DOI: 10.1002/chem.200400178. Benzene‐Templated Hydrothermal Synthesis of Metal–Organic Frameworks with Selective Sorption Properties

Benzene‐Templated Hydrothermal Synthesis of Metal–Organic Frameworks with Selective Sorption Properties

10.1002/chem.200400178

Crossref journal-article

Wiley

Chemistry – A European Journal (311)

Abstract

AbstractIn this paper, we report two metal–organic frameworks [Co3(ndc)3(bipyen)1.5]⋅H2O (1) and [Co2(ndc)2(bipyen)]⋅C6H6⋅H2O (2) (bipyen=trans‐1,2‐bis(4‐pyridyl)ethylene, H2ndc=2,6‐naphthalenedicarboxylic acid). These compounds were both synthesized from identical hydrothermal reaction conditions except that benzene was added to the reaction for 2. Crystal structures show that the two compounds have triply interpenetrated three‐dimensional frameworks and these frameworks have the same primary structure of a two‐dimensional network of interconnected [Co2(O2CR)4/2] (R=naphthalene group) paddle‐wheels and bridging bipyen ligands. Both compounds have guest water molecules and, in addition, 2 has guest benzene molecules. Structural transformations of the host accompanied guest removal, which can be monitored by powder X‐ray diffraction. N2 adsorption data of 2 show that there are two different types of pores corresponding to the benzene and water pores. Upon exposure to vapors of several organic molecules, the heat‐treated sample of 2 adsorbs benzene and cyclohexene, but does not adsorb toluene, (o‐, m‐, and p‐)xylenes, cycloheptatriene, or cyclohexane.

Bibliography

Choi, E., Park, K., Yang, C., Kim, H., Son, J., Lee, S. W., Lee, Y. H., Min, D., & Kwon, Y. (2004). BenzeneâTemplated Hydrothermal Synthesis of MetalâOrganic Frameworks with Selective Sorption Properties. Chemistry â A European Journal, 10(21), 5535â5540. Portico.

Authors 9

Eun‐Young Choi (first)
Kyungsoo Park (additional)
Cheol‐Min Yang (additional)
Hyejin Kim (additional)
Jung‐Ho Son (additional)
Soon W. Lee (additional)
Young Hee Lee (additional)
Dongwon Min (additional)
Young‐Uk Kwon (additional)

References 64 Referenced 156

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Dates

Type	When
Created	20 years, 10 months ago (Sept. 30, 2004, 6 a.m.)
Deposited	1 year, 10 months ago (Oct. 11, 2023, 8:39 a.m.)
Indexed	1 year, 2 months ago (June 18, 2024, 1:10 a.m.)
Issued	20 years, 10 months ago (Oct. 20, 2004)
Published	20 years, 10 months ago (Oct. 20, 2004)
Published Online	20 years, 10 months ago (Oct. 20, 2004)
Published Print	20 years, 9 months ago (Nov. 5, 2004)

Funders 0

None

BibTeX

@article{Choi_2004, title={Benzene‐Templated Hydrothermal Synthesis of Metal–Organic Frameworks with Selective Sorption Properties}, volume={10}, ISSN={1521-3765}, url={http://dx.doi.org/10.1002/chem.200400178}, DOI={10.1002/chem.200400178}, number={21}, journal={Chemistry – A European Journal}, publisher={Wiley}, author={Choi, Eun‐Young and Park, Kyungsoo and Yang, Cheol‐Min and Kim, Hyejin and Son, Jung‐Ho and Lee, Soon W. and Lee, Young Hee and Min, Dongwon and Kwon, Young‐Uk}, year={2004}, month=oct, pages={5535–5540} }

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