DOI: 10.1002/bbpc.19830870925. Free Energy Criteria for Glass Forming Alloys

Free Energy Criteria for Glass Forming Alloys

10.1002/bbpc.19830870925

Crossref journal-article

Wiley

Berichte der Bunsengesellschaft für physikalische Chemie (311)

Abstract

AbstractThe thermodynamic characterisation of a number of glass forming systems (Au – Si, Pd – Si, Ni – Ti, Ti – Be, Zr – Be and Hf – Be) has been reviewed, and the free energy curves calculated for the glass forming temperature as well as for the temperature of maximum rate of crystallisation, in order to check how far the data which models the equilibrium diagrams provides suitable guidance for metallic glass formation. It is shown that the glass forming range is accurately predicted from the region where the liquid phase is more stable than other competing single phases, thus confirming the importance of the T0 concept. The systems considered offer a variety of behaviour which emphasises the importance of metastable compound formation as well as the inhibition of some equilibrium compounds. The present treatment is compared with other approaches to the problem.

Bibliography

Saunders, N., & Miodownik, A. P. (1983). Free Energy Criteria for Glass Forming Alloys. Berichte Der Bunsengesellschaft FÃ¼r Physikalische Chemie, 87(9), 830â834. Portico.

Authors 2

N. Saunders (first)
A. P. Miodownik (additional)

References 31 Referenced 33

B. C.Giessen NBS “Phase Diagram Workshop” Special publ. 496(II) p.11(1977).
{'key': 'e_1_2_1_3_2', 'first-page': '50', 'volume-title': 'Rapid Solidification Processing: Principles and Technology', 'author': 'Boettinger W.', 'year': '1980'} / Rapid Solidification Processing: Principles and Technology by Boettinger W. (1980)
{'key': 'e_1_2_1_4_2', 'first-page': '77', 'volume': '73', 'author': 'Sommer F.', 'year': '1982', 'journal-title': 'Z. Metallkd.'} / Z. Metallkd. by Sommer F. (1982)
10.1016/0025-5416(76)90196-8
10.1007/BF00566250
10.1016/0001-6160(77)90240-1
J. C.BakerandJ. W.Cahn Solidification Symposium Philadelphia (ASM) Ch. 2P23(1971).
{'key': 'e_1_2_1_9_2', 'volume-title': 'To be published in Alloy Phase Diagrams, Proc. MRS Boston 1982', 'author': 'Massalski T. B.', 'year': '1983'} / To be published in Alloy Phase Diagrams, Proc. MRS Boston 1982 by Massalski T. B. (1983)
10.1016/0001-6160(79)90087-7
10.1016/0001-6160(80)90034-6
{'key': 'e_1_2_1_12_2', 'volume-title': "”︁Rapid Solidification Processing in Metals and Alloys'", 'author': 'Jones H.', 'year': '1982'} / ”︁Rapid Solidification Processing in Metals and Alloys' by Jones H. (1982)
{'key': 'e_1_2_1_13_2', 'volume-title': 'Computer Calculations of Phase Diagrams', 'author': 'Kaufman L.', 'year': '1970'} / Computer Calculations of Phase Diagrams by Kaufman L. (1970)
10.1038/187869b0
10.1016/0022-5088(75)90138-1
10.1063/1.1710186
B.LewisandH.Davies Proc. Soc. Glass Tech. Symposium Volume (ed. P. Gaskell) p.89(1967).
{'key': 'e_1_2_1_18_2', 'volume-title': 'Constitution of Binary Alloys', 'year': '1958'} / Constitution of Binary Alloys (1958)
{'key': 'e_1_2_1_19_2', 'first-page': '900', 'volume': '236', 'author': 'Hunter D.', 'year': '1966', 'journal-title': 'Trans. Metall. Soc. AIME'} / Trans. Metall. Soc. AIME by Hunter D. (1966)
{'key': 'e_1_2_1_20_2', 'first-page': '773', 'volume-title': 'Titanium Science and Technology (II)', 'author': 'Kaufman L.', 'year': '1973'} / Titanium Science and Technology (II) by Kaufman L. (1973)
10.1016/0364-5916(79)90010-5
10.1016/0364-5916(78)90006-8
10.1039/tf9585400814
10.1002/srin.193800804
{'key': 'e_1_2_1_25_2', 'first-page': '473', 'volume': '83', 'author': 'Poole D.', 'year': '1955', 'journal-title': 'J. Inst. Met.'} / J. Inst. Met. by Poole D. (1955)
10.1007/BF02652848
{'key': 'e_1_2_1_27_2', 'first-page': '719', 'volume-title': 'Science and Technology of Titanium Alloys', 'author': 'Miodownik A. P.', 'year': '1970'} / Science and Technology of Titanium Alloys by Miodownik A. P. (1970)
10.1016/0036-9748(68)90138-5
10.1016/0025-5416(76)90184-1
10.1016/0001-6160(78)90137-2
10.1016/0001-6160(74)90054-6
10.1016/0001-6160(79)90076-2

Dates

Type	When
Created	13 years ago (July 30, 2012, 8:12 a.m.)
Deposited	1 year, 10 months ago (Oct. 19, 2023, 8:44 p.m.)
Indexed	1 year ago (Aug. 6, 2024, 6:32 a.m.)
Issued	41 years, 11 months ago (Sept. 1, 1983)
Published	41 years, 11 months ago (Sept. 1, 1983)
Published Online	15 years, 3 months ago (May 7, 2010)
Published Print	41 years, 11 months ago (Sept. 1, 1983)

Funders 0

None

BibTeX

@article{Saunders_1983, title={Free Energy Criteria for Glass Forming Alloys}, volume={87}, ISSN={0005-9021}, url={http://dx.doi.org/10.1002/bbpc.19830870925}, DOI={10.1002/bbpc.19830870925}, number={9}, journal={Berichte der Bunsengesellschaft für physikalische Chemie}, publisher={Wiley}, author={Saunders, N. and Miodownik, A. P.}, year={1983}, month=sep, pages={830–834} }

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