DOI: 10.1002/chem.200800503. Helicate Extension as a Route to Molecular Wires

Helicate Extension as a Route to Molecular Wires

10.1002/chem.200800503

Crossref journal-article

Wiley

Chemistry – A European Journal (311)

Abstract

AbstractWe describe the preparation of a helicate containing four closely spaced, linearly arrayed copper(I) ions. This product may be prepared either directly by mixing copper(I) with a set of precursor amine and aldehyde subcomponents, or indirectly through the dimerization of a dicopper(I) helicate upon addition of 1,2‐phenylenediamine. A notable feature of this helicate is that its length is not limited by the lengths of its precursor subcomponents: each of the two ligands wrapped around the four copper(I) centers contains one diamine, two dialdehyde, and two monoamine residues. This work thus paves the way for the preparation of longer oligo‐ and polymeric structures. DFT calculations and electrochemical measurements indicate a high degree of electronic delocalization among the metal ions forming the cores of the structures described herein, which may therefore be described as “molecular wires”.

Bibliography

Schultz, D., Biaso, F., Shahi, A. R. M., Geoffroy, M., Rissanen, K., Gagliardi, L., Cramer, C. J., & Nitschke, J. R. (2008). Helicate Extension as a Route to Molecular Wires. Chemistry â A European Journal, 14(24), 7180â7185. Portico.

Authors 8

David Schultz (first)
Frédéric Biaso (additional)
Abdul Rehaman Moughal Shahi (additional)
Michel Geoffroy (additional)
Kari Rissanen (additional)
Laura Gagliardi (additional)
Christopher J. Cramer (additional)
Jonathan R. Nitschke (additional)

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Dates

Type	When
Created	17 years, 1 month ago (July 9, 2008, 3:24 a.m.)
Deposited	1 year, 10 months ago (Oct. 16, 2023, 10:26 a.m.)
Indexed	1 year, 2 months ago (June 12, 2024, 3:54 a.m.)
Issued	17 years ago (Aug. 6, 2008)
Published	17 years ago (Aug. 6, 2008)
Published Online	17 years ago (Aug. 6, 2008)
Published Print	17 years ago (Aug. 18, 2008)

Funders 0

None

BibTeX

@article{Schultz_2008, title={Helicate Extension as a Route to Molecular Wires}, volume={14}, ISSN={1521-3765}, url={http://dx.doi.org/10.1002/chem.200800503}, DOI={10.1002/chem.200800503}, number={24}, journal={Chemistry – A European Journal}, publisher={Wiley}, author={Schultz, David and Biaso, Frédéric and Shahi, Abdul Rehaman Moughal and Geoffroy, Michel and Rissanen, Kari and Gagliardi, Laura and Cramer, Christopher J. and Nitschke, Jonathan R.}, year={2008}, month=aug, pages={7180–7185} }

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