DOI: 10.1002/ejic.200300372. Structural Diversity in Lewis‐Base Complexes of Lithium Triflamide

Structural Diversity in Lewis‐Base Complexes of Lithium Triflamide

10.1002/ejic.200300372

Crossref journal-article

Wiley

European Journal of Inorganic Chemistry (311)

Abstract

AbstractComplexation of the salt lithium triflamide [LiNTf2; NTf2 = N(SO2CF3)2], with a range of nitrogen donor ligands results in the formation of a series of coordination complexes [(Tf2N)Li·N(H)PPh2Me] (1), [(Tf2N)Li·N(H)PPh3] (2), [(Tf2N)Li·TMEDA] (3), [(Tf2N)Li·PMDTEA] (4) and [(Bz‐TAC)2Li][NTf2] (5). The molecular structures of 1, 3, 4 and 5 have been determined by single‐crystal X‐ray diffraction. The resulting solvated structures are discussed in terms of solvent‐separated ion pairs, contact ion pairs and higher aggregates, with the degree of aggregation and ion contact being dependent on the relative coordinating abilities and steric demands of the donor ligand and the anion, and provide an insight into the possible structures of lithium aggregates present in complex systems such as polymer electrolytes and synthetic reaction media. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)

Bibliography

Davidson, M. G., Raithby, P. R., Johnson, A. L., & Bolton, P. D. (2003). Structural Diversity in LewisâBase Complexes of Lithium Triflamide. European Journal of Inorganic Chemistry, 2003(18), 3445â3452. Portico.

Authors 4

Matthew G. Davidson (first)
Paul R. Raithby (additional)
Andrew L. Johnson (additional)
Philip D. Bolton (additional)

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Dates

Type	When
Created	21 years, 11 months ago (Sept. 17, 2003, 11:01 a.m.)
Deposited	1 year, 11 months ago (Sept. 2, 2023, 11:21 a.m.)
Indexed	11 months, 4 weeks ago (Aug. 25, 2024, 8:09 a.m.)
Issued	21 years, 11 months ago (Sept. 1, 2003)
Published	21 years, 11 months ago (Sept. 1, 2003)
Published Online	21 years, 11 months ago (Sept. 12, 2003)
Published Print	21 years, 11 months ago (Sept. 1, 2003)

Funders 0

None

BibTeX

@article{Davidson_2003, title={Structural Diversity in Lewis‐Base Complexes of Lithium Triflamide}, volume={2003}, ISSN={1099-0682}, url={http://dx.doi.org/10.1002/ejic.200300372}, DOI={10.1002/ejic.200300372}, number={18}, journal={European Journal of Inorganic Chemistry}, publisher={Wiley}, author={Davidson, Matthew G. and Raithby, Paul R. and Johnson, Andrew L. and Bolton, Philip D.}, year={2003}, month=sep, pages={3445–3452} }

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      ]
    ]
  },
  "assertion": [
    {
      "value": "2003-06-17",
      "order": 0,
      "name": "received",
      "label": "Received",
      "group": {
        "name": "publication_history",
        "label": "Publication History"
      }
    },
    {
      "value": "2003-09-12",
      "order": 2,
      "name": "published",
      "label": "Published",
      "group": {
        "name": "publication_history",
        "label": "Publication History"
      }
    }
  ]
}