DOI: 10.1002/bscb.19580670706. Etude Geometrique de L'Adsorption Sur Quelques Faces Cristallographiques Simples Interpretation des Deux Adsorptions de L'Hydrogene Sur Les Surfaces Metalliques Nues

Etude Geometrique de L'Adsorption Sur Quelques Faces Cristallographiques Simples Interpretation des Deux Adsorptions de L'Hydrogene Sur Les Surfaces Metalliques Nues

10.1002/bscb.19580670706

Crossref journal-article

Wiley

Bulletin des Sociétés Chimiques Belges (311)

Abstract

AbstractGeometric definition of the sites and site lattices for square, hexagonal and pseudo‐hexagonal faces. It is shown that the site lattices do not necessarily have the same symmetry as the lattice formed by the surface metal atoms. This provides possibilities for recognizing the type of site effectively used in a given film.It is suggested that on bare metal surfaces hydrogen atoms are adsorbed over the deepest regions of the periodic surface (sites b or d). The negative adsorption is the adsorption of one hydrogen atom per metal atom. For some faces there are two sites per metal atom. A second H‐atom may then be adsorbed but it inevitably interacts with preadsorbed neighbours. The interaction involves partial lateral bonding between the H‐atoms together with a loosening of the bonds holding the preadsorbed atoms to the surface. The application of these ideas in the field of adsorption and catalysis is briefly outlined.

Bibliography

Mignolet, J. C. P. (1958). Etude Geometrique de LâAdsorption Sur Quelques Faces Cristallographiques Simples Interpretation des Deux Adsorptions de LâHydrogene Sur Les Surfaces Metalliques Nues. Bulletin Des SociÃ©tÃ©s Chimiques Belges, 67(7â8), 358â372. Portico.

Authors 1

J. C. P. Mignolet (first)

References 19 Referenced 13

10.1039/df9500800105
10.1002/recl.19550740610
{'key': 'e_1_2_1_3_2', 'volume': '241', 'author': 'Mignolet J. C. P.', 'year': '1956', 'journal-title': '6e Réunion de la Société de Chimie Physique'} / 6e Réunion de la Société de Chimie Physique by Mignolet J. C. P. (1956)
J. K.Roberts Some Problems in Adsorption.
G. C.Bond Conversation lors du symposium de la «Chemical Society» Keele 1956.
{'key': 'e_1_2_1_6_2', 'first-page': '52', 'volume-title': 'Chemisorption', 'author': 'de Boer J. H.'} / Chemisorption by de Boer J. H.
J. C. P.Mignolet Thèse de doctorat Liège p.44.
10.1063/1.1739911
10.1021/ie50509a023
10.1002/bscb.19550640303
10.1002/bscb.19560650906
W. M. H.SachtleretG. J. H.Dorgelo 6eRéunion de la Société de Chimie Physique 249 1956.
{'key': 'e_1_2_1_12_2', 'volume': '551', 'author': 'Langmuir I.', 'year': '1940', 'journal-title': 'J. Chem. Soc.'} / J. Chem. Soc. by Langmuir I. (1940)
10.1063/1.4757212
10.1098/rspa.1953.0078
{'key': 'e_1_2_1_14_2', 'first-page': '152', 'volume-title': 'Chemisorption', 'author': 'Gundry P. M.', 'year': '1957'} / Chemisorption by Gundry P. M. (1957)
10.1039/df9500800114
{'key': 'e_1_2_1_16_2', 'first-page': '176', 'author': 'Exemple P.', 'journal-title': 'Advances in Catalysis'} / Advances in Catalysis by Exemple P.
{'key': 'e_1_2_1_17_2', 'first-page': '39', 'volume-title': 'Chemisorption', 'author': 'Schuit G. C. A.', 'year': '1957'} / Chemisorption by Schuit G. C. A. (1957)

Dates

Type	When
Created	14 years, 11 months ago (Sept. 13, 2010, 10:38 a.m.)
Deposited	2 years ago (Aug. 31, 2023, 4:20 a.m.)
Indexed	1 year, 6 months ago (Feb. 8, 2024, 9:41 p.m.)
Issued	67 years, 8 months ago (Jan. 1, 1958)
Published	67 years, 8 months ago (Jan. 1, 1958)
Published Online	15 years ago (Sept. 1, 2010)
Published Print	67 years, 8 months ago (Jan. 1, 1958)

Funders 0

None

BibTeX

@article{Mignolet_1958, title={Etude Geometrique de L’Adsorption Sur Quelques Faces Cristallographiques Simples Interpretation des Deux Adsorptions de L’Hydrogene Sur Les Surfaces Metalliques Nues}, volume={67}, ISSN={0037-9646}, url={http://dx.doi.org/10.1002/bscb.19580670706}, DOI={10.1002/bscb.19580670706}, number={7–8}, journal={Bulletin des Sociétés Chimiques Belges}, publisher={Wiley}, author={Mignolet, J. C. P.}, year={1958}, month=jan, pages={358–372} }

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