DOI: 10.1002/cssc.200900059. Gold‐Catalyzed Aerobic Oxidation of 5‐Hydroxymethylfurfural in Water at Ambient Temperature

Gold‐Catalyzed Aerobic Oxidation of 5‐Hydroxymethylfurfural in Water at Ambient Temperature

10.1002/cssc.200900059

Crossref journal-article

Wiley

ChemSusChem (311)

Abstract

AbstractThe aerobic oxidation of 5‐hydroxymethylfurfural, a versatile biomass‐derived chemical, is examined in water with a titania‐supported gold‐nanoparticle catalyst at ambient temperature (30 °C). The selectivity of the reaction towards 2,5‐furandicarboxylic acid and the intermediate oxidation product 5‐hydroxymethyl‐2‐furancarboxylic acid is found to depend on the amount of added base and the oxygen pressure, suggesting that the reaction proceeds via initial oxidation of the aldehyde moiety followed by oxidation of the hydroxymethyl group of 5‐hydroxymethylfurfural. Under optimized reaction conditions, a 71 % yield of 2,5‐furandicarboxylic acid is obtained at full 5‐hydroxymethylfurfural conversion in the presence of excess base.

Bibliography

Gorbanev, Y. Y., Klitgaard, S. K., Woodley, J. M., Christensen, C. H., & Riisager, A. (2009). GoldâCatalyzed Aerobic Oxidation of 5âHydroxymethylfurfural in Water at Ambient Temperature. ChemSusChem, 2(7), 672â675. Portico.

Authors 5

Yury Y. Gorbanev (first)
Søren K. Klitgaard (additional)
John M. Woodley (additional)
Claus H. Christensen (additional)
Anders Riisager (additional)

References 27 Referenced 301

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Dates

Type	When
Created	16 years, 1 month ago (July 10, 2009, 6:21 p.m.)
Deposited	1 year, 11 months ago (Sept. 28, 2023, 10:22 p.m.)
Indexed	3 days, 15 hours ago (Aug. 29, 2025, 6:07 a.m.)
Issued	16 years, 1 month ago (July 10, 2009)
Published	16 years, 1 month ago (July 10, 2009)
Published Online	16 years, 1 month ago (July 10, 2009)
Published Print	16 years, 1 month ago (July 20, 2009)

Funders 0

None

BibTeX

@article{Gorbanev_2009, title={Gold‐Catalyzed Aerobic Oxidation of 5‐Hydroxymethylfurfural in Water at Ambient Temperature}, volume={2}, ISSN={1864-564X}, url={http://dx.doi.org/10.1002/cssc.200900059}, DOI={10.1002/cssc.200900059}, number={7}, journal={ChemSusChem}, publisher={Wiley}, author={Gorbanev, Yury Y. and Klitgaard, Søren K. and Woodley, John M. and Christensen, Claus H. and Riisager, Anders}, year={2009}, month=jul, pages={672–675} }

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