Abstract
AbstractDecomposition and ionization reactions of neat liquid alkanes, alcohols, water, and halomethanes after UV‐two‐photon absorption were investigated by pump‐and‐probe measurements with subpicosecond time resolution. Previous suggestions are revised and new mechanisms proposed which consistently explain the transient absorption signals obtained. In particular, it is shown that the importance of free or “quasi‐free” electrons as intermediates in the photodecomposition of liquids has commonly been largely overestimated.
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Dates
Type | When |
---|---|
Created | 13 years, 1 month ago (July 26, 2012, 10:29 a.m.) |
Deposited | 1 year, 10 months ago (Oct. 23, 2023, 1:52 p.m.) |
Indexed | 1 year, 6 months ago (Feb. 6, 2024, 9:48 p.m.) |
Issued | 32 years, 11 months ago (Oct. 1, 1992) |
Published | 32 years, 11 months ago (Oct. 1, 1992) |
Published Online | 15 years, 3 months ago (May 8, 2010) |
Published Print | 32 years, 11 months ago (Oct. 1, 1992) |
@article{Sander_1992, title={Fast Processes in UV‐Two‐Photon Excitation of Pare Liquids}, volume={96}, ISSN={0005-9021}, url={http://dx.doi.org/10.1002/bbpc.19920961027}, DOI={10.1002/bbpc.19920961027}, number={10}, journal={Berichte der Bunsengesellschaft für physikalische Chemie}, publisher={Wiley}, author={Sander, Martin and Brummund, Uwe and Luther, Klaus and Troe, Jürgen}, year={1992}, month=oct, pages={1486–1490} }