DOI: 10.1002/bbpc.19971010202. Multidimensional solid state NMR: A unique tool for the characterisation of complex materials

Multidimensional solid state NMR: A unique tool for the characterisation of complex materials

10.1002/bbpc.19971010202

Crossref journal-article

Wiley

Berichte der Bunsengesellschaft für physikalische Chemie (311)

Abstract

AbstractA survey is given on new developments in multidimensional solid state NMR which evolves as an indispensable tool of materials characterisation. After a short introduction NMR is compared with other techniques, in particular X‐ray and neutron scattering. The unique information available by solid state NMR is demonstrated by specific examples of structural studies of chain conformation, advanced aspects of chain dynamics, phase separation and interfacial effects as well as non‐linear plastic deformation in polymers. Emphasis is placed on the new development of high resolution multiple quantum NMR spectroscopy of abundant nuclei in solids with first experimental examples on the location of hydrogen positions in organic solids, structure of inorganic glasses and chain order in polymer melts and elastomers.

Bibliography

Spiess, H. W. (1997). Multidimensional solid state NMR: A unique tool for the characterisation of complex materials. Berichte Der Bunsengesellschaft FÃ¼r Physikalische Chemie, 101(2), 153â168. Portico.

Authors 1

Hans Wolfgang Spiess (first)

References 68 Referenced 22

{'key': 'e_1_2_1_2_2', 'volume-title': 'Polymere Werkstoffe', 'author': 'Batzer H.', 'year': '1984'} / Polymere Werkstoffe by Batzer H. (1984)
{'key': 'e_1_2_1_3_2', 'volume-title': 'Concise Encyclopedia of Polymer Science and Technology', 'author': 'Kroschwitz J. I.', 'year': '1990'} / Concise Encyclopedia of Polymer Science and Technology by Kroschwitz J. I. (1990)
{'key': 'e_1_2_1_4_2', 'volume-title': 'Polymer Characterization', 'author': 'Campbell D.', 'year': '1989'} / Polymer Characterization by Campbell D. (1989)
{'key': 'e_1_2_1_5_2', 'volume-title': 'Principles of Nuclear Magnetic Resonance in One and Two Dimensions', 'author': 'Ernst R. R.', 'year': '1987'} / Principles of Nuclear Magnetic Resonance in One and Two Dimensions by Ernst R. R. (1987)
{'key': 'e_1_2_1_6_2', 'volume-title': 'Multidimensional Solid‐State NMR and Polymers', 'author': 'Schmidt‐Rohr K.', 'year': '1994'} / Multidimensional Solid‐State NMR and Polymers by Schmidt‐Rohr K. (1994)
10.1016/0009-2614(94)00789-6
10.1016/0009-2614(95)00872-2
10.1007/978-3-642-57871-7
{'key': 'e_1_2_1_10_2', 'volume-title': 'X‐ray Scattering of Synthetic Polymers', 'author': 'Baltá‐Calleja F. J.', 'year': '1989'} / X‐ray Scattering of Synthetic Polymers by Baltá‐Calleja F. J. (1989)
{'key': 'e_1_2_1_11_2', 'volume-title': 'Theory of Neutron Scattering', 'author': 'Lovesey S. W.', 'year': '1984'} / Theory of Neutron Scattering by Lovesey S. W. (1984)
{'key': 'e_1_2_1_12_2', 'volume-title': 'Dynamic Light Scattering', 'author': 'Berne B. J.', 'year': '1976'} / Dynamic Light Scattering by Berne B. J. (1976)
10.1063/1.450032
10.1093/oso/9780198539445.001.0001 / Principles of Nuclear Magnetic Resonance Microscopy by Callaghan P. T. (1991)
10.1017/CBO9780511525278
{'key': 'e_1_2_1_16_2', 'volume-title': 'NMR Spectroscopy and Polymer Microstructure: The Conformational Connection', 'author': 'Tonelli A. E.', 'year': '1989'} / NMR Spectroscopy and Polymer Microstructure: The Conformational Connection by Tonelli A. E. (1989)
10.1002/actp.1994.010450304
10.1021/ma00084a035
10.1021/ma00127a028
{'key': 'e_1_2_1_20_2', 'volume-title': 'Conformational Theory of Large Molecules', 'author': 'Mattice W. L.', 'year': '1994'} / Conformational Theory of Large Molecules by Mattice W. L. (1994)
10.1002/9780470125793 / Reviews in Computational Chemistry by Lipkowitz K. B. (1991)
10.1007/978-3-642-75932-1_3
10.1007/978-3-642-60644-1_1
10.1016/0926-2040(95)01207-9
10.1119/1.1937646
10.1007/978-3-642-79127-7_1
10.1021/ma00099a038
M.Tomaselli P.Robyr B. H.Meier C.Grob‐Pisano R. R.Ernst andU. W.Suter Mol. Phys. in press.
10.1021/ma00059a036
10.1080/00268979500100691
10.1016/B978-0-12-025511-5.50009-8
10.1002/9780470142929.ch1
10.1006/jmra.1995.1068
10.1016/0009-2614(96)00558-1
10.1021/cr00007a013
10.1007/978-3-642-79127-7_3
10.1016/0022-3093(94)90402-2
10.1021/ja9619871
{'key': 'e_1_2_1_39_2', 'volume-title': 'Structure and Properties of Oriented Polymers', 'author': 'Ward I. M.', 'year': '1996'} / Structure and Properties of Oriented Polymers by Ward I. M. (1996)
10.1021/ma00061a022
10.1063/1.472511
10.1103/PhysRevLett.75.2851
A.Heuer Phys. Rev. E. submitted.
10.1063/1.471121
10.1209/epl/i1996-00186-5
10.1016/0009-2614(93)E1251-B
10.1021/ma00128a036
10.1063/1.470551
B.Schiener A.Loidl R.Böhmer andR. V.Chamberlain submitted.
J. P.Cohen‐Addad in:Progress in NMR Spectroscopy ed. by J.W. Emsley J. Feeney and L.H. Sutcliffe 25 1(1993). (10.1016/0079-6565(93)80004-D)
10.1021/ma00206a034
10.1021/ma00209a021
10.1063/1.472926
10.1063/1.460723
10.1021/ma00098a008
10.1021/ma00089a032
10.1002/actp.1993.010440101
10.1002/masy.19900350119
10.1021/ma00013a007
10.1002/macp.1995.021960401
10.1021/ma960095i
10.1163/156856294X00518
10.1007/978-94-010-2355-9 / The Physics of Glassy Polymers by Howard R. N. (1973)
{'key': 'e_1_2_1_64_2', 'volume-title': 'Magnetic Resonance Microscopy: Methods and Applications in Materials Science, Agriculture and Biomedicine', 'author': 'Blümich B.', 'year': '1992'} / Magnetic Resonance Microscopy: Methods and Applications in Materials Science, Agriculture and Biomedicine by Blümich B. (1992)
10.1021/ma00122a052
10.1002/adma.19960080604
10.1103/PhysRevLett.16.1097
10.1021/ma00145a012
{'key': 'e_1_2_1_69_2', 'first-page': '351', 'volume-title': 'Catalyst Design for Taylor‐made Polyolefins', 'author': 'Böhm L. L.', 'year': '1994'} / Catalyst Design for Taylor‐made Polyolefins by Böhm L. L. (1994)

