DOI: 10.1002/chem.201002381. Liquid‐Phase Epitaxy of Multicomponent Layer‐Based Porous Coordination Polymer Thin Films of [M(L)(P)0.5] Type: Importance of Deposition Sequence on the Oriented Growth

Liquid‐Phase Epitaxy of Multicomponent Layer‐Based Porous Coordination Polymer Thin Films of [M(L)(P)0.5] Type: Importance of Deposition Sequence on the Oriented Growth

10.1002/chem.201002381

Crossref journal-article

Wiley

Chemistry – A European Journal (311)

Abstract

AbstractThe progressive liquid‐phase layer‐by‐layer (LbL) growth of anisotropic multicomponent layer‐based porous coordination polymers (PCPs) of the general formula [M(L)(P)0.5] (M: Cu2+, Zn2+; L: dicarboxylate linker; P: dinitrogen pillar ligand) was investigated by using either pyridyl‐ or carboxyl‐terminated self‐assembled monolayers (SAMs) on gold substrates as templates. It was found that the deposition of smooth, highly crystalline, and oriented multilayer films of these PCPs depends on the conditions at the early growth cycles. In the case of a two‐step process with an equimolar mixture of L and P, growth along the [001] direction is strongly preferred. However, employing a three‐step scheme with full separation of all components allows deposition along the [100] direction on carboxyl‐terminated SAMs. Interestingly, the growth of additional layers on top of previously grown oriented seeding layers proved to be insensitive to the particular growth scheme and full retention of the initial orientation, either along the [001] or [100] direction, was observed. This homo‐ and heteroepitaxial LbL growth allows full control over the orientation and the layer sequence, including introduction of functionalized linkers and pillars.

Bibliography

Zacher, D., Yusenko, K., BÃ©tard, A., Henke, S., Molon, M., Ladnorg, T., Shekhah, O., SchÃ¼pbach, B., deâlosâArcos, T., Krasnopolski, M., Meilikhov, M., Winter, J., Terfort, A., WÃ¶ll, C., & Fischer, R. A. (2011). LiquidâPhase Epitaxy of Multicomponent LayerâBased Porous Coordination Polymer Thin Films of [M(L)(P)0.5] Type: Importance of Deposition Sequence on the Oriented Growth. Chemistry â A European Journal, 17(5), 1448â1455. Portico.

Authors 15

Denise Zacher (first)
Kirill Yusenko (additional)
Angèlique Bétard (additional)
Sebastian Henke (additional)
Mariusz Molon (additional)
Tatjana Ladnorg (additional)
Osama Shekhah (additional)
Björn Schüpbach (additional)
Teresa de los Arcos (additional)
Michael Krasnopolski (additional)
Mikhail Meilikhov (additional)
Jörg Winter (additional)
Andreas Terfort (additional)
Christof Wöll (additional)
Roland A. Fischer (additional)

References 38 Referenced 161

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Dates

Type	When
Created	14 years, 7 months ago (Jan. 7, 2011, 7:22 a.m.)
Deposited	1 year, 10 months ago (Oct. 16, 2023, 5:29 a.m.)
Indexed	4 weeks, 2 days ago (July 24, 2025, 7:14 a.m.)
Issued	14 years, 7 months ago (Jan. 7, 2011)
Published	14 years, 7 months ago (Jan. 7, 2011)
Published Online	14 years, 7 months ago (Jan. 7, 2011)
Published Print	14 years, 6 months ago (Feb. 1, 2011)

Funders 0

None

BibTeX

@article{Zacher_2011, title={Liquid‐Phase Epitaxy of Multicomponent Layer‐Based Porous Coordination Polymer Thin Films of [M(L)(P)0.5] Type: Importance of Deposition Sequence on the Oriented Growth}, volume={17}, ISSN={1521-3765}, url={http://dx.doi.org/10.1002/chem.201002381}, DOI={10.1002/chem.201002381}, number={5}, journal={Chemistry – A European Journal}, publisher={Wiley}, author={Zacher, Denise and Yusenko, Kirill and Bétard, Angèlique and Henke, Sebastian and Molon, Mariusz and Ladnorg, Tatjana and Shekhah, Osama and Schüpbach, Björn and de los Arcos, Teresa and Krasnopolski, Michael and Meilikhov, Mikhail and Winter, Jörg and Terfort, Andreas and Wöll, Christof and Fischer, Roland A.}, year={2011}, month=jan, pages={1448–1455} }

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