DOI: 10.1002/cphc.200600186. Adsorption and Dynamics of Long‐Range Interacting Fullerenes in a Flexible, Two‐Dimensional, Nanoporous Porphyrin Network

Adsorption and Dynamics of Long‐Range Interacting Fullerenes in a Flexible, Two‐Dimensional, Nanoporous Porphyrin Network

10.1002/cphc.200600186

Crossref journal-article

Wiley

ChemPhysChem (311)

Abstract

AbstractHerein, a detailed investigation of the adsorption and dynamics of C60 and C70 fullerenes hosted in a self‐assembled, two‐dimensional, nanoporous porphyrin network on a solid Ag surface is presented. Time‐resolved scanning tunneling microscopy (STM) studies of these supramolecular systems at the molecular scale reveal distinct host–guest interactions giving rise to a pronounced dissimilar mobility of the two fullerenes within the porphyrin network. Furthermore, long‐range coverage‐dependent interactions between the all‐carbon guests, which clearly affect their mobility and are likely mediated by a complex mechanism involving the Ag substrate and the flexible porphyrin host network, are observed. At increased fullerene coverage, this unprecedented interplay results in the formation of large fullerene chains and islands. By applying a lattice gas model with nearest‐neighbor interactions and by evaluating the fullerene‐pair distribution functions, the respective coverage‐dependent guest–guest interaction energies are estimated.

Bibliography

Kiebele, A., Bonifazi, D., Cheng, F., StÃ¶hr, M., Diederich, F., Jung, T., & Spillmann, H. (2006). Adsorption and Dynamics of LongâRange Interacting Fullerenes in a Flexible, TwoâDimensional, Nanoporous Porphyrin Network. ChemPhysChem, 7(7), 1462â1470. Portico.

Authors 7

Andreas Kiebele (first)
Davide Bonifazi (additional)
Fuyong Cheng (additional)
Meike Stöhr (additional)
François Diederich (additional)
Thomas Jung (additional)
Hannes Spillmann (additional)

References 65 Referenced 58

10.1021/ja971093w
10.1038/nature00785
10.1002/1521-4095(20020503)14:9<629::AID-ADMA629>3.0.CO;2-B
10.1021/ol025935u
10.1126/science.1070821
10.1021/ic034873g
10.1002/ange.200300610
10.1002/anie.200300610
10.1021/ja039914m
10.1021/ja054900x
10.1002/chem.200500400
10.1021/ja054119p
10.1021/ja054913a
10.1002/1438-5171(200204)3:1<25::AID-SIMO25>3.0.CO;2-K
10.1002/adma.200501575
10.1002/ange.200350432
10.1002/anie.200350432
10.1021/la047533w
10.1038/nmat1088
10.1126/science.1091979
10.1038/nature01915
10.1021/jp049521p
10.1021/jp970358q
10.1103/PhysRevLett.80.5754
10.1021/jp000994f
10.1021/jp0354301
10.1021/la034759a
10.1016/j.micromeso.2004.08.014
10.1063/1.1924548
10.1007/s10450-005-5958-8
10.1021/jp051771y
10.1002/adma.200501734
10.1002/adma.200305774
10.1103/PhysRevB.49.14746
10.1021/jp9606467
10.1002/cphc.200500215
10.1002/ange.19921040544
10.1002/anie.199206401
10.1126/science.254.5030.410
10.1002/(SICI)1521-3765(19990604)5:6<1828::AID-CHEM1828>3.0.CO;2-P
10.1002/hlca.19930760526
{'key': 'e_1_2_6_39_2', 'volume-title': 'Fullerenes: Chemistry, Physics, and Technology', 'author': 'Kadish K. M.', 'year': '2000'} / Fullerenes: Chemistry, Physics, and Technology by Kadish K. M. (2000)
10.1126/science.278.5336.257
10.1103/PhysRevLett.78.1516
10.1016/S0167-5729(00)00002-9
10.1103/PhysRevLett.88.156102
S. Berner PhD Thesis University of Basel Switzerland 2002.
10.1017/CBO9780511622564
10.1016/0039-6028(81)90048-0
10.1016/0039-6028(81)90021-2
10.1088/0034-4885/53/7/002
10.1063/1.464419
10.1103/PhysRevB.54.17850
10.1103/PhysRevLett.83.4812
10.1103/PhysRevLett.88.028301
10.1103/PhysRevB.65.115420
10.1103/PhysRevB.68.205410
10.1103/PhysRevLett.93.146805
10.1103/PhysRevLett.92.016101
10.1021/ja0472331
10.1103/PhysRevB.69.165417
10.1002/ange.200460562
10.1002/anie.200460562
10.1021/jp053293x
10.1002/hlca.200590144

Dates

Type	When
Created	19 years, 2 months ago (June 21, 2006, 7:22 a.m.)
Deposited	1 year, 10 months ago (Oct. 18, 2023, 12:37 a.m.)
Indexed	1 year, 7 months ago (Jan. 10, 2024, 5:29 a.m.)
Issued	19 years, 1 month ago (June 30, 2006)
Published	19 years, 1 month ago (June 30, 2006)
Published Online	19 years, 1 month ago (June 30, 2006)
Published Print	19 years, 1 month ago (July 10, 2006)

Funders 0

None

BibTeX

@article{Kiebele_2006, title={Adsorption and Dynamics of Long‐Range Interacting Fullerenes in a Flexible, Two‐Dimensional, Nanoporous Porphyrin Network}, volume={7}, ISSN={1439-7641}, url={http://dx.doi.org/10.1002/cphc.200600186}, DOI={10.1002/cphc.200600186}, number={7}, journal={ChemPhysChem}, publisher={Wiley}, author={Kiebele, Andreas and Bonifazi, Davide and Cheng, Fuyong and Stöhr, Meike and Diederich, François and Jung, Thomas and Spillmann, Hannes}, year={2006}, month=jun, pages={1462–1470} }

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