DOI: 10.1002/chem.201002278. Cubic and Hexagonal Mesoporous Carbon in the Pores of Anodic Alumina Membranes

Cubic and Hexagonal Mesoporous Carbon in the Pores of Anodic Alumina Membranes

10.1002/chem.201002278

Crossref journal-article

Wiley

Chemistry – A European Journal (311)

Abstract

AbstractCubic and circular hexagonal mesoporous carbon phases in the confined environment of the pores of anodic alumina membranes (AAM) were obtained by organic–organic self‐assembly of a preformed oligomeric resol precursor and the triblock copolymer templates Pluronic F127 or P123, respectively. Casting and solvent evaporation were followed by self‐assembly and the formation of a condensed wall material by thermopolymerization of the precursor oligomers, thus resulting in mesostructured phenolic resin phases. Subsequent thermal decomposition of the surfactant and carbonization were achieved through thermal treatment at temperatures up to 1000 °C under an inert atmosphere. The resulting hierarchical mesoporous composite materials were characterized by small‐angle X‐ray scattering and nitrogen‐sorption measurements. The structural features were directly imaged in TEM cross‐sections of the composite membranes. For both structures, the AAM pores were completely filled and no shrinkage was observed due to strong adhesion of the carbon‐wall material to the AAM pore walls. As a consequence, the pore size of the mesophase system stays almost constant even after thermal treatment at 1000 °C.

Bibliography

Schuster, J., Keilbach, A., KÃ¶hn, R., DÃ¶blinger, M., DÃ¶rfler, T., Dennenwaldt, T., & Bein, T. (2011). Cubic and Hexagonal Mesoporous Carbon in the Pores of Anodic Alumina Membranes. Chemistry â A European Journal, 17(34), 9463â9470. Portico.

Authors 7

Jörg Schuster (first)
Andreas Keilbach (additional)
Ralf Köhn (additional)
Markus Döblinger (additional)
Thilo Dörfler (additional)
Teresa Dennenwaldt (additional)
Thomas Bein (additional)

References 38 Referenced 19

Dates

Type	When
Created	14 years, 1 month ago (July 5, 2011, 11:34 a.m.)
Deposited	1 year, 10 months ago (Oct. 16, 2023, 10:39 a.m.)
Indexed	1 year, 10 months ago (Oct. 17, 2023, 6:31 a.m.)
Issued	14 years, 1 month ago (July 5, 2011)
Published	14 years, 1 month ago (July 5, 2011)
Published Online	14 years, 1 month ago (July 5, 2011)
Published Print	14 years ago (Aug. 16, 2011)

Funders 0

None

BibTeX

@article{Schuster_2011, title={Cubic and Hexagonal Mesoporous Carbon in the Pores of Anodic Alumina Membranes}, volume={17}, ISSN={1521-3765}, url={http://dx.doi.org/10.1002/chem.201002278}, DOI={10.1002/chem.201002278}, number={34}, journal={Chemistry – A European Journal}, publisher={Wiley}, author={Schuster, Jörg and Keilbach, Andreas and Köhn, Ralf and Döblinger, Markus and Dörfler, Thilo and Dennenwaldt, Teresa and Bein, Thomas}, year={2011}, month=jul, pages={9463–9470} }

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