DOI: 10.1002/cphc.201200918. Enhanced Oxygen Reduction Reactions in Fuel Cells on H‐Decorated and B‐Substituted Graphene

Enhanced Oxygen Reduction Reactions in Fuel Cells on H‐Decorated and B‐Substituted Graphene

10.1002/cphc.201200918

Crossref journal-article

Wiley

ChemPhysChem (311)

Abstract

AbstractIn the light of recent experimental research on the oxygen reduction reaction (ORR) with carbon materials doped with foreign atoms, we study the performance of graphene with different defects on this catalytic reaction. In addition to the reported N‐graphene, it is found that H‐decorated and B‐substituted graphene can also spontaneously promote this chemical reaction. The local high spin density plays the key role, facilitating the adsorption of oxygen and OOH, which is the start of ORR. The source of the high spin density for all of the doped graphene is attributed to unpaired single π electrons. Meanwhile, the newly formed CH covalent bond introduces a higher barrier to the p electron flow, leading to more localized and higher spin density for H‐decorated graphene. At the same time, larger structural distortion should be avoided, which could impair the induced spin density, such as for P‐substituted graphene.

Bibliography

Kong, X., Chen, Q., & Sun, Z. (2013). Enhanced Oxygen Reduction Reactions in Fuel Cells on HâDecorated and BâSubstituted Graphene. ChemPhysChem, 14(3), 514â519. Portico.

Authors 3

Xiangkai Kong (first)
Qianwang Chen (additional)
Zhiyuan Sun (additional)

References 22 Referenced 55

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Dates

Type	When
Created	12 years, 7 months ago (Jan. 9, 2013, 4:12 p.m.)
Deposited	1 year, 10 months ago (Oct. 10, 2023, 9 a.m.)
Indexed	11 months, 2 weeks ago (Sept. 15, 2024, 12:37 a.m.)
Issued	12 years, 7 months ago (Jan. 9, 2013)
Published	12 years, 7 months ago (Jan. 9, 2013)
Published Online	12 years, 7 months ago (Jan. 9, 2013)
Published Print	12 years, 6 months ago (Feb. 25, 2013)

Funders 0

None

BibTeX

@article{Kong_2013, title={Enhanced Oxygen Reduction Reactions in Fuel Cells on H‐Decorated and B‐Substituted Graphene}, volume={14}, ISSN={1439-7641}, url={http://dx.doi.org/10.1002/cphc.201200918}, DOI={10.1002/cphc.201200918}, number={3}, journal={ChemPhysChem}, publisher={Wiley}, author={Kong, Xiangkai and Chen, Qianwang and Sun, Zhiyuan}, year={2013}, month=jan, pages={514–519} }

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