DOI: 10.1002/bbpc.19930970316. Electron Spin‐Resonance (ESR) Studies of Adsorbate Dynamics on Single Crystal Surfaces: Possibilities and Limitations

Electron Spin‐Resonance (ESR) Studies of Adsorbate Dynamics on Single Crystal Surfaces: Possibilities and Limitations

10.1002/bbpc.19930970316

Crossref journal-article

Wiley

Berichte der Bunsengesellschaft für physikalische Chemie (311)

Abstract

AbstractESR is not one of the standard surface science tools because it is not inherently surface sensitive but rather probes the entire sample. However, ESR can be made into a surface science tool if we use paramagnetic adsorbates on thin nonmagnetic transition metal substrates or transition metal oxide films interacting with paramagnetic or nonmagnetic adsorbates. In contrast to NMR, ESR exhibits a sensitivity which allows one to detect monolayer and submonolayer coverages of spins (>1012 spins). The experiments can be carried out either in ultrahigh vacuum (UHV) or under an ambient gas atmosphere. — ESR provides us with the unique opportunity to study adsorbate dynamics by studying line shape changes as a function of temperature. ESR is also sensitive to molecular orientation so that the orientation distribution of the molecular planes may be derived experimentally. Thus ESR allows us to derive information not easily accessible with other techniques. We describe the set up of a UHV/ESR experiment in which the ESR measurement may be combined with LEED/Auger and TDS experiments. Several types of results are discussed: ESR of chemisorbed and physisorbed molecules on metal surfaces including angle dependent measurements. ESR of molecules on oxide surfaces at submonolayers coverages. We will touch on possible future experiments involving pulsed ESR techniques to study dynamics in the adsorbate for a wide variety of processes including rotation and diffusion.

Bibliography

Katter, U. J., Schlienz, H., Beckendorf, M., & Freund, H. âJ. (1993). Electron SpinâResonance (ESR) Studies of Adsorbate Dynamics on Single Crystal Surfaces: Possibilities and Limitations. Berichte Der Bunsengesellschaft FÃ¼r Physikalische Chemie, 97(3), 340â352. Portico.

Authors 4

U. J. Katter (first)
H. Schlienz (additional)
M. Beckendorf (additional)
H.‐J. Freund (additional)

References 49 Referenced 27

{'key': 'e_1_2_1_2_2', 'volume-title': 'Principles of Nuclear Magnetic Resonance in One and Two Dimensions', 'author': 'Ernst R. R.', 'year': '1986'} / Principles of Nuclear Magnetic Resonance in One and Two Dimensions by Ernst R. R. (1986)
{'key': 'e_1_2_1_3_2', 'volume-title': 'Ein‐ und zweidimensionale NMR‐Spektroskopie: Eine Einführung', 'author': 'Friebolin H.', 'year': '1992'} / Ein‐ und zweidimensionale NMR‐Spektroskopie: Eine Einführung by Friebolin H. (1992)
{'key': 'e_1_2_1_4_2', 'volume-title': 'NMR‐Spektroskopie', 'author': 'Günther H.', 'year': '1983'} / NMR‐Spektroskopie by Günther H. (1983)
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10.1016/0021-9517(92)90153-9
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{'key': 'e_1_2_1_17_2', 'volume-title': 'Electron Spin Resonance', 'author': 'Poole C. P.', 'year': '1967'} / Electron Spin Resonance by Poole C. P. (1967)
{'key': 'e_1_2_1_18_2', 'volume-title': 'Magnetic Atoms and Molecules” Scientific and Academic Editions', 'author': 'Weltner W.', 'year': '1983'} / Magnetic Atoms and Molecules” Scientific and Academic Editions by Weltner W. (1983)
{'key': 'e_1_2_1_19_2', 'volume-title': 'Pulsed EPR: A new field of applications', 'author': 'Keijzers C. P.', 'year': '1989'} / Pulsed EPR: A new field of applications by Keijzers C. P. (1989)
{'key': 'e_1_2_1_20_2', 'first-page': '11', 'volume': '87', 'author': 'Bagdonat S.', 'year': '1973', 'journal-title': 'Z. Phys. Chem.'} / Z. Phys. Chem. by Bagdonat S. (1973)
{'key': 'e_1_2_1_21_2', 'first-page': '23', 'volume': '87', 'author': 'Bagdonat S.', 'year': '1973', 'journal-title': 'Z. Phys. Chem.'} / Z. Phys. Chem. by Bagdonat S. (1973)
{'key': 'e_1_2_1_22_2', 'volume-title': 'Magnetic Resonance in Surface Science” in Springer Series in Chemical Physics', 'author': 'Howe R. F.', 'year': '1984'} / Magnetic Resonance in Surface Science” in Springer Series in Chemical Physics by Howe R. F. (1984)
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{'key': 'e_1_2_1_28_2', 'volume-title': 'Spin Labeling Theory and Applications', 'author': 'Schneider D. J.', 'year': '1988'} / Spin Labeling Theory and Applications by Schneider D. J. (1988)
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M.Menges Dissertation Ruhr‐Universität Bochum in preparation. — D. Cappus Dissertation Ruhr‐Universität Bochum in preparation.
Th.Bertram A.Brodde andH.Neddermeyer unpublished data.
R. M.Jaeger Dissertation Ruhr‐Universität Bochum in preparation.
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M.Zomack Dissertation FU Berlin1987.

Dates

Type	When
Created	13 years, 1 month ago (July 26, 2012, 6:15 a.m.)
Deposited	1 year, 10 months ago (Oct. 24, 2023, 10:49 p.m.)
Indexed	1 year, 2 months ago (June 12, 2024, 9:12 a.m.)
Issued	32 years, 6 months ago (March 1, 1993)
Published	32 years, 6 months ago (March 1, 1993)
Published Online	15 years, 3 months ago (May 8, 2010)
Published Print	32 years, 6 months ago (March 1, 1993)

Funders 0

None

BibTeX

@article{Katter_1993, title={Electron Spin‐Resonance (ESR) Studies of Adsorbate Dynamics on Single Crystal Surfaces: Possibilities and Limitations}, volume={97}, ISSN={0005-9021}, url={http://dx.doi.org/10.1002/bbpc.19930970316}, DOI={10.1002/bbpc.19930970316}, number={3}, journal={Berichte der Bunsengesellschaft für physikalische Chemie}, publisher={Wiley}, author={Katter, U. J. and Schlienz, H. and Beckendorf, M. and Freund, H.‐J.}, year={1993}, month=mar, pages={340–352} }

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