Abstract
AbstractHierarchical zeolites have been established as a superior type of aluminosilicate catalysts compared to their conventional (purely microporous) counterparts. An impressive array of bottom‐up and top‐down approaches has been developed during the last decade to design and subsequently exploit these exciting materials catalytically. However, the sustainability of the developed synthetic methods has rarely been addressed. This paper highlights important criteria to ensure the ecological and economic viability of the manufacture of hierarchical zeolites. Moreover, by using base leaching as a promising case study, we verify a variety of approaches to increase reactor productivity, recycle waste streams, prevent the combustion of organic compounds, and minimize separation efforts. By reducing their synthetic footprint, hierarchical zeolites are positioned as an integral part of sustainable chemistry.
References
64
Referenced
81
10.1002/9783527610044.hetcat0002
/ Handbook of Heterogeneous Catalysis, 2nd ed. by Davis B. H. (2008)10.1002/9783527621866.ch1
10.1002/ange.201102117
10.1002/anie.201102117
10.1021/cr068360d
10.1039/b418069k
10.1002/cssc.200800227
10.1002/cssc.201200794
10.1002/cssc.200900180
10.1002/ange.200800012
10.1002/anie.200800012
{'key': 'e_1_2_6_10_2', 'first-page': '1', 'volume-title': 'Zeolites in Ullmann’s Encyclopedia of Industrial Chemistry', 'author': 'Broach R. W.', 'year': '2012'}
/ Zeolites in Ullmann’s Encyclopedia of Industrial Chemistry by Broach R. W. (2012){'key': 'e_1_2_6_11_2', 'first-page': '243', 'volume-title': 'Synthesis of Solid Catalysts', 'author': 'Bulut M.', 'year': '2009'}
/ Synthesis of Solid Catalysts by Bulut M. (2009)10.1016/j.micromeso.2005.02.016
10.1016/j.micromeso.2005.01.035
10.1016/j.micromeso.2011.03.039
10.1021/cr4001513
10.1039/b809030k
10.1039/c3cs35488a
10.1002/cctc.201000158
10.1039/c0cy00027b
10.1039/C2CS35330J
10.1016/j.cattod.2011.01.007
10.1002/cssc.201200888
10.1073/pnas.1002358107
10.1021/cs300124m
10.1002/cssc.201300339
10.1002/ange.200904016
10.1002/anie.200904016
10.1021/cm702224p
10.1016/j.micromeso.2012.03.054
10.1039/c3nr01629c
10.1021/jp074980m
10.1039/c1cy00150g
10.1002/cctc.201100264
{'key': 'e_1_2_6_33_2', 'first-page': '446', 'volume-title': 'Catalysis: An Integrated Approach', 'author': 'Jong K. P. de', 'year': '1999'}
/ Catalysis: An Integrated Approach by Jong K. P. de (1999)10.1021/cm047908z
10.1126/science.1214798
10.1021/ie061146v
10.1021/jp201671s
10.1021/cg3003228
10.1021/cg4010483
10.1016/j.micromeso.2004.06.004
10.1039/C2CS35341E
10.1016/j.micromeso.2006.07.024
10.1016/j.micromeso.2007.11.027
10.1016/0144-2449(83)90173-2
- C. Baerlocher L. B. McCusker Database of Zeolite Structures http://www.iza‐structure.org/databases/(accessed January 2014).
10.1016/0016-7037(80)90281-1
10.1016/0144-2449(94)90153-8
10.1016/j.apcata.2009.05.055
10.1021/cm4006103
10.1002/ejic.200801194
10.1002/adfm.201102411
10.1007/s10924-006-0011-x
10.1021/cm060080r
10.1002/chem.201002589
10.1021/ja00243a022
10.1021/ie801501y
- V. J.Frilette G. T.Kerr US Patent 3071434 1963.
- W.Hirsh US Patent 3425800 1969.
10.1016/0009-2509(69)80008-4
10.1039/c3cs60076a
10.1080/01614948408064725
Dates
Type | When |
---|---|
Created | 11 years, 6 months ago (Feb. 12, 2014, 8:21 a.m.) |
Deposited | 1 year, 10 months ago (Oct. 16, 2023, 6:07 a.m.) |
Indexed | 1 year, 2 months ago (June 21, 2024, 12:11 p.m.) |
Issued | 11 years, 6 months ago (Feb. 12, 2014) |
Published | 11 years, 6 months ago (Feb. 12, 2014) |
Published Online | 11 years, 6 months ago (Feb. 12, 2014) |
Published Print | 11 years, 5 months ago (March 1, 2014) |
@article{Verboekend_2014, title={Towards a Sustainable Manufacture of Hierarchical Zeolites}, volume={7}, ISSN={1864-564X}, url={http://dx.doi.org/10.1002/cssc.201301313}, DOI={10.1002/cssc.201301313}, number={3}, journal={ChemSusChem}, publisher={Wiley}, author={Verboekend, Danny and Pérez‐Ramírez, Javier}, year={2014}, month=feb, pages={753–764} }