DOI: 10.1002/cctc.201402864. Improving Oxygen Electrochemistry through Nanoscopic Confinement

Improving Oxygen Electrochemistry through Nanoscopic Confinement

10.1002/cctc.201402864

Crossref journal-article

Wiley

ChemCatChem (311)

Abstract

AbstractOxygen evolution and reduction offer a promising method of grid‐level energy storage that could facilitate widespread adaptation of solar and wind power. However, the efficiency of these technologies is fundamentally limited by high overpotentials, which stem from correlations between adsorption energies of different reaction intermediates. We propose a scheme to circumvent these scaling relationships by defining a three‐dimensional nanoscopic catalyst structure that capitalizes on different interactions between the intermediates and the catalyst owing to confinement. These nanoscopic channels reduce the theoretical overpotential for oxygen evolution on RuO2 by over 200 mV, corresponding to a 10 % increase in theoretical catalyst efficiency compared with a two‐dimensional RuO2 surface. This approach may hold promise for other oxygen‐evolution catalysts or, more broadly, to other reactions limited by (intermediate) adsorption‐energy scaling relationships.

Bibliography

Doyle, A. D., Montoya, J. H., & Vojvodic, A. (2015). Improving Oxygen Electrochemistry through Nanoscopic Confinement. ChemCatChem, 7(5), 738â742. Portico.

Authors 3

Andrew D. Doyle (first)
Joseph H. Montoya (additional)
Aleksandra Vojvodic (additional)

References 34 Referenced 124

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{'key': 'e_1_2_4_24_2', 'first-page': '1032', 'volume': '119', 'author': 'Siahrostami S.', 'year': '2014', 'journal-title': 'J. Phys. Chem.'} / J. Phys. Chem. by Siahrostami S. (2014)
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Dates

Type	When
Created	10 years, 6 months ago (Jan. 30, 2015, 4:28 p.m.)
Deposited	1 year, 10 months ago (Oct. 16, 2023, 4:43 a.m.)
Indexed	2 days, 7 hours ago (Aug. 23, 2025, 1:11 a.m.)
Issued	10 years, 6 months ago (Jan. 30, 2015)
Published	10 years, 6 months ago (Jan. 30, 2015)
Published Online	10 years, 6 months ago (Jan. 30, 2015)
Published Print	10 years, 5 months ago (March 1, 2015)

Funders 0

None

BibTeX

@article{Doyle_2015, title={Improving Oxygen Electrochemistry through Nanoscopic Confinement}, volume={7}, ISSN={1867-3899}, url={http://dx.doi.org/10.1002/cctc.201402864}, DOI={10.1002/cctc.201402864}, number={5}, journal={ChemCatChem}, publisher={Wiley}, author={Doyle, Andrew D. and Montoya, Joseph H. and Vojvodic, Aleksandra}, year={2015}, month=jan, pages={738–742} }

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