DOI: 10.1002/chem.200802385. Reversible Breaking and Forming of Metal–Ligand Coordination Bonds: Temperature‐Triggered Single‐Crystal to Single‐Crystal Transformation in a Metal

Reversible Breaking and Forming of Metal–Ligand Coordination Bonds: Temperature‐Triggered Single‐Crystal to Single‐Crystal Transformation in a Metal–Organic Framework

10.1002/chem.200802385

Crossref journal-article

Wiley

Chemistry – A European Journal (311)

Abstract

AbstractThe novel Yb succinate metal–organic frameworkexhibits a reversible single‐crystal to single‐crystal polymorphic transformation (see figure) when it is heated above 130 °C, returning to its initial form when back at room temperature. This transformation produces a change in the coordination sphere of the Yb atoms, which influences the catalytic activity of the material.magnified image[Yb(C4H4O4)1.5] undergoes a temperature‐triggered single‐crystal to single‐crystal transformation. Thermal X‐ray single‐crystal studies showed a reversibly orchestrated rearrangement of the atoms generated by the breaking/formation of coordination bonds, in which the stoichiometry of the compound remains unchanged. The transformation occurs on heating the crystal at ≈130 °C. This uncommon behavior was also studied by thermal methods, FTIR spectroscopy, and thermodiffractometry. Both polymorphs,α(room‐temperature form) andβ(high‐temperature form), are proven to be active heterogeneous catalysts; the higher catalytic activity ofβis owed to a decrease in the Yb coordination number. A mechanism based on spectroscopic evidence and involving formation of the active species YbOOH is proposed for the sulfide oxidation.

Authors 8

María C. Bernini (first)
Felipe Gándara (additional)
Marta Iglesias (additional)
Natalia Snejko (additional)
Enrique Gutiérrez‐Puebla (additional)
Elena V. Brusau (additional)
Griselda E. Narda (additional)
M. Ángeles Monge (additional)

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Dates

Type	When
Created	16 years, 4 months ago (March 25, 2009, 3:08 p.m.)
Deposited	6 months, 1 week ago (Feb. 8, 2025, 12:39 p.m.)
Indexed	3 months, 2 weeks ago (May 7, 2025, 4:11 a.m.)
Issued	16 years, 3 months ago (April 28, 2009)
Published	16 years, 3 months ago (April 28, 2009)
Published Online	16 years, 3 months ago (April 28, 2009)
Published Print	16 years, 3 months ago (May 4, 2009)

Funders 0

None

BibTeX

@article{Bernini_2009, title={Reversible Breaking and Forming of Metal–Ligand Coordination Bonds: Temperature‐Triggered Single‐Crystal to Single‐Crystal Transformation in a Metal–Organic Framework}, volume={15}, ISSN={1521-3765}, url={http://dx.doi.org/10.1002/chem.200802385}, DOI={10.1002/chem.200802385}, number={19}, journal={Chemistry – A European Journal}, publisher={Wiley}, author={Bernini, María C. and Gándara, Felipe and Iglesias, Marta and Snejko, Natalia and Gutiérrez‐Puebla, Enrique and Brusau, Elena V. and Narda, Griselda E. and Monge, M. Ángeles}, year={2009}, month=apr, pages={4896–4905} }

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