DOI: 10.1002/cber.19620951220. Über katalytische Oxydationen, XIX. Konformationsanalyse und selektive katalytische Oxydationen von Pentopyranosiden zu Pentopyranosidulosen

Über katalytische Oxydationen, XIX. Konformationsanalyse und selektive katalytische Oxydationen von Pentopyranosiden zu Pentopyranosidulosen

10.1002/cber.19620951220

Crossref journal-article

Wiley

Chemische Berichte (311)

Abstract

AbstractMittels‐katalytischer Oxydation mit Sauerstoff am Platinkontakt lassen sich Benzyl‐β‐d‐arabopyranosid in Benzyl‐β‐d‐threo‐pentopyranosid‐4‐ulose (II), Benzyl‐β‐d‐ribopyranosid in Benzyl‐β‐d‐erythro‐pentopyranosid‐3‐ulose (IV), Benzyl‐α‐d‐lyxopyranosid in Benzyl‐α‐d‐threo‐pentopyranosid‐3‐ulose (VI) und Benzyl‐α‐d‐xylopyranosid in Benzyl‐α‐l‐threo‐pentopyranosid‐4‐ulose (VIII) überführen. Die Oxydation erfolgt nur an axialen Hydroxylgruppen und entspricht unter Einbeziehung entsprechender Konformationsbetrachtungen in ihrer Selektivität den für die Inositreihe aufgestellten Oxydationsregeln. Die katalytische Oxydation führt bei pH‐Werten über 7.2 bei allen Pentopyranosiden unter bevorzugter CC‐Spaltung zwischen den C‐Atomen 3 und 4 zur Dicarbonsäure XIII.

Bibliography

Heyns, K., Lenz, J., & Paulsen, H. (1962). Ãber katalytische Oxydationen, XIX. Konformationsanalyse und selektive katalytische Oxydationen von Pentopyranosiden zu Pentopyranosidulosen. Chemische Berichte, 95(12), 2964â2975. Portico.

Authors 3

Kurt Heyns (first)
Jügen Lenz (additional)
Hans Paulsen (additional)

References 20 Referenced 20

{'key': 'e_1_2_1_1_2', 'first-page': '2660', 'volume': '95', 'author': 'Heyns K.', 'year': '1962', 'journal-title': 'Angew. Chem.'} / Angew. Chem. by Heyns K. (1962)
{'key': 'e_1_2_1_2_2', 'first-page': '600', 'volume': '69', 'author': 'Heyns K.', 'year': '1957', 'journal-title': 'Chem. Ber.'} / Chem. Ber. by Heyns K. (1957)
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Dates

Type	When
Created	18 years, 3 months ago (May 23, 2007, 9:08 p.m.)
Deposited	1 year, 9 months ago (Nov. 22, 2023, 3:21 p.m.)
Indexed	1 year, 5 months ago (March 20, 2024, 5:59 a.m.)
Issued	62 years, 9 months ago (Dec. 1, 1962)
Published	62 years, 9 months ago (Dec. 1, 1962)
Published Online	19 years, 7 months ago (Jan. 21, 2006)
Published Print	62 years, 9 months ago (Dec. 1, 1962)

Funders 0

None

BibTeX

@article{Heyns_1962, title={Über katalytische Oxydationen, XIX. Konformationsanalyse und selektive katalytische Oxydationen von Pentopyranosiden zu Pentopyranosidulosen}, volume={95}, ISSN={0009-2940}, url={http://dx.doi.org/10.1002/cber.19620951220}, DOI={10.1002/cber.19620951220}, number={12}, journal={Chemische Berichte}, publisher={Wiley}, author={Heyns, Kurt and Lenz, Jügen and Paulsen, Hans}, year={1962}, month=dec, pages={2964–2975} }

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