DOI: 10.1002/ejic.201000473. Metals@MOFs – Loading MOFs with Metal Nanoparticles for Hybrid Functions

Metals@MOFs – Loading MOFs with Metal Nanoparticles for Hybrid Functions

10.1002/ejic.201000473

Crossref journal-article

Wiley

European Journal of Inorganic Chemistry (311)

Abstract

AbstractMetal–organic frameworks (MOFs) as well as porous coordination polymers (PCPs) are porous, organic–inorganic hybrid solids with zeolite‐like structures and properties. Due to their extraordinarily high surface area and well defined pore structure MOFs can be used for the stabilization of metal nanoparticles with adjustable size. The embedded metal nanoparticles are still accessible for other reagents due to the high porosity of the MOF systems. This fact makes “metal@MOF” systems especially interesting for heterogeneous catalysis, gas storage and chemical sensing. This review compiles the cases of metal nanoparticles supported by or embedded into MOFs reported so far and the main aspects and problems associated with these novel nanocomposite systems. The determination of the dispersion and the location of the particles at the MOF support, the control of the loading degree and its effect on the catalytic activity of the system are discussed as well as the partial degradation of the MOF structure upon particle formation. Examples of the introduction of stabilizing groups into the MOF network that direct the loading and can influence the size and shape of the embedded particles are still rare and point into the possible direction of future investigations. Finally, the formation of bimetallic nanoparticles, which are stabilized and supported by a MOF network, will also be reviewed.

Bibliography

Meilikhov, M., Yusenko, K., Esken, D., Turner, S., Van Tendeloo, G., & Fischer, R. A. (2010). Metals@MOFs â Loading MOFs with Metal Nanoparticles for Hybrid Functions. European Journal of Inorganic Chemistry, 2010(24), 3701â3714. Portico.

Authors 6

Mikhail Meilikhov (first)
Kirill Yusenko (additional)
Daniel Esken (additional)
Stuart Turner (additional)
Gustaaf Van Tendeloo (additional)
Roland A. Fischer (additional)

References 53 Referenced 486

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Dates

Type	When
Created	15 years, 1 month ago (July 9, 2010, 1:04 p.m.)
Deposited	1 year, 11 months ago (Sept. 2, 2023, 1:53 a.m.)
Indexed	1 week, 6 days ago (Aug. 7, 2025, 4:23 p.m.)
Issued	15 years, 1 month ago (July 9, 2010)
Published	15 years, 1 month ago (July 9, 2010)
Published Online	15 years, 1 month ago (July 9, 2010)
Published Print	15 years ago (Aug. 1, 2010)

Funders 0

None

BibTeX

@article{Meilikhov_2010, title={Metals@MOFs – Loading MOFs with Metal Nanoparticles for Hybrid Functions}, volume={2010}, ISSN={1099-0682}, url={http://dx.doi.org/10.1002/ejic.201000473}, DOI={10.1002/ejic.201000473}, number={24}, journal={European Journal of Inorganic Chemistry}, publisher={Wiley}, author={Meilikhov, Mikhail and Yusenko, Kirill and Esken, Daniel and Turner, Stuart and Van Tendeloo, Gustaaf and Fischer, Roland A.}, year={2010}, month=jul, pages={3701–3714} }

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