Dates

Type	When
Created	13 years, 1 month ago (July 26, 2012, 3:30 a.m.)
Deposited	1 year, 4 months ago (April 27, 2024, 9:29 a.m.)
Indexed	1 month ago (July 28, 2025, 6:03 p.m.)
Issued	28 years, 7 months ago (Feb. 1, 1997)
Published	28 years, 7 months ago (Feb. 1, 1997)
Published Online	15 years, 2 months ago (June 22, 2010)
Published Print	28 years, 7 months ago (Feb. 1, 1997)

Funders 0

None

BibTeX

@article{Spiess_1997, title={Multidimensional solid state NMR: A unique tool for the characterisation of complex materials}, volume={101}, ISSN={0005-9021}, url={http://dx.doi.org/10.1002/bbpc.19971010202}, DOI={10.1002/bbpc.19971010202}, number={2}, journal={Berichte der Bunsengesellschaft für physikalische Chemie}, publisher={Wiley}, author={Spiess, Hans Wolfgang}, year={1997}, month=feb, pages={153–168} }

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      "URL": "https://onlinelibrary.wiley.com/doi/10.1002/bbpc.19971010202"
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  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
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      ]
    ]
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  "journal-issue": {
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  "ISSN": [
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  "subject": [],
  "container-title-short": "Ber Bunsenges Phys Chem",
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}