DOI: 10.1002/ejic.200600860. The Effect of Hydrothermal and Non‐Hydrothermal Synthesis on the Formation of Holmium(III) Succinate Hydrate Frameworks

The Effect of Hydrothermal and Non‐Hydrothermal Synthesis on the Formation of Holmium(III) Succinate Hydrate Frameworks

10.1002/ejic.200600860

Crossref journal-article

Wiley

European Journal of Inorganic Chemistry (311)

Abstract

AbstractTwo novel hydrated holmium(III) succinates with formula [Ho2(C4H4O4)3(H2O)4]·6H2O (1) and [Ho2(C4H4O4)3(H2O)2]·H2O (2) have been synthesized from aqueous solution under ambient and hydrothermal conditions, respectively. Single‐crystal X‐ray diffraction shows that HoIII is nine‐coordinate in both compounds even though their structures are markedly different, the main distinctive features being the [H2O]/[C4H4O42–] ratio in the coordination sphere, the conformation and coordination ability of the succinate ions, and the resulting framework dimensionality. Compound 1 is a 2D hybrid polymer and its crystal structure is unprecedented for rare‐earth succinates. It consists of centrosymmetric dimers of edge‐sharing HoO7(H2O)2 polyhedra linked by succinate ions in the [100] and [101] directions. Hydrogen‐bonded hydration water molecules connect layers to give three‐dimensional stability. Compound 2 is built up from infinite chains of HoO8(H2O) polyhedra linked by succinates that result in a 3D architecture. This structure shows that hydrothermal conditions favor an increase in the overall dimensionality of these hybrids, in agreement with theoretical considerations. The compounds were characterized by FTIR and Raman spectroscopy, thermal analysis, and variable‐temperature magnetic susceptibility measurements and the results are discussed in connection with the structural findings. The effect of the dimensionality on the thermal stability of both structures after removal of the hydration water molecules is also analyzed.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)

Bibliography

Bernini, M. C., Brusau, E. V., Narda, G. E., Echeverria, G. E., Pozzi, C. G., Punte, G., & Lehmann, C. W. (2007). The Effect of Hydrothermal and NonâHydrothermal Synthesis on the Formation of Holmium(III) Succinate Hydrate Frameworks. European Journal of Inorganic Chemistry, 2007(5), 684â693. Portico.

Authors 7

Maria C. Bernini (first)
Elena V. Brusau (additional)
Griselda E. Narda (additional)
Gustavo E. Echeverria (additional)
C. Gustavo Pozzi (additional)
Graciela Punte (additional)
Christian W. Lehmann (additional)

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Dates

Type	When
Created	18 years, 7 months ago (Jan. 4, 2007, 3:26 p.m.)
Deposited	1 year, 10 months ago (Oct. 10, 2023, 6:09 a.m.)
Indexed	3 weeks, 1 day ago (July 30, 2025, 11:33 a.m.)
Issued	18 years, 6 months ago (Jan. 30, 2007)
Published	18 years, 6 months ago (Jan. 30, 2007)
Published Online	18 years, 6 months ago (Jan. 30, 2007)
Published Print	18 years, 6 months ago (Feb. 1, 2007)

Funders 0

None

BibTeX

@article{Bernini_2007, title={The Effect of Hydrothermal and Non‐Hydrothermal Synthesis on the Formation of Holmium(III) Succinate Hydrate Frameworks}, volume={2007}, ISSN={1099-0682}, url={http://dx.doi.org/10.1002/ejic.200600860}, DOI={10.1002/ejic.200600860}, number={5}, journal={European Journal of Inorganic Chemistry}, publisher={Wiley}, author={Bernini, Maria C. and Brusau, Elena V. and Narda, Griselda E. and Echeverria, Gustavo E. and Pozzi, C. Gustavo and Punte, Graciela and Lehmann, Christian W.}, year={2007}, month=jan, pages={684–693} }

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