 18, 2009, 2:24 a.m.)
Deposited	1 year, 10 months ago (Oct. 9, 2023, 3:32 p.m.)
Indexed	1 month ago (July 23, 2025, 8:09 a.m.)
Issued	15 years, 9 months ago (Nov. 10, 2009)
Published	15 years, 9 months ago (Nov. 10, 2009)
Published Online	15 years, 9 months ago (Nov. 10, 2009)
Published Print	15 years, 8 months ago (Dec. 1, 2009)

Funders 0

None

BibTeX

@article{Fisher_2009, title={Oxide‐supported tetraethylenepentamine for CO2 capture}, volume={28}, ISSN={1944-7450}, url={http://dx.doi.org/10.1002/ep.10363}, DOI={10.1002/ep.10363}, number={4}, journal={Environmental Progress & Sustainable Energy}, publisher={Wiley}, author={Fisher, James C. and Tanthana, Jak and Chuang, Steven S.C.}, year={2009}, month=nov, pages={589–598} }

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  "abstract": "<jats:title>Abstract</jats:title><jats:p>CO<jats:sub>2</jats:sub> capture capacity of tetraethylenepentamine (TEPA) supported on beta zeolite, SiO<jats:sub>2</jats:sub>, and Al<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub> has been studied by transient flow switching approach and temperature programmed desorption (TPD) technique coupled with diffuse infrared reflectance Fourier transform spectroscopy and mass spectrometry (MS). TEPA/beta zeolite shows the highest CO<jats:sub>2</jats:sub> capture capacity. Adsorbed CO<jats:sub>2</jats:sub> on TEPA/beta zeolite can be characterized as weakly and strongly adsorbed CO<jats:sub>2</jats:sub>. The former desorbs when CO<jats:sub>2</jats:sub> partial pressure decreases; the latter desorbs during TPD. Strongly adsorbed CO<jats:sub>2</jats:sub> is in the form of carbonates interacting with the N\uf8ffH functional groups of TEPA. This interaction caused the N\uf8ffH and C\uf8ffH intensity to decrease. TEPA/Al<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub> showed the lowest CO<jats:sub>2</jats:sub> capture capacity. The infrared results revealed that TEPA/Al<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub> possessed high content of H<jats:sub>2</jats:sub>O, which inhibited CO<jats:sub>2</jats:sub> adsorption. \u00a9 2009 American Institute of Chemical Engineers Environ Prog, 2009</jats:p>",
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