DOI: 10.1002/bbpc.19840880309. Metal‐Clusters: Preparation, Properties, Theory

Metal‐Clusters: Preparation, Properties, Theory

10.1002/bbpc.19840880309

Crossref journal-article

Wiley

Berichte der Bunsengesellschaft für physikalische Chemie (311)

Abstract

AbstractMethods for the production of small molecules Mnwith 2 <n< 100 are critically discussed and explained. The characterization must take into account the existence of a size‐distribution as a consequence of the generation process. Several new spectroscopic methods have been developed for the observation of single particle properties in these mixtures. They all make use of the mass spectrometer as detector. Discussed are the ionization‐potentials as function of size which do not reveal an abrupt change in electronic properties during the transition from a discrete molecular to a metallic behaviour. Certain aspects of the optical spectra of a few diatomic and triatomic clusters are then presented. Quantumchemical elucidations in the small cluster‐range are necessary and very helpful. However, more realistic computations are needed to understand spectra.

Bibliography

Schumacher, E., Kappes, M., Marti, K., Radi, P., SchÃ¤r, M., & Schmidhalter, B. (1984). MetalâClusters: Preparation, Properties, Theory. Berichte Der Bunsengesellschaft FÃ¼r Physikalische Chemie, 88(3), 220â228. Portico.

Authors 6

E. Schumacher (first)
M. Kappes (additional)
K. Marti (additional)
P. Radi (additional)
M. Schär (additional)
B. Schmidhalter (additional)

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Dates

Type	When
Created	13 years ago (July 30, 2012, 6:32 a.m.)
Deposited	4 months, 2 weeks ago (April 6, 2025, 4:15 a.m.)
Indexed	4 months, 2 weeks ago (April 6, 2025, 4:40 a.m.)
Issued	41 years, 5 months ago (March 1, 1984)
Published	41 years, 5 months ago (March 1, 1984)
Published Online	15 years, 3 months ago (May 7, 2010)
Published Print	41 years, 5 months ago (March 1, 1984)

Funders 0

None

BibTeX

@article{Schumacher_1984, title={Metal‐Clusters: Preparation, Properties, Theory}, volume={88}, ISSN={0005-9021}, url={http://dx.doi.org/10.1002/bbpc.19840880309}, DOI={10.1002/bbpc.19840880309}, number={3}, journal={Berichte der Bunsengesellschaft für physikalische Chemie}, publisher={Wiley}, author={Schumacher, E. and Kappes, M. and Marti, K. and Radi, P. and Schär, M. and Schmidhalter, B.}, year={1984}, month=mar, pages={220–228} }

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