DOI: 10.1002/cssc.200800215. Carbon‐Supported, Selenium‐Modified Ruthenium–Molybdenum Catalysts for Oxygen Reduction in Acidic Media

Carbon‐Supported, Selenium‐Modified Ruthenium–Molybdenum Catalysts for Oxygen Reduction in Acidic Media

10.1002/cssc.200800215

Crossref journal-article

Wiley

ChemSusChem (311)

Abstract

AbstractThe stability and oxygen reduction activity of two carbon‐supported catalyst materials are reported. The catalysts, Se/Ru and Se/(Ru–Mo), were prepared by using a chemical reduction method. The catalyst nanoparticles were evenly dispersed onto globular amorphous carbon supports, and their average size was ca. 2.4 nm. Thermal treatment at 500 °C for 2 h in an inert argon atmosphere resulted in coarsening of the nanoparticles, and also in some decrease of their activity. A gradual reduction of activity was also observed for Se/Ru during potential‐cycle experiments. However, the incorporation of small amounts of Mo into the Se/Ru catalysts considerably improved the stability of the catalyst against dissolution. The Mo‐containing samples showed excellent oxygen reduction activities even after cycling the potential 1000 times between 0.7 and 0.9 V. Furthermore, they showed excellent fuel‐cell behavior. The performance of the Se/Ru catalysts is greatly improved by the addition of small amounts of elemental Mo. Possible mechanisms responsible for the improvement of the activity are discussed.

Bibliography

Guinel, M. J. âF., Bonakdarpour, A., Wang, B., Babu, P. K., Ernst, F., Ramaswamy, N., Mukerjee, S., & Wieckowski, A. (2009). CarbonâSupported, SeleniumâModified RutheniumâMolybdenum Catalysts for Oxygen Reduction in Acidic Media. ChemSusChem, 2(7), 658â664. Portico.

Authors 8

Maxime J.‐F. Guinel (first)
Arman Bonakdarpour (additional)
Biao Wang (additional)
Panakkattu K. Babu (additional)
Frank Ernst (additional)
Nagappan Ramaswamy (additional)
Sanjeev Mukerjee (additional)
Andrzej Wieckowski (additional)

References 35 Referenced 24

10.1016/j.jpowsour.2003.09.032
10.1016/j.jpowsour.2006.01.030
10.1016/j.ijhydene.2008.10.092
10.1016/S0022-0728(98)00197-1
10.1016/j.electacta.2007.01.089
10.1016/j.jpowsour.2005.01.074
10.1016/S0013-4686(02)00344-4
10.1016/0013-4686(94)85149-2
10.1149/1.1393579
10.1016/0013-4686(94)00377-D
{'key': 'e_1_2_6_11_2', 'first-page': '71', 'volume': '5', 'author': 'Hilgendorff M.', 'year': '2002', 'journal-title': 'J. New Mater. Electrochem. Syst.'} / J. New Mater. Electrochem. Syst. by Hilgendorff M. (2002)
10.1007/s10008-007-0311-7
10.1007/s10800-007-9348-7
10.1016/j.jpowsour.2005.03.188
10.1016/S0360-3199(98)00023-8
10.1023/A:1017575008333
10.1149/1.2180709
10.1021/jp056715b
S. A.Campbell US Patent 7 125 820 2006. (10.1038/nrg1614-c1)
10.1021/jp0618431
10.1002/ange.200701473
10.1002/ange.200701473
10.1002/anie.200701473
10.1002/fuce.200500245
10.1016/S0013-4686(02)00351-1
10.1126/science.1134569
10.1126/science.1135941
10.1021/ja077498q
10.1016/S0013-4686(00)00556-9
10.1016/j.jpowsour.2005.07.065
10.1016/j.jpowsour.2005.03.188
10.1016/0022-0728(93)80380-Z
10.1039/b806377j
10.1016/S0022-0728(03)00241-9

Dates

Type	When
Created	16 years, 2 months ago (June 24, 2009, 10:16 a.m.)
Deposited	6 months, 2 weeks ago (Feb. 10, 2025, 3:50 a.m.)
Indexed	6 months, 2 weeks ago (Feb. 11, 2025, 12:06 a.m.)
Issued	16 years, 1 month ago (July 10, 2009)
Published	16 years, 1 month ago (July 10, 2009)
Published Online	16 years, 1 month ago (July 10, 2009)
Published Print	16 years, 1 month ago (July 20, 2009)

