DOI: 10.1002/bip.1968.360060610. General theoretical approach to the thermodynamic and kinetic properties of cooperative intramolecular transformations of linear biopolymers

General theoretical approach to the thermodynamic and kinetic properties of cooperative intramolecular transformations of linear biopolymers

10.1002/bip.1968.360060610

Crossref journal-article

Wiley

Biopolymers (311)

Abstract

AbstractA general method to calculate experimentally accessible thermodynamic and kinetic quantities for any type of cooperative transitions is developed. Special attention has been directed to transition curves and mean relaxation times. The procedure is applied to the most general case of nearest‐neighbor cooperativity by using the linear Ising model and the matrix method of evaluation. The various potential types of end effects arid the resulting chain length dependences are discussed in detail. The significance of the theory with respect to the helix‐coil transition of polypeptides as well as to the polyproline I‐II transition is indicated.

Bibliography

Schwarz, G. (1968). General theoretical approach to the thermodynamic and kinetic properties of cooperative intramolecular transformations of linear biopolymers. Biopolymers, 6(6), 873â897. Portico.

Authors 1

Gerhard Schwarz (first)

References 25 Referenced 87

{'key': 'e_1_2_1_2_2', 'first-page': '403', 'volume-title': 'Conformation of Biopolymers', 'author': 'Applequist J.', 'year': '1967'} / Conformation of Biopolymers by Applequist J. (1967)
10.1002/bip.1967.360050502
10.1146/annurev.pc.12.100161.002245
10.1002/pol.1961.1205516101
10.1021/ja01067a004
10.1063/1.1730390
10.1063/1.1731802
10.1002/bip.1967.360050309
10.1002/bip.360030605
10.1002/bip.1966.360040103
10.1143/JPSJ.22.416
10.1103/RevModPhys.40.206
10.1002/bbpc.19640680838
10.1016/S0022-2836(65)80171-1
10.1007/BF02980577
G.Schwarz Habilitation Thesis Technische Hochschule Braunschweig 1966.
10.1103/PhysRev.60.252
J.Applequist circulated preprint;Biopolymers in press.
{'key': 'e_1_2_1_20_2', 'first-page': '381', 'volume-title': 'Conformation of Biopolymers', 'author': 'Ptitsyn O. B.', 'year': '1967'} / Conformation of Biopolymers by Ptitsyn O. B. (1967)
10.1021/j100871a045
G.Schwarz inMolecular Relaxation Processes Chemical Society Special Publication No. 20 London 1966 p.191.
G.SchwarzandJ.Seelig Biopolymers in press.
10.1002/bip.1966.360040809
J.EngelandV.Ganser unpublished results
J.Engel Habilitation Thesis universität München 1967.

Dates

Type	When
Created	20 years, 8 months ago (Dec. 30, 2004, 10:29 p.m.)
Deposited	1 year, 9 months ago (Nov. 12, 2023, 7:29 a.m.)
Indexed	1 week ago (Aug. 30, 2025, 12:24 p.m.)
Issued	57 years, 3 months ago (June 1, 1968)
Published	57 years, 3 months ago (June 1, 1968)
Published Online	21 years, 7 months ago (Feb. 1, 2004)
Published Print	57 years, 3 months ago (June 1, 1968)

Funders 0

None

BibTeX

@article{Schwarz_1968, title={General theoretical approach to the thermodynamic and kinetic properties of cooperative intramolecular transformations of linear biopolymers}, volume={6}, ISSN={1097-0282}, url={http://dx.doi.org/10.1002/bip.1968.360060610}, DOI={10.1002/bip.1968.360060610}, number={6}, journal={Biopolymers}, publisher={Wiley}, author={Schwarz, Gerhard}, year={1968}, month=jun, pages={873–897} }

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