DOI: 10.1002/bbpc.19940980309. Two‐dimensional phase transitions in electrochemically formed adlayers on gold

Two‐dimensional phase transitions in electrochemically formed adlayers on gold

10.1002/bbpc.19940980309

Crossref journal-article

Wiley

Berichte der Bunsengesellschaft für physikalische Chemie (311)

Abstract

AbstractTwo‐dimensional phase transitions occurring during electrodeposition of the first Cu monolayer onto Au(111) at underpotentials or during adsorption of coumarin from solution at Au(111) and the reconstructed Au(100)‐ (hex) electrodes have been studied by cyclic voltammetry and potential step experiments. Rising current transients were observed for both systems, indicating the presence of nucleation‐and‐growth phenomena during monolayer formation. However, phase transitions in the adlayers were observed only for the densely packed gold surfaces, and not for the more open surfaces of Au(100)‐(1×1) or Au(110). A comparison between experiment and classical model transients revealed that surface imperfections may have to be taken into account when working with solid electrodes, rather than with mercury for which these models have been derived.

Bibliography

HÃ¶lzle, M. H., & Kolb, D. M. (1994). Twoâdimensional phase transitions in electrochemically formed adlayers on gold. Berichte Der Bunsengesellschaft FÃ¼r Physikalische Chemie, 98(3), 330â335. Portico.

Authors 2

M. H. Hölzle (first)
D. M. Kolb (additional)

References 53 Referenced 51

10.1002/bbpc.19860900303
{'key': 'e_1_2_1_3_2', 'first-page': '221', 'volume': '37', 'author': 'Ertl G.', 'year': '1990', 'journal-title': 'Adv. Catalysis'} / Adv. Catalysis by Ertl G. (1990)
10.1016/S0022-0728(81)80125-8
10.1007/978-94-009-4694-1_8
{'key': 'e_1_2_1_6_2', 'volume-title': 'Adsorption of Molecules at Metal Electrodes', 'author': 'Buess‐Herman C.', 'year': '1992'} / Adsorption of Molecules at Metal Electrodes by Buess‐Herman C. (1992)
10.1063/1.1750380
10.1063/1.1750631
10.1063/1.1750872
10.1039/tf9625802200
{'key': 'e_1_2_1_9_2', 'first-page': '123', 'volume-title': 'Advances of Electrochemistry and Electrochemical Engineering', 'author': 'Fleischmann M.', 'year': '1963'} / Advances of Electrochemistry and Electrochemical Engineering by Fleischmann M. (1963)
10.1002/bbpc.19870910446
10.1016/0039-6028(76)90239-9
10.1016/S0022-0728(77)80235-0
10.1016/S0022-0728(77)80299-4
10.1016/0013-4686(84)89002-7
10.1016/0013-4686(85)80006-2
10.1016/0022-0728(91)85552-Z
{'key': 'e_1_2_1_15_2', 'first-page': '215', 'volume-title': 'Adsorption of Molecules at Metal Electrodes', 'author': 'Lipkowski J.', 'year': '1992'} / Adsorption of Molecules at Metal Electrodes by Lipkowski J. (1992)
10.1016/0013-4686(92)85134-7
10.1016/S0022-0728(79)80022-4
10.1016/0013-4686(76)85072-4
10.1016/0022-0728(88)80368-1
10.1016/0022-0728(86)80127-9
{'key': 'e_1_2_1_21_2', 'first-page': '597', 'volume': '77', 'author': 'Ianelli A.', 'year': '1990', 'journal-title': 'Plating and Surface Finishing'} / Plating and Surface Finishing by Ianelli A. (1990)
10.1016/0022-0728(93)80341-E
10.1016/0013-4686(86)80005-6
10.1016/0039-6028(93)90027-H
10.1016/0039-6028(85)90977-X
{'key': 'e_1_2_1_26_2', 'first-page': '65', 'volume-title': 'Structure of the Electrified Interface', 'author': 'Kolb D. M.', 'year': '1993'} / Structure of the Electrified Interface by Kolb D. M. (1993)
10.1016/0039-6028(88)90455-4
10.1149/1.2108505
{'key': 'e_1_2_1_29_2', 'volume-title': 'Instrumental Methods in Electrochemistry', 'author': 'Southampton Electrochemical Group', 'year': '1990'} / Instrumental Methods in Electrochemistry by Southampton Electrochemical Group (1990)
10.1016/0039-6028(92)90036-6
10.1021/j100295a050
{'key': 'e_1_2_1_32_2', 'first-page': '125', 'volume-title': 'Advances of Electrochemistry and Electrochemical Engineering', 'author': 'Kolb D. M.', 'year': '1978'} / Advances of Electrochemistry and Electrochemical Engineering by Kolb D. M. (1978)
10.1002/bbpc.197800098
10.1039/fs9771200036
10.1002/bbpc.19840880405
10.1021/la00081a039
10.1063/1.451404
10.1103/PhysRevLett.64.2929
10.1016/0022-0728(91)80076-3
10.1039/fd9929400093
10.1016/0009-2614(92)87001-6
10.1002/bbpc.198800296
J. G.Gordon O.Melroy G. L.Borges K. K.Kanazawa J.Richter andJ.Howard in preparation.
L.BlumandD. A.Huckaby J. Electroanal. Chem. (1993) in press.
M. H.Hölzle U.Retter andD. M.Kolb J. Electroanal. Chem. (1994) in press.
10.1016/0013-4686(92)85232-A
10.1016/0022-0728(85)85049-X
10.1002/bbpc.19870910423
{'key': 'e_1_2_1_49_2', 'volume-title': 'Schering Lectures Publication', 'author': 'Kolb D. M.', 'year': '1991'} / Schering Lectures Publication by Kolb D. M. (1991)
10.1016/0022-0728(92)80459-H

Dates

Type	When
Created	13 years, 1 month ago (July 26, 2012, 5:51 a.m.)
Deposited	1 year, 10 months ago (Oct. 23, 2023, 9:05 p.m.)
Indexed	1 year, 6 months ago (Feb. 6, 2024, 9:49 a.m.)
Issued	31 years, 5 months ago (March 1, 1994)
Published	31 years, 5 months ago (March 1, 1994)
Published Online	15 years, 3 months ago (May 8, 2010)
Published Print	31 years, 5 months ago (March 1, 1994)

Funders 0

None

BibTeX

@article{H_lzle_1994, title={Two‐dimensional phase transitions in electrochemically formed adlayers on gold}, volume={98}, ISSN={0005-9021}, url={http://dx.doi.org/10.1002/bbpc.19940980309}, DOI={10.1002/bbpc.19940980309}, number={3}, journal={Berichte der Bunsengesellschaft für physikalische Chemie}, publisher={Wiley}, author={Hölzle, M. H. and Kolb, D. M.}, year={1994}, month=mar, pages={330–335} }

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