DOI: 10.1002/cssc.200800147. Efficient Catalytic Decomposition of Formic Acid for the Selective Generation of H<sub>2</sub> and H/D Exchange with a Water‐Soluble Rhodium Complex in Aqueous Solution

Efficient Catalytic Decomposition of Formic Acid for the Selective Generation of H2 and H/D Exchange with a Water‐Soluble Rhodium Complex in Aqueous Solution

10.1002/cssc.200800147

Crossref journal-article

Wiley

ChemSusChem (311)

Abstract

AbstractFormic acid (HCOOH) decomposes efficiently to afford H2 and CO2 selectively in the presence of a catalytic amount of a water‐soluble rhodium aqua complex, [RhIII(Cp*)(bpy)(H2O)]2+ (Cp*=pentamethylcyclopentadienyl, bpy=2,2′‐bipyridine) in aqueous solution at 298 K. No CO was produced in this catalytic decomposition of HCOOH. The decomposition rate reached a maximum value at pH 3.8. No deterioration of the catalyst was observed during the catalytic decomposition of HCOOH, and the catalytic activity remained the same for the repeated addition of HCOOH. The rhodium‐hydride complex was detected as the catalytic active species that undergoes efficient H/D exchange with water. When the catalytic decomposition of HCOOH was performed in D2O, D2 was produced selectively. Such an efficient H/D exchange and the observation of a deuterium kinetic isotope effect in the catalytic decomposition of DCOOH in H2O provide valuable mechanistic insight into this efficient and selective decomposition process.

Bibliography

Fukuzumi, S., Kobayashi, T., & Suenobu, T. (2008). Efficient Catalytic Decomposition of Formic Acid for the Selective Generation of H2 and H/D Exchange with a WaterâSoluble Rhodium Complex in Aqueous Solution. ChemSusChem, 1(10), 827â834. Portico.

Authors 3

Shunichi Fukuzumi (first)
Takeshi Kobayashi (additional)
Tomoyoshi Suenobu (additional)

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Dates

Type	When
Created	16 years, 10 months ago (Oct. 8, 2008, 8:34 a.m.)
Deposited	1 year, 11 months ago (Sept. 28, 2023, 3:01 p.m.)
Indexed	2 months ago (June 25, 2025, 11:10 a.m.)
Issued	16 years, 10 months ago (Oct. 15, 2008)
Published	16 years, 10 months ago (Oct. 15, 2008)
Published Online	16 years, 10 months ago (Oct. 15, 2008)
Published Print	16 years, 10 months ago (Oct. 24, 2008)

Funders 0

None

BibTeX

@article{Fukuzumi_2008, title={Efficient Catalytic Decomposition of Formic Acid for the Selective Generation of H2 and H/D Exchange with a Water‐Soluble Rhodium Complex in Aqueous Solution}, volume={1}, ISSN={1864-564X}, url={http://dx.doi.org/10.1002/cssc.200800147}, DOI={10.1002/cssc.200800147}, number={10}, journal={ChemSusChem}, publisher={Wiley}, author={Fukuzumi, Shunichi and Kobayashi, Takeshi and Suenobu, Tomoyoshi}, year={2008}, month=oct, pages={827–834} }

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  "abstract": "<jats:title>Abstract</jats:title><jats:p><jats:italic>Formic acid (HCOOH) decomposes efficiently to afford H<jats:sub>2</jats:sub> and CO<jats:sub>2</jats:sub> selectively in the presence of a catalytic amount of a water\u2010soluble rhodium aqua complex, [Rh<jats:sup>III</jats:sup>(Cp*)(bpy)(H<jats:sub>2</jats:sub>O)]<jats:sup>2+</jats:sup></jats:italic> <jats:italic>(Cp*=pentamethylcyclopentadienyl, bpy=2,2\u2032\u2010bipyridine) in aqueous solution at 298\u2005K. No CO was produced in this catalytic decomposition of HCOOH. The decomposition rate reached a maximum value at pH\u20053.8. No deterioration of the catalyst was observed during the catalytic decomposition of HCOOH, and the catalytic activity remained the same for the repeated addition of HCOOH. The rhodium\u2010hydride complex was detected as the catalytic active species that undergoes efficient H/D exchange with water. When the catalytic decomposition of HCOOH was performed in D<jats:sub>2</jats:sub>O, D<jats:sub>2</jats:sub> was produced selectively. Such an efficient H/D exchange and the observation of a deuterium kinetic isotope effect in the catalytic decomposition of DCOOH in H<jats:sub>2</jats:sub>O provide valuable mechanistic insight into this efficient and selective decomposition process.</jats:italic></jats:p>",
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