DOI: 10.1002/ejoc.200500481. Enantioselective Organocatalysis in Ionic Liquids: Addition of Aliphatic Aldehydes and Ketones to Diethyl Azodicarboxylate

Enantioselective Organocatalysis in Ionic Liquids: Addition of Aliphatic Aldehydes and Ketones to Diethyl Azodicarboxylate

10.1002/ejoc.200500481

Crossref journal-article

Wiley

European Journal of Organic Chemistry (311)

Abstract

AbstractThe enantioselective addition of aldehydes to diethyl azodicarboxylate in ionic liquids in the presence of chiralorganocatalysts has been investigated. Of seven differentorganocatalysts tested, L‐proline and L‐thiazoline‐2‐carboxylic acid gave the highest enantioselectivities (up to 94 % ee). The best results were obtained by using [bmim]PF6 and [hmim]BF4 as ionic liquids. The scope of the methodology was probed by using various aldehydes and ketones. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)

Bibliography

Kotrusz, P., Alemayehu, S., Toma, Å ., Schmalz, H., & Adler, A. (2005). Enantioselective Organocatalysis in Ionic Liquids: Addition of Aliphatic Aldehydes and Ketones to Diethyl Azodicarboxylate. European Journal of Organic Chemistry, 2005(22), 4904â4911. Portico.

Authors 5

Peter Kotrusz (first)
Sara Alemayehu (additional)
Štefan Toma (additional)
Hans‐Günther Schmalz (additional)
Andreas Adler (additional)

References 32 Referenced 66

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Dates

Type	When
Created	19 years, 11 months ago (Oct. 4, 2005, 12:21 p.m.)
Deposited	2 years ago (Sept. 2, 2023, 9:05 p.m.)
Indexed	3 months, 4 weeks ago (May 9, 2025, 12:34 p.m.)
Issued	19 years, 10 months ago (Nov. 1, 2005)
Published	19 years, 10 months ago (Nov. 1, 2005)
Published Online	19 years, 10 months ago (Nov. 3, 2005)
Published Print	19 years, 10 months ago (Nov. 1, 2005)

Funders 0

None

BibTeX

@article{Kotrusz_2005, title={Enantioselective Organocatalysis in Ionic Liquids: Addition of Aliphatic Aldehydes and Ketones to Diethyl Azodicarboxylate}, volume={2005}, ISSN={1099-0690}, url={http://dx.doi.org/10.1002/ejoc.200500481}, DOI={10.1002/ejoc.200500481}, number={22}, journal={European Journal of Organic Chemistry}, publisher={Wiley}, author={Kotrusz, Peter and Alemayehu, Sara and Toma, Štefan and Schmalz, Hans‐Günther and Adler, Andreas}, year={2005}, month=nov, pages={4904–4911} }

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