Abstract
AbstractIn nanosized pores, liquid water can be thermodynamically stable down to temperatures well below the limit of homogeneous nucleation of bulk water (∼235 K). Studies of water in such pores therefore offer an opportunity to reveal the anomalous behavior of deeply supercooled water. Herein we focus on recent studies of the limits of freezing and melting of water in the cylindrical pores of ordered mesoporous silicas with pore diameters in the range of 2–10 nm, based on vapor sorption measurements, calorimetric studies, NMR spectroscopy and cryoporometry, and neutron diffraction studies.
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Dates
Type | When |
---|---|
Created | 16 years, 8 months ago (Nov. 26, 2008, 12:25 p.m.) |
Deposited | 1 year, 10 months ago (Sept. 28, 2023, 2:47 p.m.) |
Indexed | 1 week, 2 days ago (Aug. 12, 2025, 5:36 p.m.) |
Issued | 16 years, 8 months ago (Dec. 15, 2008) |
Published | 16 years, 8 months ago (Dec. 15, 2008) |
Published Online | 16 years, 8 months ago (Dec. 15, 2008) |
Published Print | 16 years, 7 months ago (Dec. 22, 2008) |
@article{Findenegg_2008, title={Freezing and Melting of Water Confined in Silica Nanopores}, volume={9}, ISSN={1439-7641}, url={http://dx.doi.org/10.1002/cphc.200800616}, DOI={10.1002/cphc.200800616}, number={18}, journal={ChemPhysChem}, publisher={Wiley}, author={Findenegg, Gerhard H. and Jähnert, Susanne and Akcakayiran, Dilek and Schreiber, Andreas}, year={2008}, month=dec, pages={2651–2659} }