DOI: 10.1002/cctc.201403050. Synthesis of Sn‐Beta with Exclusive and High Framework Sn Content

Synthesis of Sn‐Beta with Exclusive and High Framework Sn Content

10.1002/cctc.201403050

Crossref journal-article

Wiley

ChemCatChem (311)

Abstract

AbstractSn‐Beta zeolite was prepared by acid dealumination of Beta zeolite, followed by dehydration and impregnation with anhydrous SnCl4. The formation of extraframework Sn (EFSn) species was prevented by the removal of unreacted SnCl4 in a methanol washing step prior to calcination. The resulting Sn‐Beta zeolites were characterized by X‐ray diffraction, Ar physisorption, NMR, UV/Vis, and FTIR spectroscopy. These well‐defined Lewis acid zeolites exhibit good catalytic activity and selectivity in the conversion of 1,3‐dihydroxyacetone to methyl lactate. Their performance is similar to a reference Sn‐Beta zeolite prepared by hydrothermal synthesis. Sn‐BEA zeolites that contain EFSn species exhibit lower catalytic activity; the EFSn species also catalyze formation of byproducts. DFT calculations show that partially hydrolyzed framework Sn‐OH species (open sites), rather than the tetrahedral framework Sn sites (closed sites), are the most likely candidate active sites for methyl lactate formation.

Bibliography

van der Graaff, W. N. P., Li, G., Mezari, B., Pidko, E. A., & Hensen, E. J. M. (2015). Synthesis of SnâBeta with Exclusive and High Framework Sn Content. ChemCatChem, 7(7), 1152â1160. Portico.

Authors 5

William N. P. van der Graaff (first)
Guanna Li (additional)
Brahim Mezari (additional)
Evgeny A. Pidko (additional)
Emiel J. M. Hensen (additional)

References 57 Referenced 113

Dates

Type	When
Created	10 years, 5 months ago (Feb. 27, 2015, 3:28 p.m.)
Deposited	1 year, 10 months ago (Oct. 16, 2023, 12:42 p.m.)
Indexed	1 month, 3 weeks ago (July 1, 2025, 8:35 a.m.)
Issued	10 years, 5 months ago (Feb. 27, 2015)
Published	10 years, 5 months ago (Feb. 27, 2015)
Published Online	10 years, 5 months ago (Feb. 27, 2015)
Published Print	10 years, 4 months ago (April 7, 2015)

Funders 3

Netherlands Organization for Scientific Research (NWO)
Chinese Ministry of Science and Technology 10.13039/501100002855 Ministry of Science and Technology of the People's Republic of China
Region: Asia
gov (National government)
Labels6
1. Chinese Ministry of Science and Technology
2. Ministry of Science & Technology, People Republic of China
3. 中华人民共和国科学技术部
4. Ministry of Science and Technology (China)
5. State Science and Technology Commission
6. MOST
European Union 10.13039/501100000780 European Commission
Region: Europe
gov (National government)
Labels26
1. European Union
2. Comisión Europea
3. Europäische Kommission
4. EU-Kommissionen
5. Euroopa Komisjoni
6. Ευρωπαϊκής Επιτροπής
7. Европейската комисия
8. Evropské komise
9. Commission européenne
10. Choimisiúin Eorpaigh
11. Europskoj komisiji
12. Commissione europea
13. La Commissione europea
14. Eiropas Komisiju
15. Europos Komisijos
16. Európai Bizottságról
17. Europese Commissie
18. Komisja Europejska
19. Comissão Europeia
20. Comisia Europeană
21. Európskej komisii
22. Evropski komisiji
23. Euroopan komission
24. Europeiska kommissionen
25. EC
26. EU
Awards1
1. FP7-NMP-2013-EU-Japan-604319

BibTeX

@article{van_der_Graaff_2015, title={Synthesis of Sn‐Beta with Exclusive and High Framework Sn Content}, volume={7}, ISSN={1867-3899}, url={http://dx.doi.org/10.1002/cctc.201403050}, DOI={10.1002/cctc.201403050}, number={7}, journal={ChemCatChem}, publisher={Wiley}, author={van der Graaff, William N. P. and Li, Guanna and Mezari, Brahim and Pidko, Evgeny A. and Hensen, Emiel J. M.}, year={2015}, month=feb, pages={1152–1160} }

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