DOI: 10.1002/bbpc.19810850907. A Structural Investigation of Liquid Chloroform

A Structural Investigation of Liquid Chloroform

10.1002/bbpc.19810850907

Crossref journal-article

Wiley

Berichte der Bunsengesellschaft für physikalische Chemie (311)

Abstract

AbstractStarting from neutron scattering experiments on the species CDCl3, CD35Cl3, CD37Cl3 and CHCl3 the expansion coefficients of the generalized pair correlation function g00000(R), g00101(R), g00202(R), and g00110(R) are determined and analyzed quantitatively, thus providing preferred positions and orientations of the molecules in liquid chloroform. From the same set of experimental data the chlorine‐chlorine pair correlation function and the weighted sum of the chlorine‐hydrogen and chlorine‐carbon pair correlation functions are evaluated. The most probable configuration between two chloroform molecules in the liquid phase is derived from the position of the first peak of the corresponding pair correlation function. Both ways of description yield a consistent structural picture; namely the dipole axes are inclined and the hydrogen atoms point into the hollow between two chlorine atoms.

Bibliography

Bertagnolli, H. (1981). A Structural Investigation of Liquid Chloroform. Berichte Der Bunsengesellschaft FÃ¼r Physikalische Chemie, 85(9), 644â650. Portico.

Authors 1

H. Bertagnolli (first)

References 14 Referenced 21

10.1080/00268977800100131
10.1080/00268977800100141
10.1080/00268977800102751
10.1002/bbpc.19800841207
10.1080/00268977800100121
10.1002/bbpc.19810850111
J. E.EnderbyandG. W.Neilson in:Water A Comprehensive Treatise Vol. 6 (F. Franks ed.) New York1979.
{'key': 'e_1_2_1_9_2', 'first-page': '69', 'volume': '263', 'author': 'Fourme R.', 'year': '1966', 'journal-title': 'C. R. Acad. Sci. Paris, Ser. B.'} / C. R. Acad. Sci. Paris, Ser. B. by Fourme R. (1966)
{'key': 'e_1_2_1_10_2', 'first-page': '951', 'volume': '80', 'author': 'Hertz H. G.', 'year': '1976', 'journal-title': 'Ber. Bunsenges. Phys. Chem.'} / Ber. Bunsenges. Phys. Chem. by Hertz H. G. (1976)
{'key': 'e_1_2_1_10_3', 'first-page': '1269', 'volume': '80', 'author': 'Hertz H. G.', 'year': '1976', 'journal-title': 'Ber. Bunsenges. Phys. Chem.'} / Ber. Bunsenges. Phys. Chem. by Hertz H. G. (1976)
10.1002/bbpc.19770810505
10.1524/zpch.1976.103.5_6.279
10.1063/1.433111
10.1080/00268977700101881

Dates

Type	When
Created	13 years, 1 month ago (July 31, 2012, noon)
Deposited	1 year, 10 months ago (Oct. 19, 2023, 12:27 a.m.)
Indexed	3 months, 2 weeks ago (May 22, 2025, 5:49 a.m.)
Issued	44 years ago (Sept. 1, 1981)
Published	44 years ago (Sept. 1, 1981)
Published Online	15 years, 2 months ago (June 22, 2010)
Published Print	44 years ago (Sept. 1, 1981)

Funders 0

None

BibTeX

@article{Bertagnolli_1981, title={A Structural Investigation of Liquid Chloroform}, volume={85}, ISSN={0005-9021}, url={http://dx.doi.org/10.1002/bbpc.19810850907}, DOI={10.1002/bbpc.19810850907}, number={9}, journal={Berichte der Bunsengesellschaft für physikalische Chemie}, publisher={Wiley}, author={Bertagnolli, H.}, year={1981}, month=sep, pages={644–650} }

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  "abstract": "<jats:title>Abstract</jats:title><jats:p>Starting from neutron scattering experiments on the species CDCl<jats:sub>3</jats:sub>, CD<jats:sup>35</jats:sup>Cl<jats:sub>3</jats:sub>, CD<jats:sup>37</jats:sup>Cl<jats:sub>3</jats:sub> and CHCl<jats:sub>3</jats:sub> the expansion coefficients of the generalized pair correlation function <jats:italic>g</jats:italic><jats:sub>00</jats:sub><jats:sup>000</jats:sup>(<jats:italic>R</jats:italic>), <jats:italic>g</jats:italic><jats:sub>00</jats:sub><jats:sup>101</jats:sup>(<jats:italic>R</jats:italic>), <jats:italic>g</jats:italic><jats:sub>00</jats:sub><jats:sup>202</jats:sup>(<jats:italic>R</jats:italic>), and <jats:italic>g</jats:italic><jats:sub>00</jats:sub><jats:sup>110</jats:sup>(<jats:italic>R</jats:italic>) are determined and analyzed quantitatively, thus providing preferred positions and orientations of the molecules in liquid chloroform. From the same set of experimental data the chlorine\u2010chlorine pair correlation function and the weighted sum of the chlorine\u2010hydrogen and chlorine\u2010carbon pair correlation functions are evaluated. The most probable configuration between two chloroform molecules in the liquid phase is derived from the position of the first peak of the corresponding pair correlation function. Both ways of description yield a consistent structural picture; namely the dipole axes are inclined and the hydrogen atoms point into the hollow between two chlorine atoms.</jats:p>",
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