DOI: 10.1002/cssc.200900123. Development of Molecular and Solid Catalysts for the Direct Low‐Temperature Oxidation of Methane to Methanol

Development of Molecular and Solid Catalysts for the Direct Low‐Temperature Oxidation of Methane to Methanol

10.1002/cssc.200900123

Crossref journal-article

Wiley

ChemSusChem (311)

Abstract

AbstractThe direct low‐temperature oxidation of methane to methanol is demonstrated on a highly active homogeneous molecular catalyst system and on heterogeneous molecular catalysts based on polymeric materials possessing ligand motifs within the material structure. The N‐(2‐methylpropyl)‐4,5‐diazacarbazolyl‐dichloro‐platinum(II) complex reaches significantly higher activity compared to the well‐known Periana system and allows first conclusions on electronic and structural requirements for high catalytic activity in this reaction. Interestingly, comparable activities could be achieved utilizing a platinum modified poly(benzimidazole) material, which demonstrates for the first time a solid catalyst with superior activity compared to the Periana system. Although the material shows platinum leaching, improved activity and altered electronic properties, compared to the conventional Periana system, support the proposed conclusions on structure–activity relationships. In comparison, platinum modified triazine‐based catalysts show lower catalytic activity, but rather stable platinum coordination even after several catalytic cycles. Based on these systems, further development of improved solid catalysts for the direct low‐temperature oxidation of methane to methanol is feasible.

Bibliography

Palkovits, R., vonâMalotki, C., Baumgarten, M., MÃ¼llen, K., Baltes, C., Antonietti, M., Kuhn, P., Weber, J., Thomas, A., & SchÃ¼th, F. (2010). Development of Molecular and Solid Catalysts for the Direct LowâTemperature Oxidation of Methane to Methanol. ChemSusChem, 3(2), 277â282. Portico.

Authors 10

Regina Palkovits (first)
Christian von Malotki (additional)
Martin Baumgarten (additional)
Klaus Müllen (additional)
Christian Baltes (additional)
Markus Antonietti (additional)
Pierre Kuhn (additional)
Jens Weber (additional)
Arne Thomas (additional)
Ferdi Schüth (additional)

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Dates

Type	When
Created	15 years, 11 months ago (Sept. 24, 2009, 2:39 p.m.)
Deposited	1 year, 11 months ago (Sept. 11, 2023, 9:44 p.m.)
Indexed	2 weeks, 4 days ago (Aug. 7, 2025, 4:57 a.m.)
Issued	15 years, 6 months ago (Feb. 15, 2010)
Published	15 years, 6 months ago (Feb. 15, 2010)
Published Online	15 years, 6 months ago (Feb. 15, 2010)
Published Print	15 years, 6 months ago (Feb. 22, 2010)

Funders 0

None

BibTeX

@article{Palkovits_2010, title={Development of Molecular and Solid Catalysts for the Direct Low‐Temperature Oxidation of Methane to Methanol}, volume={3}, ISSN={1864-564X}, url={http://dx.doi.org/10.1002/cssc.200900123}, DOI={10.1002/cssc.200900123}, number={2}, journal={ChemSusChem}, publisher={Wiley}, author={Palkovits, Regina and von Malotki, Christian and Baumgarten, Martin and Müllen, Klaus and Baltes, Christian and Antonietti, Markus and Kuhn, Pierre and Weber, Jens and Thomas, Arne and Schüth, Ferdi}, year={2010}, month=feb, pages={277–282} }

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