DOI: 10.1002/cber.19961291007. Synthesis and X‐ray Crystal Structure of the First Mononuclear Nickel(II) Alkane Thiolate Complex with a Mixed (S,N,N,O) Ligand Field

Synthesis and X‐ray Crystal Structure of the First Mononuclear Nickel(II) Alkane Thiolate Complex with a Mixed (S,N,N,O) Ligand Field

10.1002/cber.19961291007

Crossref journal-article

Wiley

Chemische Berichte (311)

Abstract

AbstractThe six‐step synthesis of a chiral, pentadentate dihydrosalen ligand, carrying a mercaptomethyl group as additional binding site, is described. When this ligand was treated with nickel(II) salts, a planar tetracoordinated nickel chelate was obtained, and not the expected pentacoordinated species. This complex was fully characterized, including X‐ray crystallography. The crystal structure revealed that the nickel ion is coordinated by the thiolate anion, both the amine and the imine nitrogen atoms of the ligand, and by one phenolate anion. The second phenolic oxygen atom of the ligand does not participate in the coordination of the nickel ion. This chelate is the first mononuclear nickel(II) thiolate complex having a mixed (S,N,N,O) ligand field. Cyclic voltammetry did not indicate a reduction up to –2.1 V (vs. Fc/Fc+). In the anodic range, no reversible but two irreversible oxidation processes were observed.

Bibliography

Berkessel, A., Bolte, M., Neumann, T., & Seidel, L. (1996). Synthesis and Xâray Crystal Structure of the First Mononuclear Nickel(II) Alkane Thiolate Complex with a Mixed (S,N,N,O) Ligand Field. Chemische Berichte, 129(10), 1183â1189. Portico.

Authors 4

Albrecht Berkessel (first)
Michael Bolte (additional)
Thomas Neumann (additional)
Lutz Seidel (additional)

References 26 Referenced 26

10.1002/9780470166420.ch7
10.1021/cr00032a008
{'key': 'e_1_2_1_1_4', 'first-page': '173', 'volume': '9', 'author': 'Kovacs J. A.', 'year': '1992', 'journal-title': 'Adv. Inorg. Biochem.'} / Adv. Inorg. Biochem. by Kovacs J. A. (1992)
10.1016/0045-2068(91)90047-S
10.1002/ange.19931051211
10.1002/anie.199317771
10.1007/978-3-322-94722-2
10.1016/0005-2728(94)90036-1
10.1016/S0040-4039(00)74088-3
– [5b]A.Berkessel M.Frauenkron T.Schwenkreis A.Steinmetz G.Baum D.Fenske J. Mol. Cata. in press
10.1002/ange.19951072011
10.1002/anie.199522471
10.1038/373580a0
10.1021/ja00066a032
– [7b]C.Bagyinka J. P.Whitehead M. J.Maroney J. Am. Chem. Soc.1993 3576–3585. (10.1021/ja00062a022)
A.Berkessel M.Bolte T.Neumann L.Seidel paper in preparation.
10.1002/anie.199107691
10.1021/cr00044a003
10.1016/S0010-8545(00)80092-2
{'key': 'e_1_2_1_11_2', 'first-page': '1368', 'volume': '50', 'author': 'Bolte M.', 'year': '1994', 'journal-title': 'Acta Cryst.'} / Acta Cryst. by Bolte M. (1994)
10.1002/cber.19951280207
{'key': 'e_1_2_1_13_2', 'first-page': '5127', 'volume-title': 'Beilsteins Handbuch der Organischen Chemie', 'year': '1979'} / Beilsteins Handbuch der Organischen Chemie (1979)
10.1002/recl.19320510513
10.1021/jo00041a054
10.1039/p19800001862
10.1039/p19780000318

Dates

Type	When
Created	18 years, 1 month ago (July 2, 2007, 6:12 p.m.)
Deposited	1 year, 10 months ago (Oct. 17, 2023, 2:12 a.m.)
Indexed	2 months ago (June 27, 2025, 9:25 a.m.)
Issued	28 years, 11 months ago (Oct. 1, 1996)
Published	28 years, 11 months ago (Oct. 1, 1996)
Published Online	19 years, 7 months ago (Jan. 25, 2006)
Published Print	28 years, 11 months ago (Oct. 1, 1996)

Funders 0

None

BibTeX

@article{Berkessel_1996, title={Synthesis and X‐ray Crystal Structure of the First Mononuclear Nickel(II) Alkane Thiolate Complex with a Mixed (S,N,N,O) Ligand Field}, volume={129}, ISSN={0009-2940}, url={http://dx.doi.org/10.1002/cber.19961291007}, DOI={10.1002/cber.19961291007}, number={10}, journal={Chemische Berichte}, publisher={Wiley}, author={Berkessel, Albrecht and Bolte, Michael and Neumann, Thomas and Seidel, Lutz}, year={1996}, month=oct, pages={1183–1189} }

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