DOI: 10.1002/bbpc.19780820705. Hydration Properties of Oxygen Containing Linear Heterohydrocarbons as Studied by Dielectric Relaxation Measurements

Hydration Properties of Oxygen Containing Linear Heterohydrocarbons as Studied by Dielectric Relaxation Measurements

10.1002/bbpc.19780820705

Crossref journal-article

Wiley

Berichte der Bunsengesellschaft für physikalische Chemie (311)

Abstract

AbstractComplex permittivities of aqueous solutions of ethylene‐glycols, HO‐(CH2‐CH2‐O)n‐H (n = 1, 2, 3, 4, 4.1, 8.7, or 13.2, and of ethylene‐glycol dimethylethers, H3C‐O‐(CH2‐CH2‐O)n,‐CH3 (n = 1, 2, or 3), have been measured at 11 up to 13 frequencies in the range 2 to 40 GHz by an interferometric transmission method. A sum of relaxation functions has been fitted to the observed data to yield the hydration number and reorientation time of the hydration water. The values of these parameters are discussed and compared with those for poly (ethylene oxide) of different degree of polymerization and those for other series of organic solutes in order to get insight into the effect of various molecular parameters on the microdynamics of the surrounding water.

Bibliography

Kaatze, U. (1978). Hydration Properties of Oxygen Containing Linear Heterohydrocarbons as Studied by Dielectric Relaxation Measurements. Berichte Der Bunsengesellschaft FÃ¼r Physikalische Chemie, 82(7), 690â696. Portico.

Authors 1

Udo Kaatze (first)

References 17 Referenced 17

{'key': 'e_1_2_1_2_2', 'first-page': '426', 'volume': '1', 'author': 'Davies J. T.', 'year': '1957', 'journal-title': 'Proc. Int. Congr. Surf. Activity, 2nd.'} / Proc. Int. Congr. Surf. Activity, 2nd. by Davies J. T. (1957)
10.1002/app.1959.070010110
10.1002/bbpc.19740780608 / Ber Bunsenges Phys. Chem. by Kaatze U. (1974)
10.1021/j100517a016
10.1021/j100490a025
10.1016/0001-8716(75)80015-0
10.1063/1.1750906
R.PottelandU.Kaatze Adv. Molec. Relaxation Processes. to be published.
Them‐ vs. ‐vrelation (Equation (8)) is displayed in Fig. 1 of Ref. [10]. Anm‐ vs. ‐cwplot is given in Fig 4 of Ref. [5].
10.1021/j100490a024
Results for aqueous dioxane solutions are taken from Ref [5]. where the Rs(v)function defined by Equation (7) was fetted to former data with the restrictions (0) =2and = 0. Complex permittivity values as obtained at around 3 8 and 23.8 GHz by Hasted et al. [12] ana static permittivity values of Akerlöf et al. [13] had been used in these calculations The ZhandThvalues quoted here are mean values for three solutions of different solute concentration.
10.1039/tf9514700577
10.1021/ja01298a044
10.1002/bbpc.19750790308
10.1002/bbpc.19690730504 / Ber. Bunsenges. Phys. Chem. by Pottel R. (1969)
U.Kaatze Colloid and Polymer Science to be published1978.
O.Göttmann U.Kaatze R.Podbielski andR.Pottel to be published.

Dates

Type	When
Created	12 years, 11 months ago (Sept. 4, 2012, 9:52 a.m.)
Deposited	1 year, 9 months ago (Nov. 13, 2023, 7:47 p.m.)
Indexed	1 year, 9 months ago (Nov. 14, 2023, 12:16 a.m.)
Issued	47 years, 2 months ago (July 1, 1978)
Published	47 years, 2 months ago (July 1, 1978)
Published Online	15 years, 3 months ago (May 6, 2010)
Published Print	47 years, 2 months ago (July 1, 1978)

Funders 0

None

BibTeX

@article{Kaatze_1978, title={Hydration Properties of Oxygen Containing Linear Heterohydrocarbons as Studied by Dielectric Relaxation Measurements}, volume={82}, ISSN={0005-9021}, url={http://dx.doi.org/10.1002/bbpc.19780820705}, DOI={10.1002/bbpc.19780820705}, number={7}, journal={Berichte der Bunsengesellschaft für physikalische Chemie}, publisher={Wiley}, author={Kaatze, Udo}, year={1978}, month=jul, pages={690–696} }

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