Funders 0

None

BibTeX

@article{Guinel_2009, title={Carbon‐Supported, Selenium‐Modified Ruthenium–Molybdenum Catalysts for Oxygen Reduction in Acidic Media}, volume={2}, ISSN={1864-564X}, url={http://dx.doi.org/10.1002/cssc.200800215}, DOI={10.1002/cssc.200800215}, number={7}, journal={ChemSusChem}, publisher={Wiley}, author={Guinel, Maxime J.‐F. and Bonakdarpour, Arman and Wang, Biao and Babu, Panakkattu K. and Ernst, Frank and Ramaswamy, Nagappan and Mukerjee, Sanjeev and Wieckowski, Andrzej}, year={2009}, month=jul, pages={658–664} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2025,
        2,
        11
      ]
    ],
    "date-time": "2025-02-11T05:06:17Z",
    "timestamp": 1739250377808,
    "version": "3.37.0"
  },
  "reference-count": 35,
  "publisher": "Wiley",
  "issue": "7",
  "license": [
    {
      "start": {
        "date-parts": [
          [
            2009,
            6,
            24
          ]
        ],
        "date-time": "2009-06-24T00:00:00Z",
        "timestamp": 1245801600000
      },
      "content-version": "vor",
      "delay-in-days": 0,
      "URL": "http://onlinelibrary.wiley.com/termsAndConditions#vor"
    }
  ],
  "content-domain": {
    "domain": [
      "chemistry-europe.onlinelibrary.wiley.com"
    ],
    "crossmark-restriction": true
  },
  "published-print": {
    "date-parts": [
      [
        2009,
        7,
        20
      ]
    ]
  },
  "abstract": "<jats:title>Abstract</jats:title><jats:p>The stability and oxygen reduction activity of two carbon\u2010supported catalyst materials are reported. The catalysts, Se/Ru and Se/(Ru\u2013Mo), were prepared by using a chemical reduction method. The catalyst nanoparticles were evenly dispersed onto globular amorphous carbon supports, and their average size was ca. 2.4\u2005nm. Thermal treatment at 500\u2009\u00b0C for 2\u2005h in an inert argon atmosphere resulted in coarsening of the nanoparticles, and also in some decrease of their activity. A gradual reduction of activity was also observed for Se/Ru during potential\u2010cycle experiments. However, the incorporation of small amounts of Mo into the Se/Ru catalysts considerably improved the stability of the catalyst against dissolution. The Mo\u2010containing samples showed excellent oxygen reduction activities even after cycling the potential 1000\u2005times between 0.7 and 0.9\u2005V. Furthermore, they showed excellent fuel\u2010cell behavior. The performance of the Se/Ru catalysts is greatly improved by the addition of small amounts of elemental Mo. Possible mechanisms responsible for the improvement of the activity are discussed.</jats:p>",
  "DOI": "10.1002/cssc.200800215",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2009,
        6,
        24
      ]
    ],
    "date-time": "2009-06-24T14:16:05Z",
    "timestamp": 1245852965000
  },
  "page": "658-664",
  "update-policy": "https://doi.org/10.1002/crossmark_policy",
  "source": "Crossref",
  "is-referenced-by-count": 24,
  "title": "Carbon\u2010Supported, Selenium\u2010Modified Ruthenium\u2013Molybdenum Catalysts for Oxygen Reduction in Acidic Media",
  "prefix": "10.1002",
  "volume": "2",
  "author": [
    {
      "given": "Maxime\u2005J.\u2010F.",
      "family": "Guinel",
      "sequence": "first",
      "affiliation": []
    },
    {
      "given": "Arman",
      "family": "Bonakdarpour",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "Biao",
      "family": "Wang",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "Panakkattu\u2005K.",
      "family": "Babu",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "Frank",
      "family": "Ernst",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "Nagappan",
      "family": "Ramaswamy",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "Sanjeev",
      "family": "Mukerjee",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "Andrzej",
      "family": "Wieckowski",
      "sequence": "additional",
      "affiliation": []
    }
  ],
  "member": "311",
  "published-online": {
    "date-parts": [
      [
        2009,
        7,
        10
      ]
    ]
  },
  "reference": [
    {
      "key": "e_1_2_6_1_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/j.jpowsour.2003.09.032"
    },
    {
      "key": "e_1_2_6_2_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/j.jpowsour.2006.01.030"
    },
    {
      "key": "e_1_2_6_3_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/j.ijhydene.2008.10.092"
    },
    {
      "key": "e_1_2_6_4_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/S0022-0728(98)00197-1"
    },
    {
      "key": "e_1_2_6_5_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/j.electacta.2007.01.089"
    },
    {
      "key": "e_1_2_6_6_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/j.jpowsour.2005.01.074"
    },
    {
      "key": "e_1_2_6_7_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/S0013-4686(02)00344-4"
    },
    {
      "key": "e_1_2_6_8_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0013-4686(94)85149-2"
    },
    {
      "key": "e_1_2_6_9_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1149/1.1393579"
    },
    {
      "key": "e_1_2_6_10_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0013-4686(94)00377-D"
    },
    {
      "key": "e_1_2_6_11_2",
      "first-page": "71",
      "volume": "5",
      "author": "Hilgendorff M.",
      "year": "2002",
      "journal-title": "J. New Mater. Electrochem. Syst."
    },
    {
      "key": "e_1_2_6_12_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1007/s10008-007-0311-7"
    },
    {
      "key": "e_1_2_6_13_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1007/s10800-007-9348-7"
    },
    {
      "key": "e_1_2_6_14_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/j.jpowsour.2005.03.188"
    },
    {
      "key": "e_1_2_6_15_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/S0360-3199(98)00023-8"
    },
    {
      "key": "e_1_2_6_16_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1023/A:1017575008333"
    },
    {
      "key": "e_1_2_6_17_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1149/1.2180709"
    },
    {
      "key": "e_1_2_6_18_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/jp056715b"
    },
    {
      "key": "e_1_2_6_19_2",
      "doi-asserted-by": "crossref",
      "unstructured": "S.\u2005A.Campbell US Patent 7\u2009125\u2009820 2006.",
      "DOI": "10.1038/nrg1614-c1"
    },
    {
      "key": "e_1_2_6_20_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/jp0618431"
    },
    {
      "key": "e_1_2_6_21_2",
      "unstructured": "\u00a0"
    },
    {
      "key": "e_1_2_6_22_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/ange.200701473"
    },
    {
      "key": "e_1_2_6_23_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/ange.200701473"
    },
    {
      "key": "e_1_2_6_23_3",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/anie.200701473"
    },
    {
      "key": "e_1_2_6_24_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/fuce.200500245"
    },
    {
      "key": "e_1_2_6_25_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/S0013-4686(02)00351-1"
    },
    {
      "key": "e_1_2_6_26_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1126/science.1134569"
    },
    {
      "key": "e_1_2_6_27_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1126/science.1135941"
    },
    {
      "key": "e_1_2_6_28_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ja077498q"
    },
    {
      "key": "e_1_2_6_29_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/S0013-4686(00)00556-9"
    },
    {
      "key": "e_1_2_6_30_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/j.jpowsour.2005.07.065"
    },
    {
      "key": "e_1_2_6_31_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/j.jpowsour.2005.03.188"
    },
    {
      "key": "e_1_2_6_32_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0022-0728(93)80380-Z"
    },
    {
      "key": "e_1_2_6_33_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1039/b806377j"
    },
    {
      "key": "e_1_2_6_34_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/S0022-0728(03)00241-9"
    }
  ],
  "container-title": "ChemSusChem",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fcssc.200800215",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "text-mining"
    },
    {
      "URL": "http://onlinelibrary.wiley.com/wol1/doi/10.1002/cssc.200800215/fullpdf",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2025,
        2,
        10
      ]
    ],
    "date-time": "2025-02-10T08:50:16Z",
    "timestamp": 1739177416000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/cssc.200800215"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        2009,
        7,
        10
      ]
    ]
  },
  "references-count": 35,
  "journal-issue": {
    "issue": "7",
    "published-print": {
      "date-parts": [
        [
          2009,
          7,
          20
        ]
      ]
    }
  },
  "alternative-id": [
    "10.1002/cssc.200800215"
  ],
  "URL": "http://dx.doi.org/10.1002/cssc.200800215",
  "relation": {},
  "ISSN": [
    "1864-5631",
    "1864-564X"
  ],
  "subject": [],
  "container-title-short": "ChemSusChem",
  "published": {
    "date-parts": [
      [
        2009,
        7,
        10
      ]
    ]
  },
  "assertion": [
    {
      "value": "2008-10-29",
      "order": 0,
      "name": "received",
      "label": "Received",
      "group": {
        "name": "publication_history",
        "label": "Publication History"
      }
    },
    {
      "value": "2009-07-10",
      "order": 2,
      "name": "published",
      "label": "Published",
      "group": {
        "name": "publication_history",
        "label": "Publication History"
      }
    }
  ]
}