DOI: 10.1002/ejic.201000937. Heterogeneous Catalytic Epoxidation of Olefins Over Hydrothermally Synthesized Lanthanide Containing Framework Compounds

Heterogeneous Catalytic Epoxidation of Olefins Over Hydrothermally Synthesized Lanthanide Containing Framework Compounds

10.1002/ejic.201000937

Crossref journal-article

Wiley

European Journal of Inorganic Chemistry (311)

Abstract

AbstractA series of novel complexes [Ln2(N3)(nic)2(OH)3(Hnic)(H2O)]n (Ln = YIII 1 and GdIII 2; Hnic = nicotinic acid) and [Sm4(N3)2(nic)4(OH)6(Hnic)2(H2O)2]n (3) have been hydrothermally synthesized and structurally characterized by single‐crystal X‐ray analysis. Complexes 1, 2 and 3 have similar structures and consist of [Ln2(N3)(nic)2(OH)3(Hnic)(H2O)] units that are linked to neighboring units through end‐on azido, μ2 and μ3 hydroxo, and bridging carboxylato groups to form 1D infinite chains. In all the complexes the 1D chains propagate parallel to crystallographic a‐axis to give rise to a ribbon‐like chain structure. All the compounds exhibit excellent catalytic performance in olefin epoxidation reactions, which is reflected in high turnover numbers. Good expoxide selectivity was obtained in the cases of cyclooctene and 1‐hexene. The possibility of easy recycling makes these catalysts highly promising candidates for addressing industrial needs and environmental concerns.

Bibliography

Sen, R., Koner, S., Hazra, D. K., Helliwell, M., & Mukherjee, M. (2010). Heterogeneous Catalytic Epoxidation of Olefins Over Hydrothermally Synthesized Lanthanide Containing Framework Compounds. European Journal of Inorganic Chemistry, 2011(2), 241â248. Portico.

Authors 5

Rupam Sen (first)
Subratanath Koner (additional)
Dipak K. Hazra (additional)
Madeleine Helliwell (additional)
Monika Mukherjee (additional)

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Dates

Type	When
Created	14 years, 8 months ago (Dec. 9, 2010, 5:26 a.m.)
Deposited	1 year, 11 months ago (Sept. 2, 2023, 3:48 p.m.)
Indexed	1 year, 5 months ago (March 13, 2024, 4:19 a.m.)
Issued	14 years, 8 months ago (Dec. 9, 2010)
Published	14 years, 8 months ago (Dec. 9, 2010)
Published Online	14 years, 8 months ago (Dec. 9, 2010)
Published Print	14 years, 7 months ago (Jan. 1, 2011)

Funders 0

None

BibTeX

@article{Sen_2010, title={Heterogeneous Catalytic Epoxidation of Olefins Over Hydrothermally Synthesized Lanthanide Containing Framework Compounds}, volume={2011}, ISSN={1099-0682}, url={http://dx.doi.org/10.1002/ejic.201000937}, DOI={10.1002/ejic.201000937}, number={2}, journal={European Journal of Inorganic Chemistry}, publisher={Wiley}, author={Sen, Rupam and Koner, Subratanath and Hazra, Dipak K. and Helliwell, Madeleine and Mukherjee, Monika}, year={2010}, month=dec, pages={241–248} }

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