DOI: 10.1002/bbpc.19750790515. Unimolecular Processes IV: Product State Distributions after Dissociation

Unimolecular Processes IV: Product State Distributions after Dissociation

10.1002/bbpc.19750790515

Crossref journal-article

Wiley

Berichte der Bunsengesellschaft für physikalische Chemie (311)

Abstract

AbstractThe statistical adiabatic channel model is used to calculate the distribution of internal states and center of mass translational energies of fragments in unimolecular dissociation. The reactions ClNO → Cl + NO and NO2 → NO + O are considered as examples. The influence of molecular parameters and dynamical constraints is illustrated. Mechanisms providing randomness in photodissociation and unimolecular decomposition are discussed as well as the relation between dissociation rates and statistical scattering. The statistical calculations for NO2 decomposition are in good agreement with the experimental center of mass translational energy distributions from photofragment spectroscopy.

Bibliography

Quack, M., & Troe, J. (1975). Unimolecular Processes IV: Product State Distributions after Dissociation. Berichte Der Bunsengesellschaft FÃ¼r Physikalische Chemie, 79(5), 469â475. Portico.

Authors 2

M. Quack (first)
J. Troe (additional)

References 58 Referenced 90

10.1063/1.1679733
10.1515/zna-1970-0711 / Z. Naturforsch. by v. Puttkamer E. (1970)
10.1515/zna-1972-0216 / Z. Naturforsch. by Andlauer B. (1972)
10.1002/bbpc.19680720808
10.1039/dc9735500233
10.1002/bbpc.19740780209
10.1063/1.1677740
10.1063/1.1677742
{'key': 'e_1_2_1_8_2', 'volume-title': 'MTP International Review of Science', 'author': 'Carrington Tucker', 'year': '1972'} / MTP International Review of Science by Carrington Tucker (1972)
10.1039/dc9735500252
10.1039/dc9735500277
10.1063/1.1681763
10.1021/ja00996a003
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10.1002/bbpc.19750790211
10.1002/bbpc.19740780306
M.Quack Dissertation Lausanne1975;
M.QuackandJ.Troe to be published.
{'key': 'e_1_2_1_16_2', 'volume-title': 'Molecular Spectra and Molecular Structure', 'author': 'Herzberg G.', 'year': '1966'} / Molecular Spectra and Molecular Structure by Herzberg G. (1966)
10.1080/00268977200100251
A. J.LorquetandJ. C.Lorquet The Predissociation of the H2O+Ion paper presented at the first International Congress of Quantum Chemistry Menton1973.
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10.1002/9780470133378.ch3
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10.1016/0301-0104(74)80075-3
10.1016/0009-2614(73)80020-X
10.1016/0009-2614(72)80389-0
10.1016/0031-8914(72)90151-6
10.1063/1.1671552
10.1063/1.1727650
{'key': 'e_1_2_1_24_2', 'first-page': '767', 'volume': '78', 'author': 'Luu S. H.', 'year': '1974', 'journal-title': 'Ber. Bunsenges. physik. Chem.'} / Ber. Bunsenges. physik. Chem. by Luu S. H. (1974)
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10.1002/bbpc.19690730832
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10.1515/zna-1970-0539 / Z. Naturforsch. by Gaedtke H. (1970)
10.1002/bbpc.19750790212
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references to earlier work and to photolysis can also be found in ref. [25].
10.1139/p65-006
By now the predictions in ref. [12] for the vibrational relaxation rate constants of O + NO(v) and Cl + NO(v) have been verified experimentally (in addition to the previously known O + O2(v):K.GlänzerandJ.Troe J. chem. Physics to be published.
10.1103/PhysRev.118.349
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10.1063/1.1672069

Dates

Type	When
Created	12 years, 11 months ago (Sept. 4, 2012, 10:34 a.m.)
Deposited	1 year, 10 months ago (Oct. 19, 2023, 5:02 a.m.)
Indexed	1 year, 3 months ago (May 23, 2024, 4:25 a.m.)
Issued	50 years, 3 months ago (May 1, 1975)
Published	50 years, 3 months ago (May 1, 1975)
Published Online	15 years, 3 months ago (May 5, 2010)
Published Print	50 years, 3 months ago (May 1, 1975)

Funders 0

None

BibTeX

@article{Quack_1975, title={Unimolecular Processes IV: Product State Distributions after Dissociation}, volume={79}, ISSN={0005-9021}, url={http://dx.doi.org/10.1002/bbpc.19750790515}, DOI={10.1002/bbpc.19750790515}, number={5}, journal={Berichte der Bunsengesellschaft für physikalische Chemie}, publisher={Wiley}, author={Quack, M. and Troe, J.}, year={1975}, month=may, pages={469–475} }

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