DOI: 10.1002/bip.1976.360150104. Irreversible thermodynamic analysis of electrophoretic light scattering experiments

Irreversible thermodynamic analysis of electrophoretic light scattering experiments

10.1002/bip.1976.360150104

Crossref journal-article

Wiley

Biopolymers (311)

Abstract

AbstractA fluctuation theory for electrolyte solutions is developed based on the coupling between the equations of nonequilibrium thermodynamics and the Poisson equation. The resulting fluctuation theory is applied to the analysis of electrophoretic light scattering. It is shown that in a binary electrolyte solution (two ionic species), the Doppler shift is not determined by the electrical mobility of either ion, but depends instead on the rate of change of transference number with salt concentration. In addition the ionic relaxation time is shown to be proportional to the conductivity of the solution.

Bibliography

Friedhoff, L., & Berne, B. J. (1976). Irreversible thermodynamic analysis of electrophoretic light scattering experiments. Biopolymers, 15(1), 21â28. Portico.

Authors 2

L. Friedhoff (first)
B. J. Berne (additional)

References 8 Referenced 12

10.1016/0009-2614(71)80621-8
10.1063/1.1682145
10.4159/harvard.9780674494121
Berne B. J.&Pecora R.(1975)Dynamic Light Scattering With Applications to Biology Chemistry and Physics Wiley New York in press.
{'key': 'e_1_2_1_6_2', 'volume-title': 'Physical Chemistry of Macromolecules', 'author': 'Tanford C.', 'year': '1961'} / Physical Chemistry of Macromolecules by Tanford C. (1961)
10.1098/rspa.1931.0133
{'key': 'e_1_2_1_8_2', 'volume-title': 'The Physical Chemistry of Electrolyte Solutions', 'author': 'Harned H. S.', 'year': '1958'} / The Physical Chemistry of Electrolyte Solutions by Harned H. S. (1958)
{'key': 'e_1_2_1_8_3', 'volume-title': 'Electrolyte Solutions', 'author': 'Stokes L. H.', 'year': '1959'} / Electrolyte Solutions by Stokes L. H. (1959)

Dates

Type	When
Created	20 years, 8 months ago (Dec. 29, 2004, 7:50 p.m.)
Deposited	1 year, 10 months ago (Oct. 19, 2023, 12:38 a.m.)
Indexed	1 year, 6 months ago (Feb. 10, 2024, 1:22 a.m.)
Issued	49 years, 8 months ago (Jan. 1, 1976)
Published	49 years, 8 months ago (Jan. 1, 1976)
Published Online	21 years, 7 months ago (Feb. 1, 2004)
Published Print	49 years, 8 months ago (Jan. 1, 1976)

Funders 0

None

BibTeX

@article{Friedhoff_1976, title={Irreversible thermodynamic analysis of electrophoretic light scattering experiments}, volume={15}, ISSN={1097-0282}, url={http://dx.doi.org/10.1002/bip.1976.360150104}, DOI={10.1002/bip.1976.360150104}, number={1}, journal={Biopolymers}, publisher={Wiley}, author={Friedhoff, L. and Berne, B. J.}, year={1976}, month=jan, pages={21–28} }